ENHANCED METAL RECOVERY THROUGH OXIDATION IN LIQUID AND/OR SUPERCRITICAL CARBON DIOXIDE

    公开(公告)号:US20170240434A1

    公开(公告)日:2017-08-24

    申请号:US15419184

    申请日:2017-01-30

    CPC classification number: C01G49/14 C22B1/11 C22B3/12 Y02P10/234 Y02P20/544

    Abstract: Process for enhanced metal recovery from, for example, metal-containing feedstock using liquid and/or supercritical fluid carbon dioxide and a source of oxidation. The oxidation agent can be free of complexing agent. The metal-containing feedstock can be a mineral such as a refractory mineral. The mineral can be an ore with high sulfide content or an ore rich in carbonaceous material. Waste can also be used as the metal-containing feedstock. The metal-containing feedstock can be used which is not subjected to ultrafine grinding. Relatively low temperatures and pressures can be used. The metal-containing feedstock can be fed into the reactor at a temperature below the critical temperature of the carbon dioxide, and an exotherm from the oxidation reaction can provide the supercritical temperature. The oxidant can be added to the reactor at a rate to maintain isothermal conditions in the reactor. Minimal amounts of water can be used as an extractive medium.

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