公开(公告)号：US5700617A

公开(公告)日：1997-12-23

申请号：US727219

申请日：1996-10-08

申请人： Tsuyoshi Takiguchi ,  Kenji Okado ,  Masaaki Taya ,  Ryoichi Fujita ,  Makoto Kanbayashi ,  Wakashi Iida ,  Tetsuya Ida

发明人： Tsuyoshi Takiguchi ,  Kenji Okado ,  Masaaki Taya ,  Ryoichi Fujita ,  Makoto Kanbayashi ,  Wakashi Iida ,  Tetsuya Ida

IPC分类号： G03G9/097 ,  H01B1/00 ,  H01B1/06

CPC分类号： G03G9/09733 ,  G03G9/09708 ,  G03G9/09783

摘要： A toner for developing an electrostatic image is formed from toner particles containing a binder resin, a colorant, and a charge-controlling agent. The charge-controlling agent comprises an aromatic oxycarboxylic acid, a metal compound of the aromatic oxycarboxylic acid, and an inorganic compound formed from an inorganic anion and an inorganic cation. The aromatic oxycarboxylic acid, the metal compound of the aromatic carboxylic acid and the inorganic anion are contained in proportions of A (wt. %), B (wt. %) and C (ppm), respectively, satisfying the following conditions: 1/99.ltoreq.A/B.ltoreq.20/80, and 10.sup.2 .ltoreq.C. Because of the inclusion of an inorganic compound providing a sufficient amount of inorganic anion, the charge-controlling agent shows a stable charge-controlling characteristic, and the resultant toner exhibits a stable developing performance and transferability in continuous image formation in various environmental conditions.

摘要翻译： 用于显影静电图像的调色剂由含有粘合剂树脂，着色剂和电荷控制剂的调色剂颗粒形成。 电荷控制剂包括芳族羟基羧酸，芳族羟基羧酸的金属化合物和由无机阴离子和无机阳离子形成的无机化合物。 芳族羟基羧酸，芳族羧酸的金属化合物和无机阴离子分别以A（重量％），B（重量％）和C（ppm）的比例包含，满足以下条件：1 / 99 。 由于含有提供足够量的无机阴离子的无机化合物，电荷控制剂显示出稳定的电荷控制特性，并且所得调色剂在各种环境条件下表现出稳定的连续成像的显影性能和转印性。

公开(公告)号：US5747209A

公开(公告)日：1998-05-05

申请号：US640077

申请日：1996-04-30

申请人： Tsuyoshi Takiguchi ,  Kenji Okado ,  Masaaki Taya ,  Ryoichi Fujita ,  Makoto Kanbayashi ,  Kohji Inaba ,  Wakashi Iida ,  Kazunori Kato ,  Tetsuya Ida ,  Shinya Yachi

发明人： Tsuyoshi Takiguchi ,  Kenji Okado ,  Masaaki Taya ,  Ryoichi Fujita ,  Makoto Kanbayashi ,  Kohji Inaba ,  Wakashi Iida ,  Kazunori Kato ,  Tetsuya Ida ,  Shinya Yachi

IPC分类号： G03G9/083 ,  G03G9/087 ,  G03G9/09 ,  G03G9/097 ,  G03G9/00

CPC分类号： G03G9/09783 ,  G03G9/09733

摘要： A toner for developing electrostatic images is formed of toner particles comprising (a) a binder resin, (b) a colorant or magnetic material, (c) an aromatic hydroxycarboxylic acid (A), and (d) a metal compound of the aromatic hydroxycarboxylic acid (A). The aromatic hydroxycarboxylic acid (A) and the metal compound of the aromatic hydroxycarboxylic acid (A) are contained in a weight ratio of 1:99 to 10:90. As a result of co-inclusion of a small amount of the aromatic hydroxycarboxylic acid (A) in addition to the metal compound thereof, the resultant toner is provided with a quick chargeability in a low humidity environment and an improved level of triboelectric charge in a high humidity environment, presumably because of the stabilization effect of the small amount of the aromatic hydroxycarboxylic acid (A) on the metal compound thereof.

摘要翻译： 用于显影静电图像的调色剂由调色剂颗粒形成，包括（a）粘合剂树脂，（b）着色剂或磁性材料，（c）芳族羟基羧酸（A），和（d）芳族羟基羧酸的金属化合物 酸（A）。 芳香族羟基羧酸（A）和芳香族羟基羧酸（A）的金属化合物的重量比为1:99〜10:90。 作为除了其金属化合物之外少量芳族羟基羧酸（A）共混物的结果，所得到的调色剂在低湿度环境中具有快速带电性，并且提供了一种改善的摩擦带电量 高湿度环境，大概是因为少量芳族羟基羧酸（A）对其金属化合物的稳定作用。

公开(公告)号：US5851714A

公开(公告)日：1998-12-22

申请号：US825395

申请日：1997-03-28

申请人： Masaaki Taya ,  Kenji Okado ,  Ryoichi Fujita ,  Makoto Kanbayashi ,  Tsuyoshi Takiguchi ,  Wakashi Iida ,  Tetsuya Ida

发明人： Masaaki Taya ,  Kenji Okado ,  Ryoichi Fujita ,  Makoto Kanbayashi ,  Tsuyoshi Takiguchi ,  Wakashi Iida ,  Tetsuya Ida

IPC分类号： G03G9/08 ,  G03G9/087 ,  G03G9/097

CPC分类号： G03G9/08797 ,  G03G9/081 ,  G03G9/08755 ,  G03G9/08793 ,  G03G9/08795

摘要： A toner for developing an electrostatic image is formed from toner particles containing at least a binder resin, a colorant and an organometallic compound. The binder resin in the toner particles has a tetrahydrofuran-insoluble (THF-insoluble) content of at most 5.0 wt.% based on the binder resin. The toner has a glass transition temperature of 50.degree.-80.degree. C. The toner further has storage modulus characteristics including a storage modulus at 80.degree. C. (G'.sub.80) of 1.times.10.sup.4 -5.times.10.sup.6 �dyn/cm.sup.2 !, a storage modulus at 130.degree. C. (G'.sub.130) providing a ratio G'.sub.80 /G'.sub.130 of 10-5.times.10.sup.3, and a storage modulus curve showing a minimum (G'min) in a temperature region of 110.degree.-190.degree. C. The toner especially exhibits excellent low-temperature fixability, anti-high temperature offset characteristic, storage stability and color-miscibility.

摘要翻译： 用于显影静电图像的调色剂由至少含有粘合剂树脂，着色剂和有机金属化合物的调色剂颗粒形成。 调色剂颗粒中的粘合剂树脂相对于粘合剂树脂具有至多5.0重量％的四氢呋喃不溶（THF不溶性）含量。 调色剂的玻璃化转变温度为50-80℃。该调色剂还具有储能模量特性，包括80℃下的储能模量（G'80）为1×104-5×106 [dyn / cm2]，储能模量 130℃（G'130），比率G'80 / G'130为10-5×103，储能模量曲线在110〜190℃的温度区域为最小值（G'min）。 调色剂特别表现出优异的低温定影性，抗高温偏移特性，储存稳定性和颜色混溶性。

公开(公告)号：US5670288A

公开(公告)日：1997-09-23

申请号：US599845

申请日：1996-02-12

申请人： Kenji Okado ,  Toshiyuki Ugai ,  Ryoichi Fujita ,  Makoto Kanbayashi ,  Tsuyoshi Takiguchi ,  Yasuhiro Ichikawa ,  Wakashi Iida

发明人： Kenji Okado ,  Toshiyuki Ugai ,  Ryoichi Fujita ,  Makoto Kanbayashi ,  Tsuyoshi Takiguchi ,  Yasuhiro Ichikawa ,  Wakashi Iida

IPC分类号： G03G9/09 ,  G03G9/097 ,  G03G9/10 ,  G03G9/107 ,  G03G13/09

CPC分类号： G03G9/10 ,  G03G9/0918 ,  G03G9/09708 ,  G03G9/09716 ,  G03G9/107

摘要： A carrier for electrophotography has carrier particles. The carrier has a 50% average particle diameter (D.sub.50) of from 15 .mu.m to 45 .mu.m and contains from 1% to 20% of carrier particles with a size smaller than 22 .mu.m, not more than 3% of carrier particles with a size smaller than 16 .mu.m, from 2% to 15% of carrier particles with a size of 62 .mu.m or larger, and not more than 2% of carrier particles with a size of 88 .mu.m or larger. The carrier has a specific surface area S.sub.1 as measured by an air-permeability method and a specific surface area S.sub.2 as calculated by the following expression: S.sub.2 =(6/.rho..multidot.D.sub.50).times.10.sup.4 wherein .rho. is a specific gravity of carrier; satisfying the following condition: 1.2 .ltoreq.S.sub.1 /S.sub.2 .ltoreq.2.0.

摘要翻译： 电子照相用载体具有载体颗粒。 载体具有15μm至45μm的50％平均粒径（D50），并且含有1％至20％的尺寸小于22μm的载体颗粒，不超过载体颗粒的3％ 尺寸小于16μm，尺寸为62μm或更大的载体颗粒的2％至15％，以及不大于2％的尺寸为88μm或更大的载体颗粒。 载体具有通过透气度测定的比表面积S1和通过下式计算的比表面积S2：S2 =（6 / rho×D50）×104其中rho是载体的比重; 满足以下条件：1.2

公开(公告)号：US5512402A

公开(公告)日：1996-04-30

申请号：US246146

申请日：1994-05-19

申请人： Kenji Okado ,  Toshiyuki Ugai ,  Ryoichi Fujita ,  Makoto Kanbayashi ,  Tsuyoshi Takiguchi ,  Yasuhiro Ichikawa ,  Wakashi Iida

发明人： Kenji Okado ,  Toshiyuki Ugai ,  Ryoichi Fujita ,  Makoto Kanbayashi ,  Tsuyoshi Takiguchi ,  Yasuhiro Ichikawa ,  Wakashi Iida

IPC分类号： G03G9/09 ,  G03G9/097 ,  G03G9/10 ,  G03G9/107 ,  G03G9/08

CPC分类号： G03G9/10 ,  G03G9/0918 ,  G03G9/09708 ,  G03G9/09716 ,  G03G9/107

摘要： A carrier for electrophotography has carrier particles. The carrier has a 50% average particle diameter (D.sub.50) of from 15 .mu.m to 45 .mu.m and contains from 1% to 20% of carrier particles with a size smaller than 22 .mu.m, not more than 3% of carrier particles with a size smaller than 16 .mu.m, from 2% to 15% of carrier particles with a size of 62 .mu.m or larger, and not more than 2% of carrier particles with a size of 88 .mu.m or larger. The carrier has a specific surface area S.sub.1 as measured by an air-permeability method and a specific surface area S.sub.2 as calculated by the following expression:S.sub.2 =(6/.rho..D.sub.50).times.10.sup.4wherein .rho. is a specific gravity of carrier; satisfying the following condition:1.2.ltoreq.S.sub.1 /S.sub.2 .ltoreq.2.0.

摘要翻译： 电子照相用载体具有载体颗粒。 载体具有15μm至45μm的50％平均粒径（D50），并且含有1％至20％的尺寸小于22μm的载体颗粒，不超过载体颗粒的3％ 尺寸小于16μm，尺寸为62μm或更大的载体颗粒的2％至15％，以及不大于2％的尺寸为88μm或更大的载体颗粒。 载体具有通过透气度法测定的比表面积S1和通过下式计算的比表面积S2：S2 =（6 / rho.D50）×104其中rho是载体的比重; 满足以下条件：1.2

公开(公告)号：US6077635A

公开(公告)日：2000-06-20

申请号：US99527

申请日：1998-06-18

申请人： Kenji Okado ,  Ryoichi Fujita ,  Wakashi Iida ,  Yuji Moriki ,  Kazumi Yoshizaki ,  Michihisa Magome

发明人： Kenji Okado ,  Ryoichi Fujita ,  Wakashi Iida ,  Yuji Moriki ,  Kazumi Yoshizaki ,  Michihisa Magome

IPC分类号： G03G9/08 ,  G03G9/097 ,  G03G13/01

CPC分类号： G03G9/0827 ,  G03G9/0819 ,  G03G9/09708

摘要： A toner is disclosed which has toner particles and an external additive. The toner has (a) in circularity distribution of particles measured with a flow type particle image analyzer, an average circularity of from 0.920 to 0.995, containing particles with a circularity of less than 0.950 in an amount of from 2% by number to 40% by number; and (b) a weight-average particle diameter of from 2.0 .mu.m to 9.0 .mu.m as measured by Coulter method. The external additive has, on the toner particles, at least (i) an inorganic fine powder (A) present in the state of primary particles or secondary particles and having an average particle length of from 10 m.mu.m to 400 m.mu.m and a shape factor SF-1 of from 100 to 130 and (ii) a non-spherical inorganic fine powder (B) formed by coalescence of a plurality of particles and having a shape factor SF-1 of greater than 150. Also, a two-component developer and an image forming method, using the toner, are disclosed.

摘要翻译： 公开了一种具有调色剂颗粒和外部添加剂的调色剂。 调色剂具有（a）以流动型颗粒图像分析仪测量的颗粒的圆形分布，平均圆形度为0.920至0.995，其中圆形度小于0.950的颗粒的量为2％至40％ 按数量 （b）通过Coulter法测定的重均粒径为2.0μm〜9.0μm。 外部添加剂在调色剂颗粒上至少存在（i）以一次粒子或二次粒子状态存在的平均粒子长度为10μm〜400μm的无机细粉末（A）， 100〜130的形状因子SF-1和（ii）通过多个粒子的聚结而形成的非球形的无机细粉末（B），并且具有大于150的形状因子SF-1。另外， - 组分显影剂和使用调色剂的图像形成方法。

公开(公告)号：US5620824A

公开(公告)日：1997-04-15

申请号：US272507

申请日：1994-07-07

申请人： Kenji Okado ,  Akihiko Nakazawa ,  Ryoichi Fujita ,  Makoto Kanbayashi

发明人： Kenji Okado ,  Akihiko Nakazawa ,  Ryoichi Fujita ,  Makoto Kanbayashi

IPC分类号： G03G9/08 ,  G03G9/097

CPC分类号： G03G9/08 ,  G03G9/0819 ,  G03G9/0823 ,  G03G9/097

摘要： A toner for developing an electrostatic image has colored resin particles-(A) containing a coloring agent or a magnetic powder, and a powdery additive. The powdery additive has organic resin particles-(B) having peaks respectively in a region of particles diameters of 20 m.mu. to 200 m.mu. and a region of particle diameters of 300 m.mu. to 800 m.mu. in their particle size distribution, and the larger-diameters particles included in the region of particle diameters of 300 m.mu. to 800 m.mu. being contained in an amount of from 2% by weight to 20% by weight.

摘要翻译： 用于显影静电图像的调色剂具有含有着色剂或磁性粉末的着色树脂颗粒 - （A）和粉末状添加剂。 粉末状添加剂具有分别在粒径20μm〜200μm的范围内具有峰值的有机树脂粒子，粒径分布为300μm〜800μm的粒子的区域， 包含在粒径为300μm至800μm的区域中的大直径粒子的含量为2重量％至20重量％。

公开(公告)号：US06316156B1

公开(公告)日：2001-11-13

申请号：US08493009

申请日：1995-06-21

申请人： Tsuyoshi Takiguchi ,  Kenji Okado ,  Tetsuya Ida

发明人： Tsuyoshi Takiguchi ,  Kenji Okado ,  Tetsuya Ida

IPC分类号： G03G9087

CPC分类号： G03G9/107 ,  G03G9/0821 ,  G03G9/08755

摘要： A carrier for electrophotography and a two component type developer using the carrier. The carrier is composed of magnetic particles of a magnetic ferrite component represented by Formula: (Fe2O3)X(MnO)Y(A)Z. An image forming method is also disclosed which uses the two component type developer.

摘要翻译： 用于电子照相的载体和使用载体的双组分型显影剂。 载体由以下公式表示的磁性铁氧体组分的磁性颗粒组成：还公开了使用双组分型显影剂的图像形成方法。

公开(公告)号：US06641967B2

公开(公告)日：2003-11-04

申请号：US10107053

申请日：2002-03-28

申请人： Tsuyoshi Takiguchi ,  Kenji Okado ,  Tetsuya Ida

发明人： Tsuyoshi Takiguchi ,  Kenji Okado ,  Tetsuya Ida

IPC分类号： G03G1308

CPC分类号： G03G9/107 ,  G03G9/0821 ,  G03G9/08755

摘要： A carrier for electrophotography and a two component type developer using the carrier. The carrier is composed of magnetic particles of a magnetic ferrite component represented by Formula: (Fe2O3)X(MnO)Y(A)Z. An image forming method is also disclosed which uses the two component type developer.

公开(公告)号：US5795693A

公开(公告)日：1998-08-18

申请号：US908624

申请日：1997-08-08

申请人： Kenji Okado ,  Tsuyoshi Takiguchi ,  Tetsuya Ida

发明人： Kenji Okado ,  Tsuyoshi Takiguchi ,  Tetsuya Ida

IPC分类号： G03G9/083 ,  G03G9/107 ,  G03G9/113 ,  G03G9/10

CPC分类号： G03G9/0833 ,  G03G9/0834 ,  G03G9/107 ,  G03G9/1136 ,  G03G9/1137

摘要： A carrier for electrophotography is constituted by magnetic carrier core particles and a resin coating layer coating the magnetic carrier core particles. The carrier core particles contain a magnetic ferrite component represented by the following formula (I): (Fe.sub.2 O.sub.3).sub.x (A).sub.y (B).sub.z (I), wherein A denotes a member selected from the group consisting of MgO, AgO and mixtures thereof; B denotes a member selected from the group consisting of Li.sub.2 O, MnO, CaO, SrO, Al.sub.2 O.sub.3, SiO.sub.2 and mixtures thereof; and x, y and z are numbers representing weight ratios and satisfying the relation of: 0.2.ltoreq.x.ltoreq.0.95, 0.005.ltoreq.y.ltoreq.0.3, 0

摘要翻译： 用于电子照相的载体由磁性载体芯颗粒和涂覆磁性载体芯颗粒的树脂涂层构成。 载体芯颗粒包含由下式（I）表示的磁性铁氧体组分:( Fe 2 O 3）x（A）y（B）z（I），其中A表示选自MgO，AgO和混合物 的; B表示选自Li2O，MnO，CaO，SrO，Al2O3，SiO2及其混合物的成员; 并且x，y和z是表示重量比的数字，并且满足以下关系：0.2≤x≤0.95,0.003≤y≤0.3,0≤z≤0.795，x + y + z