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公开(公告)号：US4086157A
公开(公告)日：1978-04-25
申请号：US677083
申请日：1976-04-15
CPC分类号： C25B11/0484
摘要： A coated valve metal electrode for electrochemical processes, which has (a) an electrode base body of valve metal; (b) a base layer on said valve metal, said base layer comprising an electrically conducting element without valve effect, and (c) a cover layer comprising titanium dioxide and/or tantalum oxide with certain doping and stable oxides.
摘要翻译： 一种用于电化学工艺的涂覆阀金属电极，其具有（a）阀金属的电极基体; （b）所述阀金属上的基层，所述基层包括不具有阀效应的导电元件，和（c）包含具有某些掺杂和稳定氧化物的二氧化钛和/或氧化钽的覆盖层。
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公开(公告)号：US4022679A
公开(公告)日：1977-05-10
申请号：US642384
申请日：1975-12-19
申请人： Konrad Koziol , Karl-Heinz Sieberer , Baptist Zenk
发明人： Konrad Koziol , Karl-Heinz Sieberer , Baptist Zenk
CPC分类号： C25B11/02
摘要： The anode is particularly designed for use at anodic densities D.sub.A greater than 10 kA/m.sup.2, and comprises substantially horizontally extending coated anode segments having a clear spacing of at least 1.5 mm from each other and upwardly extending lateral surfaces. Each segment has an active coated part higher than 5 mm and not exceeding 20 mm, measured from the horizontal undersurface of the anode. The actual active surface of the parts, up to heights of 5 mm, 7.5 mm, 10 mm and 15 mm, respectively, exceeds at least 2.5, 3.33, 4 and 4.7 times, respectively, the projected anode area which latter is the total area bounded by the periphery of the anode. At least half the actual active surface extends upwardly relative to the horizontal base area of the anode.
摘要翻译： 阳极特别设计用于大于10kA / m 2的阳极密度DA，并且包括基本上水平延伸的涂覆阳极段，其具有彼此至少1.5mm的清晰间隔和向上延伸的侧表面。 每个段具有从阳极的水平下表面测量的高于5mm且不超过20mm的活性涂层部分。 部件的实际有效表面分别高达5 mm，7.5 mm，10 mm和15 mm的高度，分别超过投影阳极面积的2.5,3.3,4.4和4.7倍，后者是总面积 由阳极的周边界定。 实际活性表面的至少一半相对于阳极的水平基底区域向上延伸。
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3.发明授权
公开(公告)号：US4003808A
公开(公告)日：1977-01-18
申请号：US573367
申请日：1975-04-30
申请人： Karl-Heinz Sieberer
发明人： Karl-Heinz Sieberer
CPC分类号： C25B15/06
摘要： A method for regulating and controlling the anode current and for avoiding short-circuits between the adjustable anodes and the cathode of an electrolysis cell, wherein by means of an apparatus controlled by a field plate (magnetically controllable resistance), a magnetic diode or a magnetic transistor as sensor, the electrical resistance of which constitutes a measure for the current flowing to an anode or an anode group and, thus, having a nominal value of the resistance for a nominal value of the current, in case there is a deviation of the current from the nominal value the deviation of the electrical resistance of the sensor from the nominal value serves to reset the electrical resistance of the sensor and, thus, also the current of the anode or anode group to the nominal value by adjusting the anode or anode group.
摘要翻译： 一种用于调节和控制阳极电流并避免可调节阳极与电解槽的阴极之间的短路的方法，其中通过由场板（可磁阻的电阻）控制的装置，磁二极管或磁 晶体管作为传感器，其电阻构成流过阳极或阳极组的电流的量度，因此具有电流额定值的电阻的标称值，如果存在偏差 从标称值的电流，传感器的电阻与标称值的偏差用于通过调节阳极或阳极来重置传感器的电阻，从而将阳极或阳极组的电流调整到标称值 组。
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公开(公告)号：US4138510A
公开(公告)日：1979-02-06
申请号：US580222
申请日：1975-05-23
CPC分类号： C25B11/0478
摘要： A valve metal anode, for electrolytical processes, having an electron-active covering layer, is prepared by anchoring electron-activating substances, counteracting passivation of the anode, in a sintered porous carrier layer of valve metal. The carrier layer which is sintered onto the cleaned valve metal base may consist of a powder of the same metal or of the crystallographically similar metal. The infusion of the active substances into the carrier layer can be accomplished by impregnating and drying or baking the active substances, by precipitating them from the vapor phase, galvanically, or from the gaseous phase. The active substances may also be ingredients of the sinter mixture.
摘要翻译： 用于具有电子活性覆盖层的电解方法的阀金属阳极通过将电子活化物质固定在阀金属的烧结多孔载体层中来制备，抵消阳极的钝化。 烧结到清洁的阀金属基底上的载体层可以由相同金属或晶体学上类似的金属的粉末组成。 将活性物质注入载体层可以通过浸渍和干燥或烘焙活性物质，通过从气相，电流或气相中沉淀而实现。 活性物质也可以是烧结混合物的成分。
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公开(公告)号：US3948752A
公开(公告)日：1976-04-06
申请号：US415421
申请日：1973-11-13
CPC分类号： C25B11/0447 , C25B11/0442 , C25B11/0478
摘要： An electrode for electrochemical processes, particularly for the electrolysis processes for manufacturing chlorine, consisting of a metal resistant to the electrolysis medium and of an active cover layer applied thereon and containing the substances causing the electrode process, which substances are compounds of the typePt.sub.x M.sub.y M.sub.z O.sub.2, Pd.sub.x M.sub.y M.sub.z O.sub.2being of rhombohedral crystal structure, and of the typeA.sub.x Pt.sub.3 O.sub.4, A.sub.x Pd.sub.3 O.sub.4which in connection with the other compounds can be regarded as Perowskistructure. On account of the marked non-stoichiometry proper to these compounds, excess electrons occur, resulting in the low electrical resistance which is characteristic for said compounds and which is in the same range as that of some of the metals.
摘要翻译： 用于电化学方法的电极，特别是用于制造氯的电解方法的电极，由对电解介质和施加于其上的活性覆盖层的金属组成，并含有引起电极过程的物质，这些物质是PtxMyMzO2型化合物， PdxMyMzO2为菱形晶体结构，AxPt3O4型，AxPd3O4型与其它化合物相关，可视为Perowskistructure。 由于对这些化合物适当的标记的非化学计量，发生过量电子，导致低电阻，这是所述化合物的特征，并且在与一些金属相同的范围内。
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