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公开(公告)号：US5529684A
公开(公告)日：1996-06-25
申请号：US440438
申请日：1995-05-12
CPC分类号： C10G32/02
摘要： The present invention provides for a method of decreasing the metals content of metal containing petroleum streams by forming a mixture of the petroleum fraction containing those metals and an essentially aqueous electrolysis medium, and passing an electric current through the mixture at a voltage, pH and time sufficient to remove the metals such as Ni, V and Fe from the stream (i.e. to produce a petroleum fraction having decreased content of the metals). The cathodic voltage is from 0 V to -3.0 V vs. SCE at a pH of from 6 to 14, preferably 7 to 14, most preferably above 7 to 14.The invention provides a method for enhancing the value of petroleum feeds that traditionally have limited use in refineries due to their Ni and V content.
摘要翻译： 本发明提供了一种通过形成含有这些金属的石油馏分和基本上含水的电解介质并使电流在电压，pH和时间下通过混合物的混合物来降低含金属的石油流的金属含量的方法 足以从流中除去诸如Ni，V和Fe的金属（即产生具有降低的金属含量的石油馏分）。 pH为6至14，优选7至14，最优选高于7至14时，阴极电压为0 V至-3.0 V，相对于SCE。本发明提供了一种增强传统上具有 由于其Ni和V含量，炼油厂的使用受到限制。
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公开(公告)号：US5514252A
公开(公告)日：1996-05-07
申请号：US440439
申请日：1995-05-12
摘要： The present invention provides a method for decreasing the Conradson carbon ("Concarbon") number of petroleum feedstreams by passing an electric current through a mixture of a petroleum stream, typically having a Conradson carbon residue of at least about 0.1% and an aqueous electrolysis medium at a pH and cathodic voltage for a time sufficient to decrease the Conradson carbon number of the petroleum stream. The electrolysis medium contains quaternary carbyl or hydrocarbyl onium salts; inorganic hydroxides such as NaOH or KOH, or mixtures thereof. A cathodic voltage of 0 V to -3.0 V vs. Saturated Calomel Electrode (SCE) and a pH of 6-14, preferably 7 to 14, more preferably above 7 to 14 are used.The invention has utility for converting less economically desirable refinery feeds to feeds that are more valuable.
摘要翻译： 本发明提供了一种通过使电流通过典型地具有至少约0.1％的康拉多森碳残余物的石油流和水电解介质的混合物来降低石油原料流的康拉多森碳（“碳”）数的方法 在pH和阴极电压下时间足以降低石油流的康拉多森碳数。 电解介质含有季碳基或烃基鎓盐; 无机氢氧化物如NaOH或KOH，或其混合物。 使用0V至-3.0V对饱和马洛代尔电极（SCE）的阴极电压和6-14，优选7至14，更优选高于7至14的pH。 本发明具有将经济上较少的炼油原料转化成更有价值的进料的效用。
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