公开(公告)号：US20090318663A1

公开(公告)日：2009-12-24

申请号：US12224831

申请日：2007-03-06

申请人： Makoto Fujita ,  Sota Sato ,  Takashi Murase ,  Tetsuya Iida ,  Takanobu Higuchi ,  Satoru Tanaka

发明人： Makoto Fujita ,  Sota Sato ,  Takashi Murase ,  Tetsuya Iida ,  Takanobu Higuchi ,  Satoru Tanaka

IPC分类号： C08G69/26

CPC分类号： C07D401/10 ,  C07F15/0066

摘要： A polymerizable spherical transition metal complex is provided which has a hollow shell which is formed from transition metal atoms and bidentate organic ligands, the bidentate organic ligands having a substituent having a polymerizable group moiety at an end thereof, and the substituents being oriented towards the interior of the hollow shell. A spherical transition metal complex in which, in the hollow shell of the polymerizable spherical transition metal complex, the polymerizable groups are polymerized, and a production method thereof are also provided. The polymerizable spherical transition metal complex which is a spherical transition metal complex having a hollow shell, is characterized in that the hollow shell is formed from a transition metal atoms (wherein a represents an integer of 6 to 60), and 2a bidentate organic ligands, the bidentate organic ligands have a substituent having at least one or more polymerizable group moieties at an end thereof, and the substituents are oriented towards an interior of the hollow shell. The spherical transition metal complex is characterized in that the polymerizable groups are polymerized in the hollow shell of the polymerizable spherical transition metal complex. The production method thereof is also provided.

摘要翻译： 提供了一种可聚合的球状过渡金属络合物，其具有由过渡金属原子和二齿有机配体形成的中空壳，二齿有机配位体在其末端具有可聚合基团部分的取代基，并且取代基朝向内部 的空心壳。 在聚合性球状过渡金属络合物的中空壳中使聚合性基团聚合的球状过渡金属络合物及其制造方法。 作为具有中空壳的球形过渡金属络合物的聚合性球状过渡金属络合物的特征在于，中空壳由过渡金属原子（其中a表示6〜60的整数）和2a二齿有机配体形成， 双齿有机配体具有在其末端具有至少一个或多个可聚合基团部分的取代基，并且取代基朝向空心壳体的内部。 球形过渡金属络合物的特征在于可聚合的基团在可聚合的球状过渡金属络合物的中空壳中聚合。 还提供了其制备方法。

公开(公告)号：US08791261B2

公开(公告)日：2014-07-29

申请号：US13255739

申请日：2010-03-10

申请人： Makoto Fujita ,  Sota Sato ,  Kosuke Suzuki

发明人： Makoto Fujita ,  Sota Sato ,  Kosuke Suzuki

IPC分类号： C07F15/00 ,  C07H23/00

CPC分类号： C07H15/26 ,  C01B33/18 ,  C01F7/021 ,  C01G1/02 ,  C01G23/047 ,  C01G23/053 ,  C01G25/02 ,  C01P2002/85 ,  C01P2002/86 ,  C01P2002/89 ,  C01P2004/04 ,  C07H23/00

摘要： Provided is a polyhedral transition metal complex including a hollow shell, the hollow shell including n1 (where n1 is an integer from 6 to 60) transition metal atoms and 2(n1) bidentate organic ligands, the bidentate organic ligands including a group derived from a polyhydroxy compound via a linking group, and formed so that the group derived from the polyhydroxy compound is oriented toward an inner space of the hollow shell. Also provided are: an ultrafine particle-containing transition metal complex including the polyhedral transition metal complex, and ultrafine particles of a metal oxide, the ultrafine particles being included within the hollow shell of the polyhedral transition metal complex; a method of producing the same. The invention thus provides a polyhedral transition metal complex that makes it possible to efficiently produce metal oxide particles having a uniform particle size of several nanometers, an ultrafine particle-containing polyhedral transition metal complex in which metal oxide particles are included within a polyhedral structure and the method of producing the same.

摘要翻译： 提供了包含中空壳体的多面体过渡金属络合物，中空壳体包括n1（其中n1为6至60的整数）过渡金属原子和2（n1）二齿有机配体，二齿有机配体包括衍生自 多羟基化合物通过连接基团形成，并且形成为使得来自多羟基化合物的基团朝向中空壳体的内部空间。 还提供：包含多面体过渡金属络合物的超细颗粒的过渡金属络合物和金属氧化物的超细颗粒，超细颗粒包含在多面体过渡金属络合物的中空壳内; 其制造方法。 因此，本发明提供了一种多面体过渡金属络合物，其可以有效地生产具有几纳米的均匀粒径的金属氧化物颗粒，其中在多面体结构内包含金属氧化物颗粒的超细颗粒的多面体过渡金属络合物， 制作方法

公开(公告)号：US20120095196A1

公开(公告)日：2012-04-19

申请号：US13255739

申请日：2010-03-10

申请人： Makoto Fujita ,  Sota Sato ,  Kosuke Suzuki

发明人： Makoto Fujita ,  Sota Sato ,  Kosuke Suzuki

IPC分类号： C07H23/00

CPC分类号： C07H15/26 ,  C01B33/18 ,  C01F7/021 ,  C01G1/02 ,  C01G23/047 ,  C01G23/053 ,  C01G25/02 ,  C01P2002/85 ,  C01P2002/86 ,  C01P2002/89 ,  C01P2004/04 ,  C07H23/00

摘要： Provided is a polyhedral transition metal complex including a hollow shell, the hollow shell including n1 (where n1 is an integer from 6 to 60) transition metal atoms and 2(n1) bidentate organic ligands, the bidentate organic ligands including a group derived from a polyhydroxy compound via a linking group, and formed so that the group derived from the polyhydroxy compound is oriented toward an inner space of the hollow shell. Also provided are: an ultrafine particle-containing transition metal complex including the polyhedral transition metal complex, and ultrafine particles of a metal oxide, the ultrafine particles being included within the hollow shell of the polyhedral transition metal complex; a method of producing the same. The invention thus provides a polyhedral transition metal complex that makes it possible to efficiently produce metal oxide particles having a uniform particle size of several nanometers, an ultrafine particle-containing polyhedral transition metal complex in which metal oxide particles are included within a polyhedral structure and the method of producing the same.

摘要翻译： 提供了包含中空壳体的多面体过渡金属络合物，中空壳体包括n1（其中n1为6至60的整数）过渡金属原子和2（n1）二齿有机配体，二齿有机配体包括衍生自 多羟基化合物通过连接基团形成，并且形成为使得来自多羟基化合物的基团朝向中空壳体的内部空间。 还提供：包含多面体过渡金属络合物的超细颗粒的过渡金属络合物和金属氧化物的超细颗粒，超细颗粒包含在多面体过渡金属络合物的中空壳内; 其制造方法。 因此，本发明提供了一种多面体过渡金属络合物，其可以有效地生产具有几纳米的均匀粒径的金属氧化物颗粒，其中在多面体结构内包含金属氧化物颗粒的超细颗粒的多面体过渡金属络合物， 制作方法