公开(公告)号：US11958799B2

公开(公告)日：2024-04-16

申请号：US17965899

申请日：2022-10-14

申请人： Kyoto University ,  Shin-Etsu Chemical Co., Ltd.

发明人： Haruo Kawamoto ,  Eiji Minami ,  Yuanyuan Zhao ,  Takashi Nomura ,  Kazuto Kobayashi ,  Akiko Miki

IPC分类号： C01B3/32 ,  B01J21/06 ,  B01J23/62 ,  C07C51/16

CPC分类号： C07C51/16 ,  B01J21/063 ,  B01J23/626 ,  C01B3/326 ,  C01B2203/06 ,  C01B2203/1047

摘要： In a method for producing hydrogen and carboxylic acid, a primary alcohol of 1 to 7 carbon atoms and water are reacted by being continuously introduced into a flow reactor packed with a solid catalyst consisting of an alloy of ruthenium and tin on a support and passed through the reactor under temperature and pressure conditions at which the water assumes a gaseous state. This method enables hydrogen and carboxylic acid to be produced in a high yield or at a high purity from a primary alcohol and water in a short time and by simple operations.