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公开(公告)号:US20210154623A1
公开(公告)日:2021-05-27
申请号:US17165025
申请日:2021-02-02
申请人: Mitsubishi Chemical Corporation , JAPAN TECHNOLOGICAL RESEARCH ASSOCIATION OF ARTIFICIAL PHOTOSYNTHETIC CHEMICAL PROCESS
发明人: Masamichi ONUKI , Naoyuki SAKAMOTO , Susumu TSUTSUMINAI , Koetsu ENDOU , Naoko FUJITA , Misa HARA , Masahiro KUJIME , Nobuo TORATANI
IPC分类号: B01D69/10 , B01D69/12 , B01D71/02 , C07C29/152
摘要: The present invention addresses the problem of providing a bonded body which has a high airtightness and exhibits excellent durability under high-temperature and high-pressure conditions. This problem is solved by a bonded body in which a complex of a zeolite and an inorganic porous support, and a dense member are bonded together by an inorganic glass or an inorganic adhesive. The inorganic glass or the inorganic adhesive has a thermal expansion coefficient of 30×10−7/K to 90×10−7/K, and the inorganic glass has a softening point of 550° C. or lower. The present invention also addresses the problem of providing a method of efficiently producing an alcohol by installing a separation membrane in an alcohol synthesis reactor based on a bonding method that gives good sealing performance and durability under high-temperature and high-pressure conditions and in the presence of methanol vapor. This problem can be solved by an alcohol production method of obtaining an alcohol by allowing a raw material gas, which contains at least hydrogen and carbon monoxide and/or carbon dioxide, to react in the presence of a catalyst in a reactor. In the reactor for carrying out the reaction, an alcohol-selective permeable membrane bonded with a dense member is installed, and an alcohol generated by the reaction permeates and is recovered through the selective permeable membrane.