公开(公告)号：US20250144591A1

公开(公告)日：2025-05-08

申请号：US18832658

申请日：2023-03-23

Applicant: North Carolina State University

Inventor： Malek Y.S. Ibrahim ,  Milad Abolhassani

IPC: B01J19/12 ,  B01J8/06 ,  B01J19/24 ,  C01B3/26

Abstract: The present disclosure relates to a photoreactor and method of use thereof. In an aspect, the photoreactor can be configured as a solar panel comprising a channel containing a heterogeneous photocatalyst. When water or another hydrogen-containing liquid is pumped through the photoreactor, it contacts the photocatalyst in the presence of UV or visible irradiation, simultaneously releasing hydrogen and separating the hydrogen via a gas-permeable membrane. In an aspect, the photoreactor can be used in a method for continuous production of high-purity H2 gas, the method comprising dehydrogenating tetrahydroquinoline (THQ) to form quinoline under visible light using a Rh/TiO2 heterogeneous photocatalyst. In another aspect, the catalyst includes Rh particles photodeposited on TiO2 microparticles. In a further aspect, the method can include regenerating THQ from quinoline using a water gas shift (WGS) reaction.

公开(公告)号：US20250019334A1

公开(公告)日：2025-01-16

申请号：US18577060

申请日：2022-07-07

Applicant: NORTH CAROLINA STATE UNIVERSITY

Inventor： Milad Abolhasani ,  Malek Y.S. Ibrahim

IPC: C07C45/50 ,  B01J23/46 ,  B01J31/22

Abstract: Described are processes for preparing linear and branched aldehydes, which comprises reacting an olefin with hydrogen and carbon monoxide in the presence of a catalyst solution comprising rhodium, a hydroformylation solvent, and a fluorophosphite ligand having the general formula (I).