公开(公告)号：US20190185491A1

公开(公告)日：2019-06-20

申请号：US16280504

申请日：2019-02-20

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed EDDAOUDI ,  Dong-Xu Dong-Xu ,  Amy J. CAIRNS ,  Youssef BELMABKHOUT

IPC: C07F5/00 ,  B01J20/22 ,  B01J31/16 ,  C07C51/41

CPC classification number: C07F5/00 ,  B01J20/226 ,  B01J31/1691 ,  C07C51/418 ,  Y02C10/08

Abstract: Embodiments of the present disclosure describe compositions comprising a molecular building block (MBB) having the formula [RE6(μ3-OH)8(O2C—)6N4C—)6] or [RE6(μ3-OH)8(O2C—)12], wherein RE is a rare earth metal ion. Embodiments of the present disclosure further describe methods of making a metal-organic framework (MOF) composition comprising contacting one or more molecular building blocks (MBBs) with one or more bidentate ligands, wherein the MBBs have the formula [RE6(μ3-OH)8(O2C—)6N4C—)6] or [RE6(μ3-OH)8(O2C—)12], wherein RE is a rare earth metal ion.