公开(公告)号：US07968743B2

公开(公告)日：2011-06-28

申请号：US12612067

申请日：2009-11-04

申请人： Kuo Chen Shih ,  Po Wen Chung ,  Mei Hua Wang

发明人： Kuo Chen Shih ,  Po Wen Chung ,  Mei Hua Wang

IPC分类号： C07C327/02 ,  C08F2/00

CPC分类号： C08F2/38 ,  C07C327/36

摘要： A thiocarbonylthio compound and free radical polymerization employing the same. The thiocarbonylthio compound is represented by formula (I) or (II): wherein Z can be independently perfluoroalkyl, alkyl, haloalkyl, aryl, alkylaryl, haloalkylaryl, arylalkyl, aminoalkyl, alkylamino, alkoxy, alkoxyaryl, alkylsulfonyl, alkylsulfonylaryl, dialkylphosphinyl, or dialkylphosphinothioyl; R1 and R2 can be each independently hydrogen, alkyl, aryl, alkylaryl, arylalkyl, aminoalkyl, alkylamino, alkoxy or alkoxyaryl; R3 is alkyl, aryl, aminoalkyl, alkylamino, alkoxy or alkoxyaryl. Furthermore, R3 can also be alkyl, aryl, alkylaryl, arylalkyl, aminoalkyl, alkylamino, alkoxy, haloalkylaryl, alkylsilyl, alkylthio, alkylthioaryl, or substituent containing CN, CO, COOH, COOCH3 or heterocyclic moieties; and R4 is perfluoroalkyl. The thiocarbonylthio compound can be used as a reversible chain transfer agent in a free radical polymerization to obtain a polymer with a controlled molecular weight and narrow polydispersity.

摘要翻译： 硫代羰基硫代化合物和使用其的自由基聚合。 硫代羰基硫代化合物由式（I）或（II）表示：其中Z可以独立地为全氟烷基，烷基，卤代烷基，芳基，烷基芳基，卤代烷基芳基，芳基烷基，氨基烷基，烷基氨基，烷氧基，烷氧基芳基，烷基磺酰基，烷基磺酰基芳基，二烷基氧膦基或二烷基膦硫基 ; R 1和R 2可各自独立地为氢，烷基，芳基，烷基芳基，芳基烷基，氨基烷基，烷基氨基，烷氧基或烷氧基芳基; R3是烷基，芳基，氨基烷基，烷基氨基，烷氧基或烷氧基芳基。 此外，R 3还可以是烷基，芳基，烷基芳基，芳基烷基，氨基烷基，烷基氨基，烷氧基，卤代烷基芳基，烷基甲硅烷基，烷硫基，烷硫基芳基或含有CN，CO，COOH，COOCH 3或杂环部分的取代基; R4是全氟烷基。 硫羰基硫代化合物可以在自由基聚合中用作可逆链转移剂，以获得具有受控分子量和窄分散性的聚合物。

公开(公告)号：US07632959B2

公开(公告)日：2009-12-15

申请号：US11136005

申请日：2005-05-24

申请人： Kuo Chen Shih ,  Po Wen Chung ,  Mei Hua Wang

发明人： Kuo Chen Shih ,  Po Wen Chung ,  Mei Hua Wang

IPC分类号： C07C327/02

CPC分类号： C08F2/38 ,  C07C327/36

摘要： A thiocarbonylthio compound and free radical polymerization employing the same. The thiocarbonylthio compound is represented by formula (I) or (II): wherein Z can be independently perfluoroalkyl, alkyl, haloalkyl, aryl, alkylaryl, haloalkylaryl, arylalkyl, aminoalkyl, alkylamino, alkoxy, alkoxyaryl, alkylsulfonyl, alkylsulfonylaryl, dialkylphosphinyl, or dialkylphosphinothioyl; R1 and R2 can be each independently hydrogen, alkyl, aryl, alkylaryl, arylalkyl, aminoalkyl, alkylamino, alkoxy or alkoxyaryl; R3 is alkyl, aryl, aminoalkyl, alkylamino, alkoxy or alkoxyaryl. Furthermore, R can also be alkyl, aryl, alkylaryl, arylalkyl, aminoalkyl, alkylamino, alkoxy, haloalkylaryl, alkylsilyl, alkylthio, alkylthioaryl, or substituent contaning CN, CO, COOH, COOCH3 or heterocyclic moieties; and R4 is perfluoroalkyl. The thiocarbonylthio compound can be used as a reversible chain transfer agent in a free radical polymerization to obtain a polymer with a controlled molecular weight and narrow polydispersity.

摘要翻译： 硫代羰基硫代化合物和使用其的自由基聚合。 硫代羰基硫代化合物由式（I）或（II）表示：其中Z可以独立地为全氟烷基，烷基，卤代烷基，芳基，烷基芳基，卤代烷基芳基，芳基烷基，氨基烷基，烷基氨基，烷氧基，烷氧基芳基，烷基磺酰基，烷基磺酰基芳基，二烷基氧膦基或二烷基膦硫基 ; R 1和R 2可各自独立地为氢，烷基，芳基，烷基芳基，芳基烷基，氨基烷基，烷基氨基，烷氧基或烷氧基芳基; R3是烷基，芳基，氨基烷基，烷基氨基，烷氧基或烷氧基芳基。 此外，R还可以是烷基，芳基，烷基芳基，芳基烷基，氨基烷基，烷基氨基，烷氧基，卤代烷基芳基，烷基甲硅烷基，烷硫基，烷基硫代芳基或与CN，CO，COOH，COOCH 3或杂环部分相连的取代基; R4是全氟烷基。 硫羰基硫代化合物可以在自由基聚合中用作可逆链转移剂，以获得具有受控分子量和窄分散性的聚合物。

公开(公告)号：US20100048844A1

公开(公告)日：2010-02-25

申请号：US12612067

申请日：2009-11-04

申请人： Kuo Chen Shih ,  Po Wen Chung ,  Mei Hua Wang

发明人： Kuo Chen Shih ,  Po Wen Chung ,  Mei Hua Wang

IPC分类号： C08F2/00

CPC分类号： C08F2/38 ,  C07C327/36

摘要： A thiocarbonylthio compound and free radical polymerization employing the same. The thiocarbonylthio compound is represented by formula (I) or (II): wherein Z can be independently perfluoroalkyl, alkyl, haloalkyl, aryl, alkylaryl, haloalkylaryl, arylalkyl, aminoalkyl, alkylamino, alkoxy, alkoxyaryl, alkylsulfonyl, alkylsulfonylaryl, dialkylphosphinyl, or dialkylphosphinothioyl; R1 and R2 can be each independently hydrogen, alkyl, aryl, alkylaryl, arylalkyl, aminoalkyl, alkylamino, alkoxy or alkoxyaryl; R3 is alkyl, aryl, aminoalkyl, alkylamino, alkoxy or alkoxyaryl. Furthermore, R can also be alkyl, aryl, alkylaryl, arylalkyl, aminoalkyl, alkylamino, alkoxy, haloalkylaryl, alkylsilyl, alkylthio, alkylthioaryl, or substituent contaning CN, CO, COOH, COOCH3 or heterocyclic moieties; and R4 is perfluoroalkyl. The thiocarbonylthio compound can be used as a reversible chain transfer agent in a free radical polymerization to obtain a polymer with a controlled molecular weight and narrow polydispersity.

摘要翻译： 硫代羰基硫代化合物和使用其的自由基聚合。 硫代羰基硫代化合物由式（I）或（II）表示：其中Z可以独立地为全氟烷基，烷基，卤代烷基，芳基，烷基芳基，卤代烷基芳基，芳基烷基，氨基烷基，烷基氨基，烷氧基，烷氧基芳基，烷基磺酰基，烷基磺酰基芳基，二烷基氧膦基或二烷基膦硫基 ; R 1和R 2可各自独立地为氢，烷基，芳基，烷基芳基，芳基烷基，氨基烷基，烷基氨基，烷氧基或烷氧基芳基; R3是烷基，芳基，氨基烷基，烷基氨基，烷氧基或烷氧基芳基。 此外，R还可以是烷基，芳基，烷基芳基，芳基烷基，氨基烷基，烷基氨基，烷氧基，卤代烷基芳基，烷基甲硅烷基，烷硫基，烷基硫代芳基或与CN，CO，COOH，COOCH 3或杂环部分相连的取代基; R4是全氟烷基。 硫羰基硫代化合物可以在自由基聚合中用作可逆链转移剂，以获得具有受控分子量和窄分散性的聚合物。

公开(公告)号：US20080280758A1

公开(公告)日：2008-11-13

申请号：US11766390

申请日：2007-06-21

申请人： Po Wen Chung

发明人： Po Wen Chung

IPC分类号： B41M5/24 ,  B41M3/12

CPC分类号： B41M5/52 ,  B41M5/5236 ,  B41M5/5254

摘要： A connecting material for cold transfer printing paper is provided and includes an acrylic coating agent composition as an isolating layer and an acrylic coating agent composition as an ink-receiving layer. Also provided is a method for preparing the connecting material for cold transfer printing paper, a cold transfer printing paper and a method for printing a pattern or letter on a fabric by using the cold transfer printing paper.

摘要翻译： 提供了用于冷转印纸的连接材料，并且包括作为隔离层的丙烯酸涂料组合物和作为油墨接收层的丙烯酸涂料组合物。 还提供了一种制备冷转印纸的连接材料的方法，冷转印纸以及通过使用冷转印纸在织物上印刷图案或字母的方法。

公开(公告)号：US07989039B2

公开(公告)日：2011-08-02

申请号：US11766390

申请日：2007-06-21

申请人： Po Wen Chung

发明人： Po Wen Chung

IPC分类号： B41M5/50

CPC分类号： B41M5/52 ,  B41M5/5236 ,  B41M5/5254

摘要： A connecting material for cold transfer printing paper is provided and includes an acrylic coating agent composition as an isolating layer and an acrylic coating agent composition as an ink-receiving layer. Also provided is a method for preparing the connecting material for cold transfer printing paper, a cold transfer printing paper and a method for printing a pattern or letter on a fabric by using the cold transfer printing paper.

摘要翻译： 提供了用于冷转印纸的连接材料，并且包括作为隔离层的丙烯酸涂料组合物和作为油墨接收层的丙烯酸涂料组合物。 还提供了一种制备冷转印纸的连接材料的方法，冷转印纸以及通过使用冷转印纸在织物上印刷图案或字母的方法。