公开(公告)号：US20150238930A1

公开(公告)日：2015-08-27

申请号：US14192063

申请日：2014-02-27

Applicant: KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS

Inventor： Syed Ahmed M. Said ,  Shakeel Ahmed ,  Najam Ul Qadir

IPC: B01J20/22

CPC classification number: B01J20/226

Abstract: The metal organic framework adsorbent for solar adsorption refrigeration is a nanocomposite made from a metal organic framework matrix having carbon nanotubes incorporated therein. Preferably, the metal organic framework is composed of MIL-100(Fe), and the carbon nanotubes are functionalized with carboxyl (COOH) groups. In order to prepare the metal organic framework adsorbent, carbon nanotubes functionalized with carboxyl (COOH) groups are first added to an aqueous solution of a precursor salt, such as ferric trinitrate nonahydrate (Fe(NO3)3·9H2O), to form a first mixture. The first mixture is then sonicated and a 1,3,5 benzenetricarboxylic acid ligand is added thereto to form a second mixture. The second mixture is then sonicated and heated, and the metal organic framework nanocomposite is separated therefrom, preferably as a powder.

Abstract translation: 用于太阳能吸附制冷的金属有机骨架吸附剂是由其中结合有碳纳米管的金属有机骨架基质制成的纳米复合材料。 优选地，金属有机骨架由MIL-100（Fe）组成，碳纳米管用羧基（COOH）官能化。 为了制备金属有机骨架吸附剂，首先将用羧基（COOH）官能化的碳纳米管加入前体盐如三水硝酸铁九水合物（Fe（NO 3）3·9H 2 O）的水溶液中以形成第一 混合物。 然后将第一混合物超声处理，并向其中加入1,3,5-苯三羧酸配体以形成第二混合物。 然后将第二混合物超声处理并加热，并将金属有机骨架纳米复合材料从其中分离，优选粉末。

公开(公告)号：US09480967B2

公开(公告)日：2016-11-01

申请号：US14192063

申请日：2014-02-27

Applicant: KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS

Inventor： Syed Ahmed M. Said ,  Shakeel Ahmed ,  Najam Ul Qadir

IPC: B01J20/22

CPC classification number: B01J20/226

Abstract: The metal organic framework adsorbent for solar adsorption refrigeration is a nanocomposite made from a metal organic framework matrix having carbon nanotubes incorporated therein. Preferably, the metal organic framework is composed of MIL-100(Fe), and the carbon nanotubes are functionalized with carboxyl (COOH) groups. In order to prepare the metal organic framework adsorbent, carbon nanotubes functionalized with carboxyl (COOH) groups are first added to an aqueous solution of a precursor salt, such as ferric trinitrate nonahydrate (Fe(NO3)3.9H2O), to form a first mixture. The first mixture is then sonicated and a 1,3,5 benzenetricarboxylic acid ligand is added thereto to form a second mixture. The second mixture is then sonicated and heated, and the metal organic framework nanocomposite is separated therefrom, preferably as a powder.

Abstract translation: 用于太阳能吸附制冷的金属有机骨架吸附剂是由其中结合有碳纳米管的金属有机骨架基质制成的纳米复合材料。 优选地，金属有机骨架由MIL-100（Fe）组成，碳纳米管用羧基（COOH）官能化。 为了制备金属有机骨架吸附剂，首先将用羧基（COOH）官能化的碳纳米管加入前体盐如三水硝酸铁九水合物（Fe（NO 3）3·4H 2 O）的水溶液中以形成第一混合物 。 然后将第一混合物超声处理，并向其中加入1,3,5-苯三羧酸配体以形成第二混合物。 然后将第二混合物超声处理并加热，并将金属有机骨架纳米复合材料从其中分离，优选粉末。

公开(公告)号：US11421920B2

公开(公告)日：2022-08-23

申请号：US16394539

申请日：2019-04-25

Applicant: KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS

Inventor： Najam Ul Qadir ,  Syed Ahmed M. Said ,  Rached Ben Mansour

IPC: F25B27/00 ,  H02S40/32 ,  H02S40/44

Abstract: A solar-powered two-bed adsorption chiller which can operate after sunset when the solar radiation intensity becomes zero. Rechargeable solar-powered batteries (SPBs) are connected to a flat-plate solar collector (FPSC). The photoelectric charges are directed from FPSC to a solar charge controller (SCC) which acts as a charge amplifier thus magnifying the total charge before it is finally collected inside the SPB for future use. The SPB is in turn connected to a resistance heating wire (RHW) which is immersed inside the HWST.