-
公开(公告)号:US20050227071A1
公开(公告)日:2005-10-13
申请号:US10500433
申请日:2002-12-30
申请人: Masahiro Muraoka , Stephen Gillett , Thomas Bell
发明人: Masahiro Muraoka , Stephen Gillett , Thomas Bell
CPC分类号: B82Y10/00 , H01L51/0083 , H01L51/0595 , H01M14/005 , Y10T428/2991 , Y10T428/2998 , Y10T428/31663
摘要: The invention relates to redox-switchable material comprising a redox-active moiety adsorbed, bonded or both, to a semiconductor material. Among the preferred redox-active moieties disclosed herein are ferrocenes, acridines, and quinones though any such moiety may be employed. The redox-switchable material of this invention may be used to selectively remove one or more selected solutes from an aqueous solution wherein adsorption/complexation of the solute is influenced by the oxidation state of the redox-active moiety. In an alternative embodiment, inclusion moieties that are covalently bound to the redox-active moiety are employed to achieve selective complexation of the desired solute. Other possible applications of the disclosed materials are photoerasable writing media, electrochromic or photochromic materials, catalysis, and solar energy storage.
摘要翻译: 本发明涉及包含与半导体材料吸附,结合或两者的氧化还原活性部分的氧化还原可切换材料。 在本文公开的优选的氧化还原活性部分中,可以使用任何这样的部分的二茂铁,吖啶和醌。 本发明的氧化还原可切换材料可用于从其中吸附/络合溶质受氧化还原活性部分的氧化态影响的水溶液中选择性地除去一种或多种选择的溶质。 在一个替代实施方案中,共价结合氧化还原活性部分的包合物部分用于实现所需溶质的选择性络合。 所公开材料的其它可能的应用是可照相的书写介质,电致变色或光致变色材料,催化和太阳能储存。