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1.发明授权
公开(公告)号：US4218569A
公开(公告)日：1980-08-19
申请号：US886366
申请日：1978-03-14
摘要： Mixed hydrocarbons of predominantly four carbon atoms each are subjected to etherification with methanol, to make ether from the tertiary olefin in the mixture; the unreacted hydrocarbons, after separation from the ether by distillation, are contaminated with methanol which is removed by absorption or extraction with a glycol before the hydrocarbons are subjected to further processing in which the methanol is detrimental.
摘要翻译： 主要有四个碳原子的混合烃各自用甲醇进行醚化，从混合物中的叔烯烃中制得乙醚; 在通过蒸馏从乙醚中分离出来之后，未反应的烃被甲醇污染，甲醇被吸收或用二醇萃取除去，然后烃进一步加工，其中甲醇是有害的。
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公开(公告)号：US4204077A
公开(公告)日：1980-05-20
申请号：US948072
申请日：1978-10-02
摘要： In the processing of olefinic hydrocarbon mixtures containing isobutylene and isoamylene which are etherified with methanol to obtain higher octane components, unreacted methanol is removed from the etherified mixture by contact with a separate liquid glycol phase before unreacted hydrocarbons, substantially free of methanol, are distilled from the etherified mixture for further catalytic processing in which methanol is deleterious to the catalyst.
摘要翻译： 在含有异丁烯和异戊烯的烯烃混合物的处理中，其与甲醇醚化以获得较高的辛烷成分，通过与单独的液体二醇相接触，从醚化的混合物中除去未反应的甲醇，在将未反应的烃（基本上不含甲醇）从 用于进一步催化加工的醚化混合物，其中甲醇对催化剂有害。
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公开(公告)号：US4193770A
公开(公告)日：1980-03-18
申请号：US905903
申请日：1978-05-15
摘要： A process for preparing, from tertiary olefin containing hydrocarbon fractions, a hydrocarbon fraction containing tertiaryamyl methyl ether, the process achieving high conversion of 2-methyl butenes to the ether by etherification with methanol after adequate separation of the 2-methyl butenes from other tertiary olefins, the improved conversion being achieved by separating unreacted 2-methyl butenes from etherified material and recycling them for further reaction.
摘要翻译： 一种由含叔烃的烃馏分制备含有叔戊基甲基醚的烃馏分的方法，该方法通过在将甲基异丁烯从其它叔烯烃充分分离后，通过甲醇醚化获得高的2-甲基丁烯转化为醚 通过从醚化物质中分离出未反应的2-甲基丁烯并将其再循环以进一步反应来实现改进的转化。
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