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公开(公告)号：US06241871B1
公开(公告)日：2001-06-05
申请号：US09314106
申请日：1999-05-19
IPC分类号： C25C100
摘要： The invention relates to a process for gas phase electrochemical oxidation of H2S to sulfur and water or steam using an electrolysis cell having an anode chamber on one side of a solid proton conducting membrane and a cathode chamber on the other side of the membrane. The process comprises the steps of passing H2S-containing gas through the anode chamber to contact a catalytic anode, where it reacts to produce elemental sulfur, protons and electrons. The protons pass through the membrane from the anode chamber to the cathode chamber. An oxygen-containing gas is passed through the cathode chamber to contact the catalytic cathode, where it reacts with protons and electrons to produce water or steam. During the process, both the anode chamber and cathode chamber are maintained at a temperature of at least 120° C. and an elevated pressure sufficient to keep the membrane moist. Sulfur is obtained in liquid or vapor form and is removed from the anode chamber while water or steam is removed from the cathode chamber. An electric current can be withdrawn from the anode and cathode. The cell can also be operated in the electrolysis mode to produce sulfur and hydrogen.
摘要翻译： 本发明涉及使用在固体质子传导膜的一侧具有阳极室和膜的另一侧上的阴极室的电解槽将气相电化学氧化成硫和水或蒸汽的方法。 该方法包括以下步骤：使含有H 2 S的气体通过阳极室与催化阳极接触，在该催化阳极反应产生元素硫，质子和电子。 质子通过膜从阳极室传递到阴极室。 含氧气体通过阴极室与催化阴极接触，在该催化阴极与质子和电子反应产生水或蒸汽。 在该过程中，阳极室和阴极室都保持在至少120℃的温度和足以使膜保持湿润的升高的压力。 硫以液体或蒸气形式获得，并从阳极室中取出，同时从阴极室除去水或蒸汽。 可以从阳极和阴极抽出电流。 电池也可以在电解模式下操作以产生硫和氢。
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公开(公告)号：US20100196242A1
公开(公告)日：2010-08-05
申请号：US12600807
申请日：2008-05-19
CPC分类号： H01M8/0618 , C01B3/02 , H01M8/04216 , H01M8/065 , Y02E60/364
摘要： A method of forming hydrogen gas comprises the steps of providing a reactor and providing a hydrogen-generating composition to the reactor. The hydrogen-generating composition consists essentially of a borohydride component and a glycerol component. The borohydride, e.g. sodium borohydride, and glycerol components are present in a generally three (3) to four (4) stoichiometric ratio, prior to reaction. The borohydride component has hydrogen atoms and the glycerol component has hydroxyl groups with hydrogen atoms. The method further comprises the step of reacting the borohydride component with the glycerol component thereby converting substantially all of the hydrogen atoms present in the borohydride component and substantially all of the hydrogen atoms present in the hydroxyl groups of the glycerol component to form the hydrogen gas. The reaction between the borohydride component and the glycerol component is an alcoholysis reaction. Reactors and reaction systems employing the method of the present invention are also described.
摘要翻译： 形成氢气的方法包括提供反应器并向反应器提供产氢组合物的步骤。 产氢组合物基本上由硼氢化物组分和甘油组分组成。 硼氢化钠，例如 硼氢化钠和甘油组分在反应之前通常以三（3）至四（4）的化学计量比存在。 硼氢化物组分具有氢原子，甘油组分具有氢原子的羟基。 该方法还包括使硼氢化物组分与甘油组分反应的步骤，从而将存在于硼氢化物组分中的基本上所有的氢原子和存在于甘油组分的羟基中的基本上所有氢原子转化成氢气。 硼氢化物组分和甘油组分之间的反应是醇解反应。 还描述了采用本发明方法的反应器和反应系统。
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公开(公告)号：US20090086025A1
公开(公告)日：2009-04-02
申请号：US12134621
申请日：2008-06-06
申请人： Yan Ngu , John Zabriskie, JR. , Max Walter Saelzer , Rex Hodge , James Braun , Walter Pierce, III , Thomas J. Pavlik , Jeffrey R. Pierce , Vesna Stanic , Daniel Agusto Betts , Michel Fuchs
发明人： Yan Ngu , John Zabriskie, JR. , Max Walter Saelzer , Rex Hodge , James Braun , Walter Pierce, III , Thomas J. Pavlik , Jeffrey R. Pierce , Vesna Stanic , Daniel Agusto Betts , Michel Fuchs
IPC分类号： H04N7/18
CPC分类号： H01M8/065 , C01B3/32 , C01B3/323 , C01B2203/066 , C01B2203/1047 , C01B2203/1064 , C01B2203/107 , G08B13/19636 , H01M8/04216 , H01M2008/1095 , H01M2250/30 , H04N5/23241 , Y02B90/18
摘要： A remote surveillance system (the system) of the present invention is designed to have a long independent operation, portability, and wireless transmission of digital data from any location worldwide. The system includes a hybrid power element having novel hydrogen storage and generation device, light weight polymer electrolyte membrane (PEM) fuel cell, and the low power and low weight electronics. The system also includes multiple day/night cameras, motion detector, global positioning system (GPS), and wireless module. The system is packed in a back pack case and is easily carried between multiple locations due to low weight and compacts size.
摘要翻译： 本发明的远程监视系统（系统）被设计为具有来自世界各地的数字数据的长独立操作，便携性和无线传输。 该系统包括具有新型氢存储和发电装置，重量轻的聚合物电解质膜（PEM）燃料电池和低功率和低重量电子装置的混合动力元件。 该系统还包括多个日夜相机，运动检测器，全球定位系统（GPS）和无线模块。 该系统包装在背包箱中，并且由于重量轻和紧凑尺寸而容易携带在多个位置之间。
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公开(公告)号：US08609054B2
公开(公告)日：2013-12-17
申请号：US12600807
申请日：2008-05-19
CPC分类号： H01M8/0618 , C01B3/02 , H01M8/04216 , H01M8/065 , Y02E60/364
摘要： A method of forming hydrogen gas comprises the steps of providing a reactor and providing a hydrogen-generating composition to the reactor. The hydrogen-generating composition consists essentially of a borohydride component and a glycerol component. The borohydride, e.g. sodium borohydride, and glycerol components are present in a generally three (3) to four (4) stoichiometric ratio, prior to reaction. The borohydride component has hydrogen atoms and the glycerol component has hydroxyl groups with hydrogen atoms. The method further comprises the step of reacting the borohydride component with the glycerol component thereby converting substantially all of the hydrogen atoms present in the borohydride component and substantially all of the hydrogen atoms present in the hydroxyl groups of the glycerol component to form the hydrogen gas. The reaction between the borohydride component and the glycerol component is an alcoholysis reaction. Reactors and reaction systems employing the method of the present invention are also described.
摘要翻译： 形成氢气的方法包括提供反应器并向反应器提供产氢组合物的步骤。 产氢组合物基本上由硼氢化物组分和甘油组分组成。 硼氢化钠，例如 硼氢化钠和甘油组分在反应之前通常以三（3）至四（4）的化学计量比存在。 硼氢化物组分具有氢原子，甘油组分具有氢原子的羟基。 该方法还包括使硼氢化物组分与甘油组分反应的步骤，从而将存在于硼氢化物组分中的基本上所有的氢原子和基本上全部存在于甘油组分的羟基中的氢原子转化成氢气。 硼氢化物组分和甘油组分之间的反应是醇解反应。 还描述了采用本发明方法的反应器和反应系统。
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公开(公告)号：US08455152B2
公开(公告)日：2013-06-04
申请号：US12603655
申请日：2009-10-22
申请人： Vesna Stanic
发明人： Vesna Stanic
IPC分类号： H01M8/10
CPC分类号： H01M8/0223 , H01M8/0256 , H01M8/0258 , H01M8/0267 , H01M8/0271 , H01M8/0297 , H01M8/1004 , H01M8/241 , H01M8/2457 , H01M8/2483 , H01M2008/1095 , Y10T156/10
摘要： An integrated PEM fuel cell includes bipolar plate assemblies that utilize fiber groups that extend from the surfaces of gas impermeable plates to terminate in uncoated tips facing adjacent tips to form anodes and cathodes of an MEA assembly. The catalyst support and catalyst can be applied to the tips as beads or thin layers and joined with a membrane. The assembly can use a unified seal and include collector plates at the ends of the stacks, using similar fiber construction.
摘要翻译： 集成的PEM燃料电池包括双极板组件，该双极板组件利用从不透气板的表面延伸的纤维团，以终止面向相邻尖端的未涂覆的尖端，以形成MEA组件的阳极和阴极。 催化剂载体和催化剂可以作为珠粒或薄层施用于尖端并与膜结合。 组件可以使用统一的密封，并且使用类似的纤维结构在堆叠的端部包括收集板。
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公开(公告)号：US20090123784A1
公开(公告)日：2009-05-14
申请号：US12210726
申请日：2008-09-15
申请人： Thomas J. Pavlik , Hodge Rex , Jeffrey R. Pierce , James Braun , Walter Pierce, III , Vesna Stanic
发明人： Thomas J. Pavlik , Hodge Rex , Jeffrey R. Pierce , James Braun , Walter Pierce, III , Vesna Stanic
IPC分类号： H01M8/24
CPC分类号： H01M8/2485 , H01M8/2415 , H01M8/242 , H01M2008/1095 , Y02P70/56
摘要： The invention relates to the design and manufacturing of a symmetrical polymer electrolyte fuel cell (the cell module) having two cells arranged in mirror symmetry with respect to a central plane of a non conductive fuel manifold. The symmetrical dual cell configuration allows application of adhesive seals for the innermost fuel electrodes. These seals are formed by gluing two membrane electrode assemblies to the opposing faces of the central manifold. The cell module employed as an array of individual modules, or combined into planar or stacked fuel cell configurations.
摘要翻译： 本发明涉及一种对称聚合物电解质燃料电池（电池模块）的设计和制造，其具有相对于非导电燃料歧管的中心平面以镜面对称的方式布置的两个电池。 对称双电池配置允许对最内燃料电极施加粘合剂密封。 这些密封件通过将两个膜电极组件粘合到中央歧管的相对表面而形成。 电池模块用作单个模块的阵列，或组合成平面或堆叠的燃料电池配置。
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