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公开(公告)号：US20110224386A1
公开(公告)日：2011-09-15
申请号：US13130139
申请日：2009-11-12
申请人： Martin Weber , Christian Maletzko , Gerhard Lange , Jörg Erbes , Matthias Dietrich , Nicholas Inchaurrondo , Tobias Kortekamp , Bernd Trotte
发明人： Martin Weber , Christian Maletzko , Gerhard Lange , Jörg Erbes , Matthias Dietrich , Nicholas Inchaurrondo , Tobias Kortekamp , Bernd Trotte
摘要： The present invention relates to a process for the preparation of a polymer composition comprising (a) the provision of at least one polyarylene ether (P) having predominantly terminal phenolate groups in the presence of a solvent (L), (b) the addition of at least one polyfunctional carboxylic acid and (c) the isolation of the polymer composition as a solid. The present invention also relates to polymer compositions obtainable by the process, mixtures which comprise these polyarylene ethers and the use of the polymer compositions according to the invention for toughening epoxy resins.
摘要翻译： 本发明涉及一种制备聚合物组合物的方法，其包括（a）在溶剂（L）存在下，提供至少一种主要具有末端酚盐基团的聚亚芳基醚（P），（b）添加 至少一种多官能羧酸和（c）聚合物组合物作为固体的分离。 本发明还涉及通过该方法获得的聚合物组合物，其包含这些聚亚芳基醚的混合物以及根据本发明的聚合物组合物用于增韧环氧树脂的用途。
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2.发明授权Process for preparing polyoxymethylene homopolymers or copolymers by homopolymerization or copolymerization of trioxane, starting from methanol 失效通过三恶烷的均聚或共聚制备聚甲醛均聚物或共聚物的方法，从甲醇开始公开(公告)号：US08378144B2
公开(公告)日：2013-02-19
申请号：US12747742
申请日：2008-12-11
IPC分类号： C07C213/00
CPC分类号： C07D323/06 , C08G2/10
摘要： A process for preparing polyoxymethylene homopolymers or copolymers (7) by homopolymerization or copolymerization of trioxane, starting from methanol (1), in which methanol (1) is oxidized in a first reactor in a first production plant (A) to give an aqueous formaldehyde-comprising stream (2) which is fed to a second production plant (B) in which pure trioxane (6) is obtained and removal of low boilers (5) by distillation is carried out and the pure trioxane (6) is fed to a third production plant (C) in which it is homopolymerized or copolymerized to form polyoxymethylene homopolymers or copolymers (7), wherein the low boiler stream (5) from the low boiler removal column (K 2) is recycled to the feed stream into the first reactor in the first production plant (A), is proposed.
摘要翻译： 从甲醇（1）开始，通过三恶烷的均聚或共聚制备聚甲醛均聚物或共聚物（7）的方法，其中甲醇（1）在第一生产设备（A）中的第一反应器中被氧化，得到甲醛水溶液 （2），其被供给到其中获得纯三恶烷（6）并通过蒸馏除去低锅炉（5）的第二生产设备（B），并将纯三恶烷（6）进料至 第三生产厂（C），其中其被均聚或共聚以形成聚甲醛均聚物或共聚物（7），其中来自低锅炉除去塔（K 2）的低沸点物流（5）被再循环到进料流中， 提出了第一个生产厂（A）中的反应堆。
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3.发明申请PROCESS FOR PREPARING POLYOXYMETHYLENE HOMOPOLYMERS OR COPOLYMERS BY HOMOPOLYMERIZATION OR COPOLYMERIZATION OF TRIOXANE, STARTING FROM METHANOL 失效制备聚甲基苯乙烯共聚物或共聚物的方法，由三元共聚物的共聚合或共聚合，从甲醇开始公开(公告)号：US20100280195A1
公开(公告)日：2010-11-04
申请号：US12747742
申请日：2008-12-11
CPC分类号： C07D323/06 , C08G2/10
摘要： A process for preparing polyoxymethylene homopolymers or copolymers (7) by homopolymerization or copolymerization of trioxane, starting from methanol (1), in which methanol (1) is oxidized in a first reactor in a first production plant (A) to give an aqueous formaldehyde-comprising stream (2) which is fed to a second production plant (B) in which pure trioxane (6) is obtained and removal of low boilers (5) by distillation is carried out and the pure trioxane (6) is fed to a third production plant (C) in which it is homopolymerized or copolymerized to form polyoxymethylene homopolymers or copolymers (7), wherein the low boiler stream (5) from the low boiler removal column (K 2) is recycled to the feed stream into the first reactor in the first production plant (A), is proposed.
摘要翻译： 从甲醇（1）开始，通过三恶烷的均聚或共聚制备聚甲醛均聚物或共聚物（7）的方法，其中甲醇（1）在第一生产设备（A）中的第一反应器中被氧化，得到甲醛水溶液 （2），其被供给到其中获得纯三恶烷（6）并通过蒸馏除去低锅炉（5）的第二生产设备（B），并将纯三恶烷（6）进料至 第三生产厂（C），其中其被均聚或共聚以形成聚甲醛均聚物或共聚物（7），其中来自低锅炉除去塔（K 2）的低沸点物流（5）被再循环到进料流中， 提出了第一个生产厂（A）中的反应堆。
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