公开(公告)号：US5218083A

公开(公告)日：1993-06-08

申请号：US429574

申请日：1989-10-31

申请人： Margaret K. Gerber ,  Terry L. St. Clair ,  J. Richard Pratt ,  Anne K. St. Clair

发明人： Margaret K. Gerber ,  Terry L. St. Clair ,  J. Richard Pratt ,  Anne K. St. Clair

IPC分类号： C08G73/10

CPC分类号： C08G73/1085 ,  C08G73/1039 ,  C08G73/106 ,  C08G73/1064

摘要： High performance, thermooxidatively stable polyimides are prepared by reacting aromatic diamines with pendant trifluoromethyl groups and dianhydrides in an amide solvent to form a poly(amic acid), followed by cyclizing the poly(amic acid) to form the corresponding polyimide, which has the following general structure: ##STR1##

摘要翻译： 通过使芳族二胺与侧基三氟甲基和二酐在酰胺溶剂中反应形成聚（酰胺酸）制备高性能，热氧化稳定的聚酰亚胺，然后使聚（酰胺酸）环化形成相应的聚酰亚胺，其具有以下 一般结构：其中R是任何芳族或取代的芳族基团，Ar是任何芳族或取代的芳族基团，n APPROX 10-100。

公开(公告)号：US5189127A

公开(公告)日：1993-02-23

申请号：US801867

申请日：1991-12-03

申请人： Margaret K. Gerber ,  Terry L. St. Clair

发明人： Margaret K. Gerber ,  Terry L. St. Clair

IPC分类号： C08F38/00 ,  C08F290/06 ,  C08G73/10

CPC分类号： C08F290/06 ,  C08F38/00 ,  C08G73/101 ,  C08G73/1071

摘要： The compound N-(3-ethynylphenyl)maleimide (NEPMI) was used to prepare thermally stable, glassy polyimides which did not exhibit glass transition temperatures below 500.degree. C. NEPMI was blended with the maleimide of methylene dianiline (BMI) and heated to form the polyimide. NEPMI was also mixed with Thermid 600.RTM., a commercially available bisethynyl oligomeric material, and heated to form a thermally stable, glassy polyimide. Lastly, NEPMI was blended with both BMI and Thermid 600.RTM. to form thermally stable, glassy polyimides.

摘要翻译： 使用化合物N-（3-乙炔基苯基）马来酰亚胺（NEPMI）制备热稳定的玻璃化聚酰亚胺，其不显示低于500℃的玻璃化转变温度。将NEPMI与亚甲基二苯胺（BMI）的马来酰亚胺共混并加热形成 聚酰亚胺。 NEPMI也与市售的双乙炔基低聚物材料Thermid 600 TM混合，并加热形成热稳定的玻璃状聚酰亚胺。 最后，NEPMI与BMI和Thermid 600 TM混合以形成热稳定的玻璃状聚酰亚胺。

公开(公告)号：US5189129A

公开(公告)日：1993-02-23

申请号：US801868

申请日：1991-12-03

申请人： Margaret K. Gerber ,  Terry L. St. Clair

发明人： Margaret K. Gerber ,  Terry L. St. Clair

IPC分类号： C08F38/00 ,  C08F290/06 ,  C08G73/10

CPC分类号： C08F38/00 ,  C08F290/06 ,  C08G73/101 ,  C08G73/1071

摘要： Thermally stable, glassy polymeric materials were prepared from maleimideacetylene terminated monomeric materials by several methods. The monomers were heated to self-polymerize. The A-B structure of the monomer allowed it to polymerize with either bismaleimide monomers/oligomers or bis-acetylene monomers/oligomers. Copolymerization can also take place by mixing bismaleimide and bisacetylene monomers/oligomers with the maleimide-acetylene terminated monomers to yield homogenous glassy polymers.

摘要翻译： 通过几种方法由马来酰亚胺乙炔封端的单体材料制备热稳定的玻璃状聚合物材料。 将单体加热以自聚合。 单体的A-B结构允许其与双马来酰亚胺单体/低聚物或双 - 乙炔单体/低聚物聚合。 共聚也可以通过将双马来酰亚胺和双乙炔单体/低聚物与马来酰亚胺 - 乙炔封端的单体混合以产生均匀的玻璃状聚合物来进行。