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1.发明授权Metal complexation of 1-acyldipyrromethanes and porphyrins formed therefrom 失效由此形成的1-酰基二吡咯烷和卟啉的金属络合公开(公告)号：US07323561B2
公开(公告)日：2008-01-29
申请号：US11020901
申请日：2004-12-23
申请人： Jonathan S. Lindsey , Kannan Muthukumaran , Duddu S. Sharada , Ana Z. Muresan , W. Justin Youngblood
发明人： Jonathan S. Lindsey , Kannan Muthukumaran , Duddu S. Sharada , Ana Z. Muresan , W. Justin Youngblood
IPC分类号： C07B47/00
CPC分类号： C07D487/22
摘要： A first aspect of the invention is a method of making a porphyrin-metal complex, comprising: (a) providing a first reagent selected from the group consisting of 1-acyldipyrromethanes, 1-acyldipyrrins, dipyrromethane-1-carbinols 1,9-diacyldipyrromethanes and 1,9-diacyldipyrrins; and then (b) condensing the first reagent with either itself (in the case of 1-acyldipyrromethanes, 1-acyldipyrrins, and dipyrromethane-1-carbinols) or a dipyrromethane (in the case of 1,9-diacyldipyrromethanes and 1,9-diacyldipyrrins) in a reaction mixture comprising a solvent and a second reagent selected from the group consisting of palladium and copper complexes to produce the porphyrin-metal complex (with the metal being palladium or copper). In preferred embodiments of the foregoing, the reaction mixture further comprises a base such as KOH or NaH.
摘要翻译： 本发明的第一方面是一种制备卟啉金属络合物的方法，其包括：（a）提供选自1-酰基二吡咯烷，1-酰基二吡啶，二吡咯烷-1-甲醇1,9-二酰基二吡咯烷的第一试剂 和1,9-二酰基二吡啶; 然后（b）将第一试剂与其自身（在1-酰基二吡咯烷，1-酰基二吡啶和双吡咯烷-1-甲醇）的情况下缩合，或者将二吡咯烷烃（在1,9-二酰基二吡咯烷和1.9- 二酰基二吡啶）在包含溶剂和选自钯和铜络合物的第二试剂的反应混合物中以产生卟啉金属络合物（金属为钯或铜）。 在前述的优选实施方案中，反应混合物还包含碱如KOH或NaH。
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2.发明申请SUBSTITUTED BENZAZOLOPORPHYRAZINES FOR POLYMERIZATION AND SURFACE ATTACHMENT AND ARTICLES FORMED THEREFROM 审中-公开用于聚合和表面附着的取代的苯并唑磷腈和其形成的制品公开(公告)号：US20120101243A1
公开(公告)日：2012-04-26
申请号：US13329523
申请日：2011-12-19
IPC分类号： C08F230/04 , C07D498/22 , C07D513/22 , C07C253/00 , C07D487/04 , C07D235/18 , C07F7/10 , C07D487/22 , C07D517/22
CPC分类号： C09B7/00
摘要： The present invention provides an article of manufacture formed from a substrate and a benzazoloporphyrazine bound to the substrate. The article may take a variety of different forms and may be for example an electrochromic display, a molecular capacitor, a battery, a solar cell, or a molecular memory device. Methods of making such articles, along with compounds, methods and intermediates useful for making such benzazoloporphyrazines, are also described.
摘要翻译： 本发明提供了由底物和与该底物结合的苯并唑并吡嗪形成的制品。 制品可以采用各种不同的形式，并且可以是例如电致变色显示器，分子电容器，电池，太阳能电池或分子存储器件。 还描述了制备这些制品的方法，以及可用于制备这种苯并唑啉吡嗪的化合物，方法和中间体。
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公开(公告)号：US20120004384A1
公开(公告)日：2012-01-05
申请号：US13035157
申请日：2011-02-25
IPC分类号： C08F230/04 , C07C253/14 , C07D235/08 , C07F5/00 , C07F7/10 , C07D487/04 , C07F3/06 , C07D487/22 , C07D235/10
CPC分类号： C09B7/00
摘要： The present invention provides an article of manufacture formed from a substrate and a benzazoloporphyrazine bound to the substrate. The article may take a variety of different forms and may be for example an electrochromic display, a molecular capacitor, a battery, a solar cell, or a molecular memory device. Methods of making such articles, along with compounds, methods and intermediates useful for making such benzazoloporphyrazines, are also described.
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4.发明授权Substituted benzazoloporphyrazines for polymerization and surface attachment and articles formed therefrom 失效用于聚合和表面附着的取代苯并吡喃并吡嗪和由其形成的制品公开(公告)号：US08106393B2
公开(公告)日：2012-01-31
申请号：US13035157
申请日：2011-02-25
IPC分类号： H01L51/00
CPC分类号： C09B7/00
摘要： The present invention provides an article of manufacture formed from a substrate and a benzazoloporphyrazine bound to the substrate. The article may take a variety of different forms and may be for example an electrochromic display, a molecular capacitor, a battery, a solar cell, or a molecular memory device. Methods of making such articles, along with compounds, methods and intermediates useful for making such benzazoloporphyrazines, are also described.
摘要翻译： 本发明提供了由底物和与该底物结合的苯并唑并吡嗪形成的制品。 制品可以采用各种不同的形式，并且可以是例如电致变色显示器，分子电容器，电池，太阳能电池或分子存储器件。 还描述了制备这些制品的方法，以及可用于制备这种苯并唑啉吡嗪的化合物，方法和中间体。
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5.发明授权Substituted benzazoloporphyrazines for polymerization and surface attachment and articles formed therefrom 失效用于聚合和表面附着的取代苯并吡喃并吡嗪和由其形成的制品公开(公告)号：US07919770B2
公开(公告)日：2011-04-05
申请号：US11447219
申请日：2006-06-05
IPC分类号： H01L35/24
CPC分类号： C09B7/00
摘要： The present invention provides an article of manufacture formed from a substrate and a benzazoloporphyrazine bound to the substrate. The article may take a variety of different forms and may be for example an electrochromic display, a molecular capacitor, a battery, a solar cell, or a molecular memory device. Methods of making such articles, along with compounds, methods and intermediates useful for making such benzazoloporphyrazines, are also described.
摘要翻译： 本发明提供了由底物和与该底物结合的苯并唑并吡嗪形成的制品。 制品可以采用各种不同的形式，并且可以是例如电致变色显示器，分子电容器，电池，太阳能电池或分子存储器件。 还描述了制备这些制品的方法，以及可用于制备这种苯并唑啉吡嗪的化合物，方法和中间体。
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公开(公告)号：US20110015388A1
公开(公告)日：2011-01-20
申请号：US11447219
申请日：2006-06-05
IPC分类号： C09B47/04
CPC分类号： C09B7/00
摘要： The present invention provides an article of manufacture formed from a substrate and a benzazoloporphyrazine bound to the substrate. The article may take a variety of different forms and may be for example an electrochromic display, a molecular capacitor, a battery, a solar cell, or a molecular memory device. Methods of making such articles, along with compounds, methods and intermediates useful for making such benzazoloporphyrazines, are also described.
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