THERMALLY EXPANDABLE MICROSPHERES PREPARED FROM BIO-BASED MONOMERS

    公开(公告)号:US20220220274A1

    公开(公告)日:2022-07-14

    申请号:US17656899

    申请日:2022-03-29

    摘要: The present invention relates to thermally expandable microspheres at least partially prepared from bio-based monomers and to a process of their manufacture. The microspheres comprise a thermoplastic polymer shell encapsulating a blowing agent, wherein the thermoplastic polymer shell comprises a polymer being a homo- or copolymer of a lactone according to formula (1): wherein each of R1, R2, R3, R4, separately from one another, is selected from the group consisting of H and an alkyl group preferably with 1-4 carbon atoms. The invention further provides expanded microspheres, which can be used in a variety of applications.

    THERMALLY EXPANDABLE MICROSPHERES PREPARED FROM BIO-BASED MONOMERS

    公开(公告)号:US20200216631A1

    公开(公告)日:2020-07-09

    申请号:US16644448

    申请日:2018-09-04

    摘要: The present invention relates to thermally expandable microspheres at least partially prepared from bio-based monomers and to a process of their manufacture. The microspheres comprise a thermoplastic polymer shell encapsulating a blowing agent, wherein the thermoplastic polymer shell comprises a polymer being a homo- or copolymer of a lactone according to formula (1): wherein each of R1, R2, R3, R4, separately from one another, is selected from the group consisting of H and an alkyl group preferably with 1-4 carbon atoms. The invention further provides expanded microspheres, which can be used in a variety of applications.

    THERMALLY EXPANDABLE MICROSPHERES PREPARED FROM BIO-BASED MONOMERS

    公开(公告)号:US20200347197A1

    公开(公告)日:2020-11-05

    申请号:US16758637

    申请日:2018-11-20

    摘要: The present invention relates to thermally expandable microspheres at least partially prepared from bio-based monomers and to a process of their manufacture. The microspheres comprise a thermoplastic polymer shell encapsulating a blowing agent, wherein the thermoplastic polymer shell comprises a copolymer of an itaconate dialkylester and at least one aliphatic or aromatic mono-ethylenically unsaturated comonomer, wherein the itaconate dialkylester is according to formula (1): wherein each of R1 and R2, separately from one another, is an alkyl group preferably with 1-4 carbon atoms, and wherein the copolymer contains 0-50 wt. % of vinyl aromatic comonomers, based on the total weight of the comonomers. The invention further provides expanded microspheres, which can be used in a variety of applications.