公开(公告)号：US07328989B2

公开(公告)日：2008-02-12

申请号：US10845877

申请日：2004-05-13

申请人： Hideo Ohira ,  Yoshito Toyoda ,  Masahito Kato ,  Ryuji Kato ,  Akihiko Taniguchi ,  Kazuma Goto ,  Masaya Fujioka ,  Shunichi Higashiyama

发明人： Hideo Ohira ,  Yoshito Toyoda ,  Masahito Kato ,  Ryuji Kato ,  Akihiko Taniguchi ,  Kazuma Goto ,  Masaya Fujioka ,  Shunichi Higashiyama

IPC分类号： C09D11/00

CPC分类号： C09D11/40

摘要： An ink set for ink-jet recording comprises a pigment ink and a dye ink containing a pigment and a dye as coloring agent, respectively. The pigment ink contains water, a water-soluble organic solvent, and a negatively charged pigment wherein potassium ion and sodium ion have a total ion concentration of not more than 200 ppm, and divalent or multivalent metal ion or ions have a total ion concentration of not more than 10 ppm. The dye ink contains water, a water-soluble organic solvent, and a dye associated with a counter ion of lithium ion wherein potassium ion and sodium ion have a total ion concentration of not more than 400 ppm, and divalent or multivalent metal ion or ions have a total ion concentration of not more than 10 ppm. In the ink set, the pigment and dye inks can be used in combination without complicating a maintenance system.

摘要翻译： 用于喷墨记录的油墨组分别包括颜料油墨和含有颜料和染料作为着色剂的染料油墨。 颜料墨含有水，水溶性有机溶剂和带负电荷的颜料，其中钾离子和钠离子的总离子浓度不大于200ppm，并且二价或多价金属离子或离子的总离子浓度为 不超过10ppm。 染料墨水含有水，水溶性有机溶剂和与锂离子的抗衡离子相关的染料，其中钾离子和钠离子的总离子浓度不大于400ppm，二价或多价金属离子或离子 总离子浓度不大于10ppm。 在油墨组中，颜料和染料油墨可以组合使用，而不会使维护系统复杂化。

公开(公告)号：US07281789B2

公开(公告)日：2007-10-16

申请号：US10850412

申请日：2004-05-19

申请人： Kazuma Goto ,  Hideo Ohira ,  Masahito Kato ,  Masaya Fujioka ,  Shunichi Higashiyama

发明人： Kazuma Goto ,  Hideo Ohira ,  Masahito Kato ,  Masaya Fujioka ,  Shunichi Higashiyama

IPC分类号： G01D11/00

CPC分类号： C09D11/40

摘要： In a water base ink set for ink-jet recording, a pigment ink has a total ion concentration of lithium ion, potassium ion, and sodium ion of not less than 60 ppm and a total ion concentration of divalent or multivalent metal ion or ions of not more than 10 ppm, and a dye ink has a total ion concentration of lithium ion, potassium ion, and sodium ion of not more than 1,800 ppm and a total ion concentration of divalent or multivalent metal ion or ions of not more than 10 ppm, wherein the total ion concentration of lithium ion, potassium ion, and sodium ion of the dye ink is 3 to 25 times that of the pigment ink. Accordingly, the water base ink set in which the pigment ink and the dye ink can be reliably used in combination without complicating a maintenance system is provided.

摘要翻译： 在用于喷墨记录的水基油墨组中，颜料墨水具有不小于60ppm的锂离子，钾离子和钠离子的总离子浓度，并且二价或多价金属离子的总离子浓度 不大于10ppm，并且染料墨水具有不超过1,800ppm的锂离子，钾离子和钠离子的总离子浓度以及不大于10ppm的二价或多价金属离子或离子的总离子浓度 其中，染料墨水的锂离子，钾离子和钠离子的总离子浓度为颜料墨水的3〜25倍。 因此，提供了可以可靠地使用颜料墨水和染料墨水而不使维护系统复杂化的水基墨水组。

公开(公告)号：US07014695B2

公开(公告)日：2006-03-21

申请号：US10387739

申请日：2003-03-13

申请人： Narumi Koga ,  Masaya Fujioka ,  Hideo Ohira ,  Kazuma Goto ,  Hiromitsu Sago ,  Shunichi Higashiyama

发明人： Narumi Koga ,  Masaya Fujioka ,  Hideo Ohira ,  Kazuma Goto ,  Hiromitsu Sago ,  Shunichi Higashiyama

IPC分类号： C09D11/02 ,  G01D11/00

CPC分类号： C09D11/38 ,  C09D11/40

摘要： A water base ink for ink-jet recording contains a surfactant represented by the following formula (1) or (2), dipropylene glycol, a coloring agent, and water: CH3—(CH2)11—O—(CH2CH2O)z—H(2) In the formula (1), R represents alkyl group, and x and y represent integers which satisfy x+y=5 to 15. In the formula (2), z represents an integer of not more than 9. The performance of initial introduction into a recording head is satisfactory, and it is possible to simultaneously reduce the feathering and the color bleed even when the recording is performed on regular paper.

摘要翻译： 用于喷墨记录的水性油墨包含由下式（1）或（2）表示的表面活性剂，二丙二醇，着色剂和水：CH 3 - （CH 3） （CH 2）2 H 2（CH 2 CH 2 CH 2）n H（2） ）在式（1）中，R表示烷基，x和y表示满足x + y = 5〜15的整数。在式（2）中，z表示不大于9的整数。初始 引入记录头是令人满意的，即使在普通纸上进行记录，也可以同时减少羽化和着色。

公开(公告)号：US20050279250A1

公开(公告)日：2005-12-22

申请号：US11153626

申请日：2005-06-16

申请人： Akihiko Taniguchi ,  Kazuma Goto ,  Hideo Ohira ,  Masaya Fujioka ,  Shunichi Higashiyama

发明人： Akihiko Taniguchi ,  Kazuma Goto ,  Hideo Ohira ,  Masaya Fujioka ,  Shunichi Higashiyama

IPC分类号： C09D11/00 ,  C09D11/02

CPC分类号： C09D11/40

摘要： A water base ink set for ink-jet recording includes a black ink containing water, a black pigment and a water-soluble organic solvent and a color ink containing water, a dye, and a water-soluble organic solvent. The black pigment is a negatively-chargeable and self-dispersible pigment. The dye has a fluorescein structure. The color ink further contains an alkylamine ethylene oxide adduct. The water-soluble organic solvent contained in the black ink is same as that contained in the color ink. With the ink set, not only the bleeding hardly occurs but also satisfactory discharge stability is obtained even when an ink-jet recording is performed on a regular paper.

摘要翻译： 用于喷墨记录的水基油墨组包括含有水，黑色颜料和水溶性有机溶剂的黑色油墨和含有水，染料和水溶性有机溶剂的彩色油墨。 黑色颜料是可带负电和自分散颜料。 染料具有荧光素结构。 彩色墨水还含有烷基胺环氧乙烷加合物。 黑色油墨中所含的水溶性有机溶剂与彩色油墨中所含的相同。 对于油墨组，即使在普通纸上进行喷墨记录，也不会出现几乎不出现渗色，而且也能获得令人满意的喷射稳定性。

公开(公告)号：US07780285B2

公开(公告)日：2010-08-24

申请号：US10802652

申请日：2004-03-16

申请人： Narumi Koga ,  Masaya Fujioka ,  Kazuma Goto ,  Mayuko Okada ,  Tatsunosuke Hoshi ,  Narumi Kawai ,  Shunichi Higashiyama ,  Junichiro Sugimoto ,  Hideo Ohira ,  Michiko Aoyama

发明人： Narumi Koga ,  Masaya Fujioka ,  Kazuma Goto ,  Mayuko Okada ,  Tatsunosuke Hoshi ,  Narumi Kawai ,  Shunichi Higashiyama ,  Junichiro Sugimoto ,  Hideo Ohira ,  Michiko Aoyama

IPC分类号： G01D11/00

CPC分类号： C09D11/326

摘要： A water base ink for ink-jet recording contains a self-dispersible coloring agent, a propylene glycol ether, and a surfactant represented by the following general formula (3): R1—O—(CH2CH2O)n—SO3M  (3) wherein R1 represents an alkyl group having a number of carbon atoms of 12 to 15, M represents Na or triethanolamine, and n represents an integer of 2 to 4, and wherein the propylene glycol ether is dipropylene glycol propyl ether. The ink satisfies three requirements of i) the satisfactory initial introduction performance of the ink into an ink flow passage of a stacked type printer head, ii) the prevention of the occurrence of feathering, and iii) the prevention of the insufficient spread of the ink.

摘要翻译： 用于喷墨记录的水性油墨包含自分散着色剂，丙二醇醚和由以下通式（3）表示的表面活性剂：R1-O-（CH2CH2O）n-SO3M（3）其中R1 表示碳原子数为12〜15的烷基，M为Na或三乙醇胺，n为2〜4的整数，丙二醇醚为二丙二醇丙醚。 油墨满足以下三个要求：i）油墨在层叠型打印头的墨水流路中的令人满意的初始引入性能，ii）防止羽化的发生，以及iii）防止油墨不足的扩散 。

公开(公告)号：US07247197B2

公开(公告)日：2007-07-24

申请号：US10668078

申请日：2003-09-22

申请人： Kazuma Goto ,  Hideo Ohira ,  Yoshito Toyoda ,  Mayuko Okada ,  Masaya Fujioka ,  Shunichi Higashiyama

发明人： Kazuma Goto ,  Hideo Ohira ,  Yoshito Toyoda ,  Mayuko Okada ,  Masaya Fujioka ,  Shunichi Higashiyama

IPC分类号： C09D11/02

CPC分类号： C09D11/322 ,  C09D11/38

摘要： A water base ink for ink-jet recording is provided, which is excellent in time-dependent stability of ink characteristics, which can be stably jetted over a long period of time, and which makes it possible to perform the high quality recording. The water base ink for ink-jet recording contains a self-dispersing type water-insoluble particulate coloring agent, a compound represented by the following formula (1), a surfactant having a nitrogen atom in a molecule, water, and a water-soluble organic solvent, wherein a surface tension is 30 to 50 mN/m, and a ratio of change of the surface tension after storage at 60° C. for 2 weeks is less than 5%: R1—O—(CH2CH2O)x—SO3Na  (1) wherein R1 represents an alkyl group and x is 20 to 30 in the formula (1).

摘要翻译： 提供了一种用于喷墨记录的水基油墨，其具有优异的油墨特性的时间依赖性稳定性，其能够在长时间内稳定地喷射，并且这使得可以进行高质量记录。 用于喷墨记录的水基油墨包含自分散型水不溶性颗粒着色剂，由下式（1）表示的化合物，分子中具有氮原子的表面活性剂，水和水溶性 有机溶剂，其中表面张力为30〜50mN / m，并且在60℃下保存2周后的表面张力变化率小于5％：<？在线配方说明=“ 在线公式“end =”lead“？> R 1 -O-（CH 2 CH 2 O 2）x < （1）<β在线公式描述=“在线公式”end =“tail”？>其中R 1表示 式（1）中的烷基，x为20〜30。

公开(公告)号：US07247192B2

公开(公告)日：2007-07-24

申请号：US10645197

申请日：2003-08-21

申请人： Hideo Ohira ,  Hiromitsu Sago ,  Kazuma Goto ,  Narumi Koga ,  Masaya Fujioka ,  Shunichi Higashiyama

发明人： Hideo Ohira ,  Hiromitsu Sago ,  Kazuma Goto ,  Narumi Koga ,  Masaya Fujioka ,  Shunichi Higashiyama

IPC分类号： C09D11/00

CPC分类号： C09D11/30

摘要： A water base ink for ink-jet recording is provided, which makes it possible to secure a high recording quality with a sharp image area edge by avoiding any blurring even when recording is performed on regular paper and which has satisfactory purge restoration performance. Therefore, no bubble remains in an ink flow passage, and no discharge failure is caused. Further, the discharge operation never becomes unstable. In the water base ink for ink-jet recording, the surface tension is not less than 40 mN/m, and the amount of dissolved oxygen is not more than 4 mg/L.

摘要翻译： 提供了一种用于喷墨记录的水性墨水，这使得即使在普通纸上进行记录并且具有令人满意的清除恢复性能的情况下也可以避免任何模糊，从而可以确保具有清晰图像区域边缘的高记录质量。 因此，在墨水流路中没有气泡残留，不会产生放电故障。 此外，放电操作不会变得不稳定。 在用于喷墨记录的水基油墨中，表面张力不小于40mN / m，溶解氧量不大于4mg / L。

公开(公告)号：US07347891B2

公开(公告)日：2008-03-25

申请号：US11153626

申请日：2005-06-16

申请人： Akihiko Taniguchi ,  Kazuma Goto ,  Hideo Ohira ,  Masaya Fujioka ,  Shunichi Higashiyama

发明人： Akihiko Taniguchi ,  Kazuma Goto ,  Hideo Ohira ,  Masaya Fujioka ,  Shunichi Higashiyama

IPC分类号： C09D11/00 ,  C09D11/02

CPC分类号： C09D11/40

摘要： A water base ink set for ink-jet recording includes a black ink containing water, a black pigment and a water-soluble organic solvent and a color ink containing water, a dye, and a water-soluble organic solvent. The black pigment is a negatively-chargeable and self-dispersible pigment. The dye has a fluorescein structure. The color ink further contains an alkylamine ethylene oxide adduct. The water-soluble organic solvent contained in the black ink is same as that contained in the color ink. With the ink set, not only the bleeding hardly occurs but also satisfactory discharge stability is obtained even when an ink-jet recording is performed on a regular paper.

摘要翻译： 用于喷墨记录的水基油墨组包括含有水，黑色颜料和水溶性有机溶剂的黑色油墨和含有水，染料和水溶性有机溶剂的彩色油墨。 黑色颜料是可带负电和自分散颜料。 染料具有荧光素结构。 彩色墨水还含有烷基胺环氧乙烷加合物。 黑色油墨中所含的水溶性有机溶剂与彩色油墨中所含的相同。 对于油墨组，即使在普通纸上进行喷墨记录，也不会出现几乎不出现渗色，而且也能获得令人满意的喷射稳定性。

公开(公告)号：US06852155B2

公开(公告)日：2005-02-08

申请号：US10373530

申请日：2003-02-25

申请人： Narumi Koga ,  Kazuma Goto ,  Hiromitsu Sago ,  Hideo Ohira ,  Shunichi Higashiyama ,  Masaya Fujioka

发明人： Narumi Koga ,  Kazuma Goto ,  Hiromitsu Sago ,  Hideo Ohira ,  Shunichi Higashiyama ,  Masaya Fujioka

IPC分类号： B41J2/01 ,  B41M5/00 ,  C09D11/00 ,  C09D11/326 ,  C09D11/328 ,  C09D11/38 ,  C09D11/40 ,  C09D11/02

CPC分类号： C09D11/40

摘要： A water base ink set for ink-jet recording comprises a black ink which contains a black pigment, water, and a water-soluble organic solvent, and a color ink which contains a dye, water, a water-soluble organic solvent, and at least one compound represented by the following formulas (1) to (3), wherein the nozzle clog-up at an ink-jet head and the malfunction of a purging pump, which would be otherwise caused by the aggregation of the black ink, can be avoided: R1—O—(CH2CH2O)x—SO3.Na  (1) wherein R1 represents a straight chain alkyl group having a number of carbon atoms of 16 to 22, and x=20 to 30 is satisfied in the formula (1); wherein l+m+n+o+p+q=20 to 100 is satisfied in the formula (2); and wherein R2 represents a straight chain alkyl group having a number of carbon atoms of 16 to 22, and y=100 to 300 is satisfied in the formula (3).

摘要翻译： 用于喷墨记录的水基油墨组包括含有黑色颜料，水和水溶性有机溶剂的黑色油墨和含有染料，水，水溶性有机溶剂的彩色油墨，以及在 至少一种由下式（1）至（3）表示的化合物，其中在喷墨头处的喷嘴堵塞和否则由黑色墨水的聚集引起的清洗泵的故障可以 其中R 1表示碳原子数为16〜22的直链烷基，式（1）中X = 20〜30，其中l + m + n + o + p 在式（2）中满足+ q = 20〜100。 其中R 2表示碳原子数为16〜22的直链烷基，式（3）中y = 100〜300。

公开(公告)号：US06783223B2

公开(公告)日：2004-08-31

申请号：US10379596

申请日：2003-03-06

申请人： Mayuko Okada ,  Narumi Koga ,  Kazuma Goto ,  Hiromitsu Sago ,  Hideto Yamazaki ,  Kazuo Kobayashi ,  Tatsunosuke Hoshi ,  Michiko Aoyama ,  Hideo Ohira ,  Shunichi Higashiyama ,  Masaya Fujioka ,  Yoshito Toyoda

发明人： Mayuko Okada ,  Narumi Koga ,  Kazuma Goto ,  Hiromitsu Sago ,  Hideto Yamazaki ,  Kazuo Kobayashi ,  Tatsunosuke Hoshi ,  Michiko Aoyama ,  Hideo Ohira ,  Shunichi Higashiyama ,  Masaya Fujioka ,  Yoshito Toyoda

IPC分类号： B41J201

CPC分类号： C09D11/30

摘要： A water base ink for ink-jet recording, which is usable for an ink-jet recording apparatus having an ink-jet head provided therein with an ink flow passage formed of nickel or nickel alloy, includes a coloring agent, water, and a water-soluble organic solvent. The ink is blended so that a current density, which is obtained within an electric potential range of −600 to +300 mV, is not more than 100 &mgr;A/cm2 when anodic polarization measurement is performed by using a reference electrode of silver/silver chloride, a counter electrode of platinum, and a working electrode of nickel or nickel alloy. The ink does not corrode any part for constituting the flow passage in the ink-jet head.

摘要翻译： 用于喷墨记录的水性墨水，其可用于具有其中设置有由镍或镍合金形成的墨流道的喷墨头的喷墨记录装置，包括着色剂，水和水 - 可溶性有机溶剂。 将油墨混合，使得当在-600〜+ 300mV的电位范围内获得的电流密度不大于100μA/ cm 2，当通过使用银的参比电极进行阳极极化测量时 /氯化银，铂电极和镍或镍合金的工作电极。 油墨不会腐蚀用于构成喷墨头中的流路的任何部分。