公开(公告)号：US20110178189A1

公开(公告)日：2011-07-21

申请号：US12672981

申请日：2008-08-05

申请人： Johannes Jacobus Huyser ,  Riaan Bekker ,  Janse Van Vuuren ,  Ryno Kotze

发明人： Johannes Jacobus Huyser ,  Riaan Bekker ,  Janse Van Vuuren ,  Ryno Kotze

IPC分类号： C07C27/00

CPC分类号： B01J23/745 ,  B01J23/78 ,  B01J37/16 ,  B01J37/18 ,  C10G2/332 ,  C10G2300/703

摘要： This invention relates to a Fischer Tropsch process using a catalyst activated in accordance with the invention. More particularly the invention relates to a three phase Low Temperature Fischer Tropsch process wherein CO and H2 are converted to hydrocarbons and possibly oxygenates thereof by contacting syngas including CO and H2 in the presence of an iron based Fischer Tropsch catalyst, wherein the ratio of H2:CO in the feed is between 2.5 and 1, and wherein the iron based Fischer Tropsch catalyst is activated according to the steps of: (a) providing an iron catalyst including iron in a positive oxidation state; and (b) contacting the iron catalyst in a reactor with a reducing gas selected from CO and a combination of H2 and CO; at a temperature of at least 245° C. and below 280° C.; at a reducing gas pressure of above 0.5 MPa and not more than 2.2 MPa; and at a GHSV of total gas fed to the reactor of at least 6000 ml(N)/g cat/h, thereby reducing the iron that is in a positive oxidation step in the catalyst.

摘要翻译： 本发明涉及使用根据本发明活化的催化剂的费 - 托法。 更具体地说，本发明涉及一种三相低温费 - 托法，其中CO和H 2在铁基费 - 托催化剂存在下，通过使包含CO和H 2的合成气接触将CO和H 2转化为烃，并且可能含氧化合物，其中H 2 ：进料中的CO为2.5〜1，其中铁基费托催化剂根据以下步骤活化：（a）提供含有正氧化态的铁的铁催化剂; 和（b）使反应器中的铁催化剂与选自CO和H 2和CO的组合的还原气体接触; 在至少245℃和低于280℃的温度下进行。 在0.5MPa以上且2.2MPa以下的还原气体压力下， 并且在进料到反应器的总气体的GHSV为至少6000ml（N）/ g cat / h，从而减少催化剂中正氧化步骤中的铁。

公开(公告)号：US08513312B2

公开(公告)日：2013-08-20

申请号：US12672981

申请日：2008-08-05

申请人： Johannes Jacobus Huyser ,  Riaan Bekker ,  Matthys Josephus Janse Van Vuuren ,  Ryno Kotze

发明人： Johannes Jacobus Huyser ,  Riaan Bekker ,  Matthys Josephus Janse Van Vuuren ,  Ryno Kotze

IPC分类号： C07C27/00 ,  B01J20/34

CPC分类号： B01J23/745 ,  B01J23/78 ,  B01J37/16 ,  B01J37/18 ,  C10G2/332 ,  C10G2300/703

摘要： This invention relates to a Fischer Tropsch process using a catalyst activated in accordance with the invention. More particularly the invention relates to a three phase Low Temperature Fischer Tropsch process wherein CO and H2 are converted to hydrocarbons and possibly oxygenates thereof by contacting syngas including CO and H2 in the presence of an iron based Fischer Tropsch catalyst, wherein the ratio of H2:CO in the feed is between 2.5 and 1, and wherein the iron based Fischer Tropsch catalyst is activated according to the steps of: (a) providing an iron catalyst including iron in a positive oxidation state; and (b) contacting the iron catalyst in a reactor with a reducing gas selected from CO and a combination of H2 and CO; at a temperature of at least 245° C. and below 280° C.; at a reducing gas pressure of above 0.5 MPa and not more than 2.2 MPa; and at a GHSV of total gas fed to the reactor of at least 6000 ml(N)/g cat/h, thereby reducing the iron that is in a positive oxidation step in the catalyst.

摘要翻译： 本发明涉及使用根据本发明活化的催化剂的费 - 托法。 更具体地说，本发明涉及一种三相低温费 - 托法，其中CO和H 2在铁基费 - 托催化剂存在下，通过使包含CO和H 2的合成气接触将CO和H 2转化成烃，并且其中CO 2和H 2的比例 进料中的CO为2.5〜1，其中铁基费托催化剂根据以下步骤活化：（a）提供包含正氧化态的铁的铁催化剂; 和（b）使反应器中的铁催化剂与选自CO和H 2和CO的组合的还原气体接触; 在至少245℃和低于280℃的温度下进行。 在0.5MPa以上且2.2MPa以下的还原气体压力下， 并且在进料到反应器的总气体的GHSV为至少6000ml（N）/ g cat / h，从而减少催化剂中正氧化步骤中的铁。