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    Electrophotographic photoreceptor with bisazo compound
    3.
    发明授权
    Electrophotographic photoreceptor with bisazo compound 失效
    双偶氮化合物的电子照相感光体

    公开(公告)号：US4999269A

    公开(公告)日：1991-03-12

    申请号：US560874

    申请日：1990-07-31

    申请人： Kazuhiro Emoto ,  Kozo Haino ,  Akira Itoh ,  Makoto Okaji

    发明人： Kazuhiro Emoto ,  Kozo Haino ,  Akira Itoh ,  Makoto Okaji

    IPC分类号： C09B35/023 ,  C09B35/03 ,  C09B35/215 ,  C09B35/34 ,  C09B56/08 ,  C09B56/16 ,  G03G5/06

    CPC分类号： C09B35/03 ,  C09B35/023 ,  C09B35/215 ,  C09B35/34 ,  C09B56/08 ,  C09B56/16 ,  G03G5/0681 ,  G03G5/0685

    摘要： This invention provides an electrophotographic photoreceptor which is high in durability and high in sensitivity. This photoreceptor comprises an electroconductive support and, provided thereon, a photosensitive layer containing an azo pigment represented by the following formula [I] or [II]: ##STR1## wherein A represents a hydrogen atom, an alkyl group, a phenyl group or a heterocyclic ring group, m and n each represents 0 or 1, X represents a hydrogen atom, a lower alkyl group, a cyano group or a halogen atom and Cp represents a coupler residue, or ##STR2## wherein Z represents an alkyl group, a phenyl group or a heterocyclic ring group, X represents a hydrogen atom, a lower alkyl group, a cyano group or a halogen atom and Cp represents a coupler residue.

    摘要翻译： 本发明提供一种耐久性高，灵敏度高的电子照相感光体。 该感光体包括导电载体，并且在其上提供含有由下式[I]或[II]表示的偶氮颜料的感光层：其中A表示氢原子，烷基，苯基 基或杂环基，m和n各自表示0或1，X表示氢原子，低级烷基，氰基或卤素原子，Cp表示成色剂残基，或者其中Z 表示烷基，苯基或杂环基，X表示氢原子，低级烷基，氰基或卤素原子，Cp表示成色剂残基。

    Electrophotographic disazo photoreceptor
    4.
    发明授权
    Electrophotographic disazo photoreceptor 失效
    电子照相双面感光体

    公开(公告)号：US5041349A

    公开(公告)日：1991-08-20

    申请号：US560736

    申请日：1990-07-31

    申请人： Kazuhiro Emoto ,  Kozo Haino ,  Akira Itoh ,  Makoto Okaji

    发明人： Kazuhiro Emoto ,  Kozo Haino ,  Akira Itoh ,  Makoto Okaji

    IPC分类号： C09B35/023 ,  C09B35/03 ,  C09B35/215 ,  C09B35/34 ,  C09B56/08 ,  C09B56/16 ,  G03G5/06

    CPC分类号： C09B35/03 ,  C09B35/023 ,  C09B35/215 ,  C09B35/34 ,  C09B56/08 ,  C09B56/16 ,  G03G5/0681 ,  G03G5/0685

    摘要： This invention provides an electrophotographic photoreceptor which is high in durability and high in sensitivity. This photoreceptor comprises an electroconductive support and, provided thereon, a photosensitive layer containing an azo pigment represented by the following formula [I] or [II]: ##STR1## wherein A represents a hydrogen atom, an alkyl group, a phenyl group or a heterocyclic ring group, m and n each represents 0 or 1, X represents a hydrogen atom, a lower alkyl group, a cyano group or a halogen atom and Cp represents a coupler residue, or ##STR2## wherein Z represents an alkyl group, a phenyl group or a heterocyclic ring group, X represents a hydrogen atom, a lower alkyl group, a cyano group or a halogen atom and Cp represents a coupler residue.

    摘要翻译： 本发明提供一种耐久性高，灵敏度高的电子照相感光体。 该感光体包括导电性支持体，并且在其上设置含有由下式[I]或[II]表示的偶氮颜料的感光层：其中A表示氢原子，烷基 ，苯基或杂环基，m和n各自表示0或1，X表示氢原子，低级烷基，氰基或卤素原子，Cp表示成色剂残基，或者[II] 其中Z表示烷基，苯基或杂环基，X表示氢原子，低级烷基，氰基或卤素原子，Cp表示成色剂残基。

    Electrophotographic photoreceptor containing a trisazo compound
    5.
    发明授权
    Electrophotographic photoreceptor containing a trisazo compound 失效
    含有三偶氮化合物的电子照相感光体

    公开(公告)号：US4687721A

    公开(公告)日：1987-08-18

    申请号：US905450

    申请日：1986-09-10

    申请人： Kazuhiro Emoto ,  Akira Itoh ,  Kozo Haino

    发明人： Kazuhiro Emoto ,  Akira Itoh ,  Kozo Haino

    IPC分类号： C09B35/023 ,  C09B35/378 ,  G03G5/06 ,  G03G5/14

    CPC分类号： G03G5/0681 ,  C09B35/023 ,  C09B35/378 ,  G03G5/0688

    摘要： There is disclosed an electrophotographic photoreceptor comprising an electroconductive support and, provided thereon, a photosensitive layer containing (A) a trisazo pigment formed by the reaction between a coupler component represented by the following general formula (I) and a diazonium salt represented by the following general formula (II) or (B) a bisazo pigment represented by the following general formula (III): ##STR1## wherein Z is a substituted or unsubstituted hydrocarbon ring or a group of atoms necessary to complete a substituted or unsubstituted hetero ring, R is oxygen, sulfur, or --NR'--, Y is a chain hydrocarbon necessary to complete a 5- or 6-membered ring, and R' is hydrogen or an alkyl, benzyl, or aryl group which may have a substituent; ##STR2## wherein A is a trivalent moiety whose carbon atom is bonded to nitrogen atom forming azo group and X.crclbar. is an anionic functional group; ##STR3## wherein A is a divalent moiety whose carbon atom is bonded to nitrogen atom forming azo group, R's which may be the same or different are each hydrogen, methyl, ethyl, nitro, or halogen, R' is hydrogen or halogen, X is --O--, --S--, or --NH--, and a is an integer of 1 or 2.

    摘要翻译： 公开了一种电子照相感光体，其包含导电性支持体，并且在其上设置感光层，感光层含有（A）由下述通式（I）表示的成色剂成分与下述通式（I）表示的重氮盐之间的反应形成的三偶氮颜料 通式（II）或（B）由以下通式（III）表示的双偶氮颜料：其中Z是取代或未取代的烃环或完成取代或未取代杂原子所必需的原子团 环，R是氧，硫或-NR'-，Y是完成5-或6-元环所必需的链烃，R'是氢或可具有取代基的烷基，苄基或芳基 ; （II）其中A是其碳原子与形成氮原子的氮原子键合的三价部分，X（ - ）是阴离子官能团; 其中A是碳原子与形成氮原子的氮原子连接的二价部分，R可相同或不同，分别为氢，甲基，乙基，硝基或卤素，R' 是氢或卤素，X是-O - ， - S-或-NH-，a是1或2的整数。

    Bisazo electrophotographic sensitive materials with --CF.sub.3 group
    6.
    发明授权
    Bisazo electrophotographic sensitive materials with --CF.sub.3 group 失效

    公开(公告)号：US4631242A

    公开(公告)日：1986-12-23

    申请号：US772878

    申请日：1985-09-05

    申请人： Kazuhiro Emoto ,  Kozo Haino ,  Akira Itoh

    发明人： Kazuhiro Emoto ,  Kozo Haino ,  Akira Itoh

    IPC分类号： G03G5/06 ,  G03G5/14

    CPC分类号： G03G5/0681 ,  G03G5/0679

    摘要： An electrophotographic material comprises a conductive support and a light-sensitive layer containing at least one of the azo compound of the formulas [I]-[III]: formula [I]:Cp.sub.1 --N.dbd.N--A--N.dbd.N--Cp.sub.2 A represents a divalent residue which bonds through C atoms to N atoms which constitute azo and Cp.sub.1 is a group of by the formula: ##STR1## Z represents a substituted or unsubstituted carbocyclic aromatic ring, a substituted or unsubstituted heterocyclic aromatic ring or a unsaturated monocyclic hydrocarbon ring and R represents an aryl group containing one or two CF.sub.3 groups and Cp.sub.2 is a coupler residue different from said Cp.sub.1 and is selected from following formulas (a)-(f): ##STR2## Z.sup.1 and Z.sup.2 represent a substituted or unsubstituted aromatic hydrocarbon ring or substituted or unsubstituted hetero ring, R.sup.1 and R.sup.2 represent substituted or unsubstituted alkyl, aralkyl, aryl or hetero ring group, R.sup.3 represents an alkyl or carboxyl group or an ester thereof, R.sup.4 and R.sup.6 represent substituted or unsubstituted aryl or hetero ring group and R.sup.5 represents H, a substituted or unsubstituted alkyl, aralkyl, aryl or hetero ring group and Y.sup.1 and Y.sup.2 represent --NR.sup.7 R.sup.8, --OR.sup.9, --NHN.dbd.CH--R.sup.10 or --NHNR.sup.11 R.sup.12 wherein R.sup.7, R.sup.8, R.sup.9, R.sup.11 and R.sup.12 represent H, substituted or unsubstituted alkyl, aralkyl, aryl or hetero ring group and R.sup.10 represents a substituted or unsubstituted aryl or hetero ring group. formula (II): ##STR3## X represents H, a halogen atom, a lower alkyl group, methoxy group or nitro group and Y represents an aromatic ring or hetero ring which may be substituted. formula (III): ##STR4## A represents a divalent residue which bonds through C atoms to N atoms which constitute azo and Z represents a substituted or unsubstituted carbocyclic aromatic ring, a substituted or unsubstituted heterocyclic aromatic ring or unsaturated monocyclic hydrocarbon ring.

    Electrophotographic photoreceptor comprising bis-azo pigment
    7.
    发明授权
    Electrophotographic photoreceptor comprising bis-azo pigment 失效
    包含双偶氮颜料的电子照相感光体

    公开(公告)号：US4702983A

    公开(公告)日：1987-10-27

    申请号：US4494

    申请日：1987-01-20

    申请人： Kozo Haino ,  Kazuhiro Emoto ,  Akira Itoh

    发明人： Kozo Haino ,  Kazuhiro Emoto ,  Akira Itoh

    IPC分类号： G03G5/06 ,  G03G5/14

    CPC分类号： G03G5/0679 ,  G03G5/0681 ,  G03G5/0685

    摘要： An electrophotographic photoreceptor excellent in properties after repeated use and durability is provided by containing a bis-azo pigment represented by the following general formula [I] or [II] in the light-sensitive layer on the conductive support: ##STR1## wherein X represents --O--, --S--or >N--R.sub.4 wherein R.sub.4 represents a hydrogen atom, an alkyl group or an aralkyl group, R.sub.1, R.sub.2 and R.sub.3 each represent a hydrogen atom, an alkyl group, an alkoxy group, an aryl group or a group of atoms necessary to form a condensed ring by combination of two or them, Y.sub.1 and Y.sub.2 each represent a hydrogen atom, a halogen atom, an alkyl group or an alkoxy group, A represents a coupler residue necessary to produce an azo pigment and n is 0 or 1; ##STR2## wherein Y.sub.1 and Y.sub.2 each represent a hydrogen atom, a halogen atom, an alkyl group or an alkoxy group, R.sub.1 and R.sub.2 each represent a hydrogen atom, an alkyl group, an alkoxy group or a group of atoms necessary to form a condensed ring by combination of them, A represents a coupler residue necessary to produce an azo pigment and n is 0 or 1.

    摘要翻译： 通过在导电性支持体的感光层中含有下述通式[I]或[II]表示的双偶氮颜料，提供反复使用性和耐久性优异的电子照相感光体。 其中X表示-O - ， - S-或> N-R4，其中R4表示氢原子，烷基或芳烷基，R1，R2和R3各自表示氢原子，烷基，烷氧基， 芳基或通过两个或它们的组合形成稠环所必需的一组原子，Y1和Y2各自表示氢原子，卤素原子，烷基或烷氧基，A表示生成 偶氮颜料，n为0或1; 其中Y1和Y2各自表示氢原子，卤原子，烷基或烷氧基，R1和R2各自表示氢原子，烷基，烷氧基或必要的原子团 通过它们的组合形成稠环，A代表产生偶氮颜料所必需的成色剂残基，n为0或1。

    Hydrazone photoconductive materials for electrophotography
    8.
    发明授权
    Hydrazone photoconductive materials for electrophotography 失效
    用于电子照相的腙光导材料

    公开(公告)号：US4567126A

    公开(公告)日：1986-01-28

    申请号：US675743

    申请日：1984-11-28

    申请人： Kazuhiro Emoto ,  Kozo Haino

    发明人： Kazuhiro Emoto ,  Kozo Haino

    IPC分类号： C07D295/135 ,  G03G5/06 ,  G03G5/14

    CPC分类号： C07D295/135 ,  C07C251/72 ,  G03G5/0616 ,  G03G5/0637 ,  G03G5/0638 ,  G03G5/0668 ,  G03G5/067

    摘要： Photoconductive materials for electrophotography which have high sensitivity and high durability are provided by incorporating at least one hydrazone compound represented by the following general formula (I) in photoconductive layer: ##STR1## (wherein M is 0, 1, 2 or 3 and l is 1 or 2), R.sub.2 is a hydrogen atom, a lower alkyl group, a lower alkoxy group or a halogen atom,R.sub.3 is a hydrogen atom, a lower alkyl group or an aryl group,R.sub.4 is a hydrogen atom, a lower alkyl group, a lower alkoxy group or a halogen atom,R.sub.5 is an allyl group, propenyl group or ##STR2## (wherein R.sub.6 is a lower alkyl group, a lower alkoxy group or a halogen atom), and n is 0 or 1.

    摘要翻译： 具有高灵敏度和高耐久性的用于电子照相术的光导材料通过在光电导层中引入至少一种由以下通式（I）表示的腙化合物来提供：图像（I） + TR （其中M为0,1,2或3且l为1或2），R2为氢原子，低级烷基，低级烷氧基或卤素原子，R3为氢原子，低级烷基或 芳基，R 4为氢原子，低级烷基，低级烷氧基或卤素原子，R 5为烯丙基，丙烯基或其中R 6为低级烷基，低级烷氧基或 卤原子），n为0或1。

    Disazo electrophotographic photoreceptor
    9.
    发明授权
    Disazo electrophotographic photoreceptor 失效
    双面电子照相感光体

    公开(公告)号：US4913997A

    公开(公告)日：1990-04-03

    申请号：US296129

    申请日：1989-01-12

    申请人： Kazuhiro Emoto ,  Kozo Haino

    发明人： Kazuhiro Emoto ,  Kozo Haino

    IPC分类号： B08B3/08 ,  C09B56/16 ,  C23G3/00 ,  G03G5/06 ,  H01L21/304

    CPC分类号： C09B56/16 ,  G03G5/0681 ,  G03G5/0685

    摘要： This provides an electrophotographic photoreceptor high in durability and sensitivity which comprises an electroconductive support and, provided thereon, a photosensitive layer containing an azo pigment represented by the formula [I]: ##STR1## wherein A represents an aryl group, a heterocyclic group or an alkyl group, Z represents a hydrogen atom, --B or --CH.dbd.CH--B wherein B represents an aryl group, a heterocyclic group or an alkyl group and Cp represents a coupler residue.

    摘要翻译： 这提供了耐久性和灵敏度高的电子照相感光体，其包括导电性载体，并且在其上提供含有由式[I]表示的偶氮颜料的感光层：其中A表示芳基，杂环 基团或烷基，Z表示氢原子，-B或-CH = CH-B，其中B表示芳基，杂环基或烷基，Cp表示成色剂残基。

    Trisazo electrophotographic photoconductive material
    10.
    发明授权
    Trisazo electrophotographic photoconductive material 失效
    Trisazo电子照相感光材料

    公开(公告)号：US4600674A

    公开(公告)日：1986-07-15

    申请号：US748398

    申请日：1985-06-24

    申请人： Kazuhiro Emoto ,  Akira Itoh

    发明人： Kazuhiro Emoto ,  Akira Itoh

    IPC分类号： C09B35/378 ,  G03G5/06

    CPC分类号： G03G5/069 ,  C09B35/378 ,  G03G5/0687 ,  G03G5/0688 ,  G03G5/0692

    摘要： Disclosed is an electrophotographic photoconductive material excellent in sensitivity and durability which comprises an electroconductive substrate and, provided thereon, a photosensitive layer containing a trisazo pigment represented by the general formula ##STR1## wherein R's, which may be the same or different, represent each a hydrogen atom, halogen atom, substituted or unsubstituted alkyl group, alkoxyl group, or nitrile group; n is an integer of 1 or 2; and A represents ##STR2## wherein Z represents a group of atoms necessary to complete a substituted or unsubstituted aromatic carbon ring or a substituted or unsubstituted aromatic hetero-ring; X represents a hydrogen atom, an alkyl group, or a group of atoms necessary to complete a substituted or unsubstituted aromatic carbon ring, a substituted or unsubstituted aromatic hetero ring, or a substituted or unsubstituted hetero ring; m is 0 or 1; B represents a group of atoms necessary to complete a substituted or unsubstituted aromatic carbon ring, a substituted or unsubstituted aromatic hetero ring, or a substituted or unsubstituted monocyclic hetero ring; Y represents a hydrogen atom, hydroxyl group, carboxyl group or an ester thereof, sulfo group, substituted or unsubstituted carbamoyl group, or substituted or unsubstituted sulfamoyl group; R.sub.1 represents a hydrogen atom, substituted or unsubstituted alkyl group, substituted or unsubstituted amino group, substituted or unsubstituted carbamoyl group, carboxyl group or an ester thereof, or cyano group; Ar represents a substituted or unsubstituted aryl group; and R.sub.2 represents a substituted or unsubstituted alkyl group, substituted or unsubstituted aralkyl group, or substituted or unsubstituted aryl group.

    摘要翻译： 公开了一种敏感性和耐久性优异的电子照相感光材料，其包含导电性基材，并且在其上设置含有通式（I）[I]表示的三偶氮颜料的感光层，其中R可以相同或不同， 代表氢原子，卤素原子，取代或未取代的烷基，烷氧基或腈基; n为1或2的整数; A表示 其中Z表示完成取代或未取代的芳族碳环或取代或未取代的芳族杂环所必需的原子团; X表示完成取代或未取代的芳族碳环所需的氢原子，烷基或原子团，取代或未取代的芳族杂环或取代或未取代的杂环; m为0或1; B表示完成取代或未取代的芳族碳环，取代或未取代的芳族杂环或取代或未取代的单环杂环所必需的一组原子; Y表示氢原子，羟基，羧基或其酯，磺基，取代或未取代的氨基甲酰基或取代或未取代的氨磺酰基; R 1表示氢原子，取代或未取代的烷基，取代或未取代的氨基，取代或未取代的氨基甲酰基，羧基或其酯或氰基; Ar表示取代或未取代的芳基; 并且R 2表示取代或未取代的烷基，取代或未取代的芳烷基或取代或未取代的芳基。