Abstract:
The present invention discloses an electrochemical pretreatment method of a vanadium positive electrode for a lithium secondary battery, which can improve the lifetime characteristics of the positive electrode and the battery by inhibiting the leaching of vanadium when charging/discharging the lithium secondary battery using vanadium oxide (V2O5) as a positive electrode, and a vanadium positive electrode for a lithium secondary battery pretreated thereby. The electrochemical pretreatment method of the vanadium positive electrode for a lithium secondary battery comprises a) a step of discharging the lithium free vanadium positive electrode at a voltage of 1.9 V or more; b) an electrochemical pretreatment step of maintaining the discharged vanadium positive electrode at an onset potential value or a potential value having a maximum current through a potentiostat; and c) a step of charging/discharging the pretreated vanadium positive electrode at a voltage range of 2.1 to 4.0V.
Abstract:
A polymer electrolyte is provided, which includes a polymer including an ethylene oxide unit; and a lithium salt, wherein the terminal of the polymer is substituted with one to four functional groups selected from the group consisting of a nitrogen compound functional group and phosphorus compound functional group, and the terminal of the polymer and the one to four functional groups are linked by one selected from the group consisting of a C2 to C20 alkylene linker, a C2 to C20 ether linker, and a C2 to C20 amine linker. A method for preparing the same is also provided.
Abstract:
A positive electrode material for lithium secondary batteries capable of easily doping vanadium oxide with molybdenum, and a method of manufacturing the same are disclosed. The method of manufacturing a positive electrode material for lithium secondary batteries includes (a) reacting vanadium oxide with a water-soluble molybdenum-based compound in the presence of a solvent; and (b) thermally treating the reaction product of (a).
Abstract:
The present application relates to a separation membrane and a lithium-sulfur battery including the same, and the separation membrane according to the present application prevents elution of lithium polysulfide in a cathode and suppresses growth of a lithium dendrite generated in an anode, and thus has an effect that a life-span and safety of the battery are improved.
Abstract:
A solid polymer electrolyte and a method for preparing the solid polymer electrolyte are disclosed. More particularly, a solid polymer electrolyte including a multifunctional acrylate-based polymer, a C1 to C10 polyalkylene oxide, a flame-retardant polymer, a lithium salt, and a non-aqueous solvent, wherein the multifunctional acrylate-based polymer is cross-linked with the polyalkylene oxide to form semi-interpenetrating polymer networks (semi-IPN), and the flame-retardant polymer is present blended with the semi-interpenetrating polymer networks of the multifunctional acrylate-based polymer and the polyalkylene oxide, which shows high solid content and flame-retardant characteristics, and a method for preparing the same.
Abstract:
The present specification relates to a silicon-carbon composite, a negative electrode including the same, a secondary battery using the silicon-carbon composite, and a method for preparing the silicon-carbon composite.