Abstract:
The present invention relates to a catalyst for producing 1,1-difluoroethane (HCFC-152a) and producing method thereof. More particularly, it is to provide the catalyst prepared by impregnating palladium on the active carbon pretreated with an aqueous hydrogen fluoride solution and an aqueous hydrogen chloride solution in series and its use in the production of 1,1-difluoroethane (HCFC-142b) by dehydrochlorinating 1,1-difluoro-1-chloroethane at 240-300null C. in the supplying molar ratio of 2-6 (H2/HCFC-142b) with maximizing a selectivity toward the product of HCFC-152a.
Abstract:
A novel refrigerant composition useful as a substitute for HCFC-22, comprising a first constituent of difluoromethane (CH2F2, HFC-32); a second constituent of pentafluoroethane (CHF2CF3, HFC-125); a third constituent of 1,1,1-trifluoroethane (CH3CF3, HFC-143a); a fourth constituent selected from the group consisting of cyclopropane (C3H6, RC-270), 1,1,1,2,3,3,3-heptafluoropropane (CF3CHFCF3, HFC-227ea), 1,1,1,2,2-pentafluoropropane (CH3CF2CF3, HFC-245cb), isobutane (CH(CH3)2CH3, R-600a), octafluorocyclobutane (C4F8, RC-318), 1,1,1,2,3,3-hexafluoropropane (CHF2CHFCF3, HFC-236ea), butane (C4H10, R-600), bis(difluoromethyl)ether (CHF2OCHF2, HFE-134) and pentafluoroethylmethylether (CF3CF2OCH3, HFE-245).