公开(公告)号：US20150374612A1

公开(公告)日：2015-12-31

申请号：US14767194

申请日：2013-11-11

Applicant: KAO CORPORATION

Inventor： Satomi NAKAZONO ,  Ryosuke FUJII

IPC: A61K8/893 ,  A45D7/06 ,  A61Q5/06 ,  C08G77/445 ,  C08G77/442

CPC classification number: A61K8/893 ,  A45D7/06 ,  A61K2800/805 ,  A61Q5/06 ,  C08F283/12 ,  C08F290/148 ,  C08G77/442 ,  C08G77/445

Abstract: The present invention relates to an organopolysiloxane graft polymer including an organopolysiloxane segment as a main chain thereof and an unsaturated monomer-derived copolymer segment containing a repeating unit derived from an unsaturated monomer containing a carboxylic acid or a carboxylic acid salt as a side chain thereof, in which a content of the organopolysiloxane segment in the organopolysiloxane graft polymer is 35 to 59% by mass, a content of the repeating unit derived from the unsaturated monomer containing a carboxylic acid or a carboxylic acid salt in the organopolysiloxane graft polymer is 4 to 17% by mass, and a content of a repeating unit derived from an unsaturated monomer whose homopolymer has a glass transition point of not lower than 150° C. (except for the unsaturated monomer containing a carboxylic acid or a carboxylic acid salt) in the organopolysiloxane graft polymer is not more than 14% by mass, and a number-average molecular weight of the organopolysiloxane segment is not less than 8,000 and not more than 200,000.

Abstract translation: 本发明涉及包含有机聚硅氧烷链段作为其主链的有机聚硅氧烷接枝聚合物和含有源自含羧酸或羧酸盐作为侧链的不饱和单体的重复单元的不饱和单体衍生的共聚物链段， 有机聚硅氧烷接枝聚合物中的有机聚硅氧烷链段的含量为35〜59质量％，来自有机聚硅氧烷接枝聚合物中含有羧酸或羧酸盐的不饱和单体的重复单元的含量为4〜17 质量％，衍生自均聚物的玻璃化转变点为150℃以上的不饱和单体（除了含有羧酸或羧酸盐的不饱和单体除外）的重复单元的含量在有机聚硅氧烷中 接枝聚合物的有机聚硅氧烷的数均分子量不超过14质量％ 部分不低于8000，不超过20万。

公开(公告)号：US20150297498A1

公开(公告)日：2015-10-22

申请号：US14648947

申请日：2013-11-05

Applicant: KAO CORPORATION

Inventor： Chihiro OHBA ,  Shuichiro KOBARU ,  Tomoka MAEKAWA ,  Satomi NAKAZONO

IPC: A61K8/89 ,  A61Q5/06 ,  C08G77/42

CPC classification number: A61K8/89 ,  A61K8/895 ,  A61Q5/06 ,  C08F220/34 ,  C08F226/06 ,  C08F283/12 ,  C08G77/388 ,  C08G77/42 ,  C08G77/442

Abstract: The present invention relates to an organopolysiloxane graft polymer including an organopolysiloxane segment as a main chain thereof and an unsaturated monomer-derived polymer segment as a side chain thereof, in which a content of the organopolysiloxane segment in the organopolysiloxane graft polymer is not less than 35% by mass and not more than 70% by mass, and the unsaturated monomer-derived polymer segment contains a repeating unit derived from a nonionic unsaturated monomer having a glass transition temperature Tg of 60° C. or higher (except for a repeating unit derived from an unsaturated monomer containing an amino group) in an amount of not less than 40% by mass and not more than 90% by mass, and further contains a repeating unit derived from a cationic unsaturated monomer in an amount of not less than 10% by mass and not more than 60% by mass.

Abstract translation: 本发明涉及包含作为其主链的有机聚硅氧烷链段和作为侧链的不饱和单体衍生的聚合物链段的有机聚硅氧烷接枝聚合物，其中有机聚硅氧烷接枝聚合物中的有机聚硅氧烷链段的含量不小于35 质量％且不超过70质量％，不饱和单体衍生的聚合物链段含有衍生自玻璃化转变温度Tg为60℃以上的非离子型不饱和单体的重复单元（除了衍生自 由含有氨基的不饱和单体构成）为40质量％以上且90质量％以下，进一步含有来自阳离子不饱和单体的重复单元的量不小于10质量％ 以上60质量％以下。