公开(公告)号：US11339085B2

公开(公告)日：2022-05-24

申请号：US16073131

申请日：2017-11-21

Applicant: JUSHI GROUP CO., LTD.

Inventor： Guorong Cao ,  Lin Zhang ,  Wenzhong Xing ,  Xiucheng Hong ,  Zhonghua Yao

IPC: C03C13/00 ,  C03C3/087 ,  C03C3/112

Abstract: A composition for producing a glass fiber, including the following components with corresponding percentage amounts by weight: SiO2: 57.4-60.9%; Al2O3: greater than 17% and less than or equal to 19.8%; MgO: greater than 9% and less than or equal to 12.8%; CaO: 6.4-11.8%; SrO: 0-1.6%; Na2O+K2O: 0.1-1.1%; Fe2O3: 0.05-1%; TiO2: lower than 0.8%; and SiO2+Al2O3: lower than or equal to 79.4%. The total weight percentage of the above components in the composition is greater than 99%. The weight percentage ratio of Al2O3+MgO to SiO2 is between 0.43 and 0.56, and the weight percentage ratio of CaO+MgO to SiO2+Al2O3 is greater than 0.205. The composition can significantly increase the glass modulus, effectively reduce the glass crystallization rate, secure a desirable temperature range (ΔT) for fiber formation and enhance the refinement of molten glass, thus making it particularly suitable for high performance glass fiber production with refractory-lined furnaces.

公开(公告)号：US10329189B2

公开(公告)日：2019-06-25

申请号：US15739110

申请日：2016-06-16

Applicant: JUSHI GROUP CO., LTD.

Inventor： Yuqiang Zhang ,  Guorong Cao ,  Lin Zhang ,  Wenzhong Xing ,  Guijiang Gu

IPC: C03C3/095 ,  C03C13/00

Abstract: A high-modulus glass fiber composition, and a glass fiber and a composite material therefrom. The glass fiber composition comprises the following components in weight percentage: SiO2 55.7 to 58.9%, Al2O3 15 to 19.9%, Y2O3 0.1 to 4.3%, La2O3 less than or equal to 1.5%, CeO2 less than or equal to 1.2%, CaO 6 to 10%, MgO 9.05 to 9.95%, SrO less than or equal to 2%, Li2O+Na2O+K2O less than or equal to 0.99%, Li2O less than or equal to 0.65%, Fe2O3 less than 1%, TiO2 0.1 to 1.5%; wherein, the range of the weight percentage ratio C1=Y2O3/(Y2O3+La2O3+CeO2) is greater than 0.6. The composition can greatly improve the elastic modulus of glass, significantly reduce liquidus temperature and forming temperature of the glass, greatly reduce the crystallization rate of molten glass and bubble amount under the same conditions, and therefore is more suitable for large-scale tank furnace production of high-modulus fiberglass with low bubble amount.

公开(公告)号：US10239781B2

公开(公告)日：2019-03-26

申请号：US15738563

申请日：2016-03-07

Applicant: JUSHI GROUP CO., LTD.

Inventor： Yuqiang Zhang ,  Guorong Cao ,  Lin Zhang ,  Wenzhong Xing

IPC: C03C13/00 ,  C03C3/095

Abstract: The present invention provides a high-modulus glass fiber composition, a glass fiber and a composite material therefrom. The glass fiber composition comprises the following components expressed as percentage by weight: 55-64% SiO2, 13-24% Al2O3, 0.1-6% Y2O3, 3.4-10.9% CaO, 8-14% MgO, lower than 22% CaO+MgO+SrO, lower than 2% Li2O+Na2O+K2O, lower than 2% TiO2, lower than 1.5% Fe2O3, 0-1.2% La2O3, wherein the range of the weight percentage ratio C1=(Li2O+Na2O+K2O)/(Y2O3+La2O3) is greater than 0.26. Said composition can significantly increase the glass elastic modulus, effectively inhibit the crystallization tendency of glass, decrease the liquidus temperature, secure a desirable temperature range (ΔT) for fiber formation and enhance the fining of molten glass, thus making it particularly suitable for production of high-modulus glass fiber with refractory-lined furnaces.

公开(公告)号：US10696581B2

公开(公告)日：2020-06-30

申请号：US16269379

申请日：2019-02-06

Applicant: JUSHI GROUP CO., LTD.

Inventor： Yuqiang Zhang ,  Guorong Cao ,  Lin Zhang ,  Wenzhong Xing

IPC: C03C13/00 ,  C03C3/095

Abstract: The present invention provides a high-modulus glass fiber composition, a glass fiber and a composite material therefrom. The glass fiber composition comprises the following components expressed as percentage by weight: 55-64% SiO2, 13-24% Al2O3, 0.1-6% Y2O3, 3.4-10.9% CaO, 8-14% MgO, lower than 22% CaO+MgO+SrO, lower than 2% Li2O+Na2O+K2O, lower than 2% TiO2, lower than 1.5% Fe2O3, 0-1.2% La2O3, wherein the range of the weight percentage ratio C1=(Li2O+Na2O+K2O)/(Y2O3+La2O3) is greater than 0.26. Said composition can significantly increase the glass elastic modulus, effectively inhibit the crystallization tendency of glass, decrease the liquidus temperature, secure a desirable temperature range (ΔT) for fiber formation and enhance the fining of molten glass, thus making it particularly suitable for production of high-modulus glass fiber with refractory-lined furnaces.

公开(公告)号：US10590027B2

公开(公告)日：2020-03-17

申请号：US16081350

申请日：2016-03-21

Applicant: JUSHI GROUP CO., LTD.

Inventor： Yuqiang Zhang ,  Guorong Cao ,  Lin Zhang ,  Wenzhong Xing ,  Guijiang Gu

IPC: C03C3/095 ,  C03C13/00 ,  C03C3/085 ,  C03C3/087

Abstract: Provided are a high performance glass fiber composition, and a glass fiber and a composite material thereof. The content, given in weight percentage, of each component of the glass fiber composition is as follows: 52-67% of SiO2, 12-24% of Al2O3, 0.05-4.5% of Sm2O3+Gd2O3, less than 2% of Li2O+Na2O+K2O, 10-24% of CaO+MgO+SrO, less than 16% of CaO, less than 13% of MgO, less than 3% of TiO2, and less than 1.5% of Fe2O3. The composition significantly improves the mechanical properties and the thermal stability of glass, significantly reduces the liquidus temperature and forming temperature of glass, and under equal conditions, significantly reduces the crystallisation rate of glass. The composition is particularly suitable for the tank furnace production of a high performance glass fiber having excellent thermal stability.

公开(公告)号：US10287206B2

公开(公告)日：2019-05-14

申请号：US15851759

申请日：2017-12-22

Applicant: JUSHI GROUP CO., LTD.

Inventor： Guorong Cao ,  Lin Zhang ,  Wenzhong Xing ,  Guijiang Gu

IPC: C03C13/00 ,  C03C3/087

Abstract: A composition of matter, including the following components expressed as percentage by weight: SiO2, 58-60.4%; Al2O3, 14-16.5%; CaO, 14.1-16.5%; MgO, 6-8.2%; Li2O, 0.01-0.4%; Na2O+K2O, less than 1.15%; K2O, greater than 0.5%; TiO2, less than 1.5%; and Fe2O3, less than 1%. The range of the weight percentage ratio CaO/MgO is greater than 2 and less than or equal to 2.4. A glass fiber prepared from the composition is also provided.

公开(公告)号：US10207949B2

公开(公告)日：2019-02-19

申请号：US15821710

申请日：2017-11-22

Applicant: JUSHI GROUP CO., LTD.

Inventor： Lin Zhang ,  Wenzhong Xing ,  Guorong Cao ,  Guijiang Gu

IPC: C03C13/00 ,  C03C3/095 ,  C03C3/087

Abstract: A composition for producing a glass fiber, including the following components with corresponding percentage amounts by weight: SiO2: 57.1-61.4%; Al2O3: 17.1-21%; MgO: 10.1-14.5%; Y2O3: 1.1-4.3%; CaO:

公开(公告)号：US09758423B2

公开(公告)日：2017-09-12

申请号：US15122127

申请日：2015-01-20

Applicant: JUSHI GROUP CO., LTD.

Inventor： Guorong Cao ,  Wenzhong Xing ,  Lin Zhang ,  Guijiang Gu

IPC: C03C13/00 ,  C03C3/087 ,  B32B17/04

CPC classification number: C03C3/087 ,  B32B17/04 ,  C03C13/00

Abstract: The present invention provides a glass fiber composition, a glass fiber and a composite material therefrom. The glass fiber composition comprises the following components expressed as percentage by weight: 58-64% SiO2, 14-19% Al203, ≧8.8% and

公开(公告)号：US11919802B2

公开(公告)日：2024-03-05

申请号：US16979089

申请日：2019-10-30

Applicant: JUSHI GROUP CO., LTD.

Inventor： Guorong Cao ,  Wenzhong Xing ,  Lin Zhang ,  Zhonghua Yao ,  Hongya Zhou

IPC: C03C13/00 ,  C03C3/118 ,  C03C4/16 ,  C03C13/06 ,  H05K1/03

CPC classification number: C03C13/00 ,  C03C3/118 ,  C03C4/16 ,  C03C13/06 ,  H05K1/0306 ,  C03C2204/00 ,  C03C2213/00 ,  H05K2201/029

Abstract: An electronic-grade glass fiber composition includes the following components with corresponding amounts by weight percentages 51.0-57.5% SiO2, 11.0-17.0% Al2O3, >4.5% and ≤6.4% B2O3, 19.5-24.8% CaO, 0.1-1.9% MgO, 0.05-1.2% R2O=Na2O+K2O+Li2O, 0.05-0.8% Fe2O3, 0.01-1.0% TiO2, and 0.01-1.0% F2. A weight percentage ratio C1=SiO2/B2O3 is 8.1-12.7, a weight percentage ratio C2=B2O3/(R2O+MgO) is 1.7-6.3, and a total weight percentage of the above components is greater than or equal to 99%.

公开(公告)号：US11884575B2

公开(公告)日：2024-01-30

申请号：US17721958

申请日：2022-04-15

Applicant: JUSHI GROUP CO., LTD.

Inventor： Guorong Cao ,  Lin Zhang ,  Wenzhong Xing ,  Xiucheng Hong ,  Zhonghua Yao

IPC: C03C13/00 ,  C03C3/087 ,  C03C3/112

CPC classification number: C03C13/00 ,  C03C3/087 ,  C03C3/112 ,  C03C2213/00

Abstract: A composition for producing a glass fiber, including the following components with corresponding percentage amounts by weight: SiO2: 57.4-60.9%; Al2O3: greater than 17% and less than or equal to 19.8%; MgO: greater than 9% and less than or equal to 12.8%; CaO: 6.4-11.8%; SrO: 0.1-1.5%; Na2O+K2O: 0.1-1.1%; Fe2O3: 0.05-1%; TiO2: lower than 0.8%; and SiO2+Al2O3: lower than or equal to 79.4%. The total weight percentage of the above components in the composition is greater than 99%. The weight percentage ratio of Al2O3+MgO to SiO2 is between 0.43 and 0.56, and the weight percentage ratio of CaO+MgO to SiO2+Al2O3 is greater than 0.205. The composition can significantly increase the glass modulus, effectively reduce the glass crystallization rate, secure a desirable temperature range (ΔT) for fiber formation and enhance the refinement of molten glass, thus making it particularly suitable for high performance glass fiber production with refractory-lined furnaces.