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1.发明授权2,9-dipyridyl-1,10-phenanthroline derivatives useful as actinide ligands, method for synthesizing same, and uses thereof 有权可用作锕系配体的2,9-联吡啶-1,10-菲咯啉衍生物及其合成方法及其用途公开(公告)号：US09074266B2
公开(公告)日：2015-07-07
申请号：US14009292
申请日：2012-03-28
申请人： Julia Bisson , Marie-Christine Charbonnel , Nathalie Boubals , Manuel Miguirditchian , Denis Guillaneux , Dominique Guillaumont , Cecile Marie , Didier Dubreuil , Muriel Pipelier , Virginie Blot
发明人： Julia Bisson , Marie-Christine Charbonnel , Nathalie Boubals , Manuel Miguirditchian , Denis Guillaneux , Dominique Guillaumont , Cecile Marie , Didier Dubreuil , Muriel Pipelier , Virginie Blot
CPC分类号： C22B60/0295 , C07D471/04 , C22B3/0035 , C22B60/026 , C22B60/04 , G21C19/42 , G21C19/44 , G21C19/46 , Y02P10/234 , Y02W30/882 , Y02W30/883
摘要： The invention relates to novel compounds useful as ligands of actinides and which meet general formula (I) hereinafter: where: R1 and R2=H, a C1 to C12 hydrocarbon group, a monocyclic aryl or aryl-(C1 to C6)alkyl group; R3, R4, R5 and R6=H; a C1 to C12 hydrocarbon group; a monocyclic aryl or aryl-(C1 to C6)alkyl group; a —NR7R8 or —NR7COR8 group where R7=H, a C1 to C12 hydrocarbon group, a monocyclic aryl or aryl-(C1 to C6)alkyl group, while R8=a C1 to C12 hydrocarbon group, a monocyclic aryl or aryl-(C1 to C6)alkyl group; an —OR9 or —SR9 group where R9=a C1 to C12 hydrocarbon group, a monocyclic C6 aryl or aryl-(C1 to C6)alkyl group. A further subject of the invention is a method for synthesizing these compounds and the uses thereof.
摘要翻译： 本发明涉及可用作锕系配体的新化合物，其符合以下通式（I）：其中：R1和R2 = H，C1至C12烃基，单环芳基或芳基 - （C1至C6）烷基; R3，R4，R5和R6 = H; C1〜C12烃基; 单环芳基或芳基 - （C1-C6）烷基; 其中R7 = H，C1-C12烃基，单环芳基或芳基 - （C1-C6）烷基的-NR7R8或-NR7COR8基团，而R8 = C1-C12烃基，单环芳基或芳基 - （ C1〜C6）烷基; 其中R9 = C1-C12烃基，单环C6芳基或芳基 - （C1-C6）烷基的-OR9或-SR9基团。 本发明的另一个主题是合成这些化合物的方法及其用途。
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2.发明申请2,9-DIPYRIDYL-1,10-PHENANTHROLINE DERIVATIVES USEFUL AS ACTINIDE LIGANDS, METHOD FOR SYNTHESIZING SAME, AND USES THEREOF 有权用作丙二酸配位体的2,9-二吡啶-1,10-苯并呋喃衍生物，其合成方法及其用途公开(公告)号：US20140030172A1
公开(公告)日：2014-01-30
申请号：US14009292
申请日：2012-03-28
申请人： Julia Bisson , Marie-Christine Charbonnel , Nathalie Boubals , Manuel Miguirditchian , Denis Guillaneux , Dominique Guillaumont , Cecile Marie , Didier Dubreuil , Muriel Pipelier , Virginie Blot
发明人： Julia Bisson , Marie-Christine Charbonnel , Nathalie Boubals , Manuel Miguirditchian , Denis Guillaneux , Dominique Guillaumont , Cecile Marie , Didier Dubreuil , Muriel Pipelier , Virginie Blot
IPC分类号： C22B60/02 , C22B60/04 , C07D471/04
CPC分类号： C22B60/0295 , C07D471/04 , C22B3/0035 , C22B60/026 , C22B60/04 , G21C19/42 , G21C19/44 , G21C19/46 , Y02P10/234 , Y02W30/882 , Y02W30/883
摘要： The invention relates to novel compounds useful as ligands of actinides and which meet general formula (I) hereinafter: where: R1 and R2═H, a C1 to C12 hydrocarbon group, a monocyclic aryl or aryl-(C1 to C6)alkyl group; R3, R4, R5 and R6═H; a C1 to C12 hydrocarbon group; a monocyclic aryl or aryl-(C1 to C6)alkyl group; a —NR7R8 or —NR7COR8 group where R7═H, a C1 to C12 hydrocarbon group, a monocyclic aryl or aryl-(C1 to C6)alkyl group, whilst R8=a C1 to C12 hydrocarbon group, a monocyclic aryl or aryl-(C1 to C6)alkyl group; an —OR9 or —SR9 group where R9=a C1 to C12 hydrocarbon group, a monocyclic C6 aryl or aryl-(C1 to C6)alkyl group. A further subject of the invention is a method for synthesizing these compounds and the uses thereof.
摘要翻译： 本发明涉及可用作锕系配体的新化合物，其符合以下通式（I）：其中：R1和R2 = H，C1至C12烃基，单环芳基或芳基 - （C1至C6）烷基; R3，R4，R5和R6 = H; C1〜C12烃基; 单环芳基或芳基 - （C1-C6）烷基; 其中R7 = H，C1-C12烃基，单环芳基或芳基 - （C1-C6）烷基的-NR7R8或-NR7COR8基团，而R8 = C1-C12烃基，单环芳基或芳基 - （ C1〜C6）烷基; 其中R9 = C1-C12烃基，单环C6芳基或芳基 - （C1-C6）烷基的-OR9或-SR9基团。 本发明的另一个主题是合成这些化合物的方法及其用途。
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3.发明授权公开(公告)号：US08709129B2
公开(公告)日：2014-04-29
申请号：US13386340
申请日：2010-07-16
IPC分类号： C22B60/00 , C07D401/14
CPC分类号： C07D401/14 , C22B3/0035 , G21C19/46 , Y02P10/234 , Y02W30/883
摘要： The invention relates to novel compounds which are useful as ligands of actinides, to the synthesis of these compounds and to their uses.These compounds fit the general formula (I) hereafter: wherein R1 and R2, either identical or different, represent H, a linear or branched, saturated or unsaturated C1-C12 hydrocarbon group, a phenyl, benzyl, diphenyl or tolyl group; R3 represents H, a linear or branched, saturated or unsaturated C1-C12 hydrocarbon group, a phenyl, tolyl or linear or branched C1-C12 alkoxy group; while R4 represents H, a linear or branched, saturated or unsaturated C1-C12 hydrocarbon group, a phenyl or tolyl group. Field of applications: the processing of used nuclear fuels via a hydrometallurgical route.
摘要翻译： 本发明涉及可用作锕系元素配体，合成这些化合物及其应用的新化合物。 这些化合物适合下文通式（I）：其中R1和R2相同或不同，代表H，直链或支链，饱和或不饱和的C1-C12烃基，苯基，苄基，二苯基或甲苯基; R 3表示H，直链或支链饱和或不饱和的C 1 -C 12烃基，苯基，甲苯基或直链或支链C 1 -C 12烷氧基; 而R 4表示H，直链或支链，饱和或不饱和的C 1 -C 12烃基，苯基或甲苯基。 应用领域：通过湿法冶金途径处理使用过的核燃料。
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4.发明申请COMPOUNDS USEFUL AS LIGANDS OF ACTINIDES, THEIR SYNTHESIS AND THEIR USES 有权有用的化合物作为丙酰胺的配体，它们的合成及其用途公开(公告)号：US20120186396A1
公开(公告)日：2012-07-26
申请号：US13386340
申请日：2010-07-16
IPC分类号： C22B60/00 , C07D401/14
CPC分类号： C07D401/14 , C22B3/0035 , G21C19/46 , Y02P10/234 , Y02W30/883
摘要： The invention relates to novel compounds which are useful as ligands of actinides, to the synthesis of these compounds and to their uses.These compounds fit the general formula (I) hereafter: wherein R1 and R2, either identical or different, represent H, a linear or branched, saturated or unsaturated C1-C12 hydrocarbon group, a phenyl, benzyl, diphenyl or tolyl group; R3 represents H, a linear or branched, saturated or unsaturated C1-C12 hydrocarbon group, a phenyl, tolyl or linear or branched C1-C12 alkoxy group; while R4 represents H, a linear or branched, saturated or unsaturated C1-C12 hydrocarbon group, a phenyl or tolyl group.Field of applications: the processing of used nuclear fuels via a hydrometallurgical route.
摘要翻译： 本发明涉及可用作锕系元素配体，合成这些化合物及其应用的新化合物。 这些化合物适合下文通式（I）：其中R1和R2相同或不同，代表H，直链或支链，饱和或不饱和的C1-C12烃基，苯基，苄基，二苯基或甲苯基; R 3表示H，直链或支链饱和或不饱和的C 1 -C 12烃基，苯基，甲苯基或直链或支链C 1 -C 12烷氧基; 而R 4表示H，直链或支链，饱和或不饱和的C 1 -C 12烃基，苯基或甲苯基。 应用领域：通过湿法冶金途径处理使用过的核燃料。
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