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    Five-coordinate phosphorous compound, process for producing the same and its use
    1.
    发明授权
    Five-coordinate phosphorous compound, process for producing the same and its use 失效
    五配位磷化合物，其制备方法及其用途

    公开(公告)号：US5902516A

    公开(公告)日：1999-05-11

    申请号：US908202

    申请日：1997-08-07

    申请人： Naoki Inui ,  Taketoshi Kikuchi ,  Kanako Fukuda ,  Takashi Sanada

    发明人： Naoki Inui ,  Taketoshi Kikuchi ,  Kanako Fukuda ,  Takashi Sanada

    IPC分类号： C07F9/6571 ,  C07F9/6578 ,  C08K5/51 ,  C09K15/32 ,  C07D327/00 ,  C07F9/02

    CPC分类号： C08K5/51 ,  C07F9/6571 ,  C07F9/6578 ,  C09K15/324

    摘要： A five-coordinate phosphorous compound which is useful as an stabilizer for organic materials and represented by the formula (I): ##STR1## wherein R.sup.1, R.sup.2, R.sup.4 and R.sup.5 independently represent hydrogen atom, an alkyl group, a cycloalkyl group, an alkylcycloalkyl group, an aralkyl group or a phenyl group; R.sup.3 represents hydrogen atom or an alkyl group; X represents a direct bond, a sulfur atom or a group represented by --CHR.sup.6 -- wherein R.sup.6 represents hydrogen atom, an alkyl group or a cycloalkyl group, and a process for producing the compound (I) are provided.

    摘要翻译： 可用作有机材料稳定剂并由式（I）表示的五配位磷化合物：其中R1，R2，R4和R5独立地表示氢原子，烷基，环烷基，烷基环烷基， 芳烷基或苯基; R3表示氢原子或烷基; X表示直接键，硫原子或-CHR 6 - 表示的基团，其中R 6表示氢原子，烷基或环烷基，以及制备化合物（I）的方法。

    Phosphite, a process for producing the same and a use thereof
    2.
    发明授权
    Phosphite, a process for producing the same and a use thereof 失效
    亚磷酸酯，其制备方法及其用途

    公开(公告)号：US6075159A

    公开(公告)日：2000-06-13

    申请号：US961183

    申请日：1997-10-30

    申请人： Naoki Inui ,  Taketoshi Kikuchi ,  Kanako Fukuda ,  Takashi Sanada

    发明人： Naoki Inui ,  Taketoshi Kikuchi ,  Kanako Fukuda ,  Takashi Sanada

    IPC分类号： C09K15/32 ,  C07F9/145 ,  C07F9/6574 ,  C07F9/6578 ,  C08K5/526 ,  C08L23/00 ,  C08L101/00 ,  C07F9/06

    CPC分类号： C08K5/526 ,  C07F9/145 ,  C07F9/65744 ,  C07F9/6578

    摘要： A phosphite represented by the formula (I): ##STR1## wherein n repesents 1 or 2; A represents alkylene; B represents a direct bond or alkylene; one of Y and Z represents a hydroxyl group, alkoxy or aralkyloxy, and the other one represents a hydrogen atom or alkyl; X represents a group of formula (II): ##STR2## wherein R.sup.1 and R.sup.2 represent a hydrogen atom, an alkyl group, a cycloalkyl group, an alkylcycloalkyl group, an aralkyl group or a phenyl group; R.sup.3 represents a hydrogen atom or an alkyl group; and R.sup.4 represents a hydrogen atom, an alkyl group, a cycloalkyl group, an alkylcycloalkyl group, an aralkyl group or a phenyl group, or R.sup.4 may be combined to form a direct bond, a sulfur bond (--S--), or an unsubstituted or substituted methylene group; R.sup.5 and R.sup.6 independently represent a hydrogen atom, an alkyl group, a cycloalkyl group, an alkylcycloalkyl group, an aralkyl group or a phenyl group;R.sup.8 represents a hydrogen atom or an alkyl group; andR.sup.7 represents a hydrogen atom or an alkyl group or --CH(R8)--A--O--X; and the organic phosphorus compound is useful as a stabilizer for an organic material.

    摘要翻译： 由式（I）表示的亚磷酸酯：其中n个取代基1或2; A表示亚烷基; B表示直接键或亚烷基; Y和Z之一表示羟基，烷氧基或芳烷氧基，另一个表示氢原子或烷基; X表示式（II）的基团：其中R1和R2表示氢原子，烷基，环烷基，烷基环烷基，芳烷基或苯基; R3表示氢原子或烷基; 并且R 4表示氢原子，烷基，环烷基，烷基环烷基，芳烷基或苯基，或R 4可以结合形成直接键，硫键（-S-）或未取代的 或取代的亚甲基; R5和R6独立地表示氢原子，烷基，环烷基，烷基环烷基，芳烷基或苯基; R8表示氢原子或烷基; 并且R 7表示氢原子或烷基或-CH（R 8）-A-O-X; 有机磷化合物可用作有机材料的稳定剂。

    Phosphites, process for producing them and their use
    3.
    发明授权
    Phosphites, process for producing them and their use 失效
    亚磷酸酯，生产它们的过程及其用途

    公开(公告)号：US5891939A

    公开(公告)日：1999-04-06

    申请号：US906972

    申请日：1997-08-06

    申请人： Taketoshi Kikuchi ,  Naoki Inui ,  Kanako Fukuda ,  Takashi Sanada

    发明人： Taketoshi Kikuchi ,  Naoki Inui ,  Kanako Fukuda ,  Takashi Sanada

    IPC分类号： C07F9/6574 ,  C07F9/6578 ,  C08K5/527 ,  C07F9/02

    CPC分类号： C08K5/527 ,  C07F9/65744 ,  C07F9/6578

    摘要： Phosphites inhibitors for organic material represented by the formula: ##STR1## wherein R.sup.1, R.sup.2, R.sup.4 and R.sup.5 independently represent hydrogen atom, an alkyl group, a cycloalkyl group, an alkylcycloalkyl group, an aralkyl group or a phenyl group; R.sup.3 is hydrogen atom or alkyl; X is a direct bond, sulfur atom, or methylene group which may optionally be substituted with alkyl or cycloalkyl; A represents a dihydric alcohol residue; B is a direct bond or alkylene; and one of Y and Z represents an alkoxy group or an aralkyloxy group, and the other one represents hydrogen atom or an alkyl group; and a process for producing the same are provided.

    摘要翻译： 由下式表示的有机材料用亚磷酸酯抑制剂：其中R1，R2，R4和R5独立地表示氢原子，烷基，环烷基，烷基环烷基，芳烷基或苯基; R3是氢原子或烷基; X是可以被烷基或环烷基任选取代的直接键，硫原子或亚甲基; A表示二元醇残基; B是直接键或亚烷基; Y和Z中的一个表示烷氧基或芳烷氧基，另一个表示氢原子或烷基; 并提供其制造方法。

    Phosphites, process for producing the same and their use
    4.
    发明授权
    Phosphites, process for producing the same and their use 失效
    亚磷酸酯，生产方法及其用途

    公开(公告)号：US5889095A

    公开(公告)日：1999-03-30

    申请号：US905329

    申请日：1997-08-04

    申请人： Naoki Inui ,  Taketoshi Kikuchi ,  Kanako Fukuda ,  Takashi Sanada

    发明人： Naoki Inui ,  Taketoshi Kikuchi ,  Kanako Fukuda ,  Takashi Sanada

    IPC分类号： C07F9/6574 ,  C07F9/6578 ,  C08K5/527 ,  C09K15/32 ,  C08K5/49 ,  C07C69/76

    CPC分类号： C07F9/65744 ,  C07F9/6578 ,  C08K5/527 ,  C09K15/322 ,  C09K15/324

    摘要： A phosphite stabilizer for organic material is represented by the formula (1): ##STR1## wherein R.sup.1, R.sup.2, R.sup.4 and R.sup.5 is hydrogen, alkyl, cycloalkyl, alkyl, cycloalkyl, aralkyl or phenyl; R is hydrogen or alkyl; X is a direct bond, sulfur atom or a --CHR.sup.6 group in which R.sup.6 represents hydrogen, alkyl or cycloalkyl; A is an alkylene group having 2 to 8 carbon atoms or *--COR.sup.7 -- in which R.sup.7 is a direct bond or alkyl group, and * represents the bond to the oxygen atom of the phenoxy radical; and one of Y and Z represents a hydroxyl group, an alkoxy group or an aralkoxy group and the other one represents atom or an alkyl group.

    摘要翻译： 用于有机材料的亚磷酸酯稳定剂由式（1）表示：其中R 1，R 2，R 4和R 5是氢，烷基，环烷基，烷基，环烷基，芳烷基或苯基; R是氢或烷基; X是直接键，硫原子或-CHR6基团，其中R6表示氢，烷基或环烷基; A是具有2-8个碳原子的亚烷基或* -COR7-，其中R7是直接键或烷基，*表示与苯氧基的氧原子的键; Y和Z中的一个表示羟基，烷氧基或芳烷氧基，另一个表示原子或烷基。

    Phosphites, process for producing them and their use
    5.
    发明授权
    Phosphites, process for producing them and their use 失效
    亚磷酸酯，生产它们的过程及其用途

    公开(公告)号：US5830936A

    公开(公告)日：1998-11-03

    申请号：US916229

    申请日：1997-08-22

    申请人： Taketoshi Kikuchi ,  Naoki Inui ,  Kanako Fukuda ,  Takashi Sanada

    发明人： Taketoshi Kikuchi ,  Naoki Inui ,  Kanako Fukuda ,  Takashi Sanada

    IPC分类号： C07F9/6574 ,  C07F9/6578 ,  C08K5/527 ,  C07F9/02

    CPC分类号： C08K5/527 ,  C07F9/65744 ,  C07F9/6578

    摘要： Phosphites which are a deterioration inhibitors for organic material represented by the formula: ##STR1## wherein R.sup.1 and R.sup.2 independently represent a hydrogen atom, or certain hydrocarbyl radicals; X represents a direct bond, a sulfur atom or a methylene group which may optionally be substituted; Z is --A.sup.1 --CO--O--Y.sup.1 or --A.sup.2 --O--CO--Y.sup.2 wherein A.sup.1 is a direct bond or an alkylene group; Y.sup.1 is aralkyl or aryl; A.sup.2 is a residue of a dihydric alcohol; and Y.sup.2 is alkyl, aralkyl or a phenyl group, and a process for producing the same are provided.

    摘要翻译： 作为由下式表示的有机材料的劣化抑制剂的亚磷酸酯：其中R 1和R 2独立地表示氢原子或某些烃基; X表示直接键，硫原子或可任选被取代的亚甲基; Z是-A1-CO-O-Y1或-A2-O-CO-Y2，其中A1是直接键或亚烷基; Y1是芳烷基或芳基; A2是二元醇的残基; 并且Y2是烷基，芳烷基或苯基，并且提供其制备方法。

    Phosphites, process for producing them and their use
    6.
    发明授权
    Phosphites, process for producing them and their use 失效
    亚磷酸酯，生产它们的过程及其用途

    公开(公告)号：US5874494A

    公开(公告)日：1999-02-23

    申请号：US917486

    申请日：1997-08-26

    申请人： Naoki Inui ,  Taketoshi Kikuchi ,  Kanako Fukuda ,  Takashi Sanada

    发明人： Naoki Inui ,  Taketoshi Kikuchi ,  Kanako Fukuda ,  Takashi Sanada

    IPC分类号： C07F9/145 ,  C07F9/6574 ,  C07F9/6578 ,  C08K5/526

    CPC分类号： C07F9/145 ,  C07F9/65744 ,  C07F9/6578 ,  C08K5/526

    摘要： Phosphites which are useful as a deterioration inhibitor for organic material and are represented by the following formula: ##STR1## wherein R.sup.1, R.sup.2, R.sup.5 and R.sup.6 represent a hydrogen atom, an alkyl group, a cycloalkyl group, an alkylcycloalkyl group, an aralkyl group or a phenyl group;R.sup.3 represents hydrogen atom or an alkyl group;R.sup.4 represents a hydrogen atom, an alkyl group, a cycloalkyl group, an alkylcycloalkyl group, an aralkyl group or a phenyl group, or the two R.sup.4 together form a direct bond, a group represented by --S-- or an optionally substituted methylene group;A represents an alkylene group;W represents a group represented by --O-- or a group represented by --NR.sup.7wherein R.sup.7 represents a hydrogen atom, an alkyl group, etc.;B represents an alkylene group;and one of Y and Z represents a hydroxyl group, an alkoxy group or an aralkyloxy group, and the other one represents hydrogen atom or an alkyl group.

    摘要翻译： 可用作有机材料的劣化抑制剂的亚磷酸酯并由下式表示：其中R 1，R 2，R 5和R 6表示氢原子，烷基，环烷基，烷基环烷基， 芳烷基或苯基; R3表示氢原子或烷基; R4表示氢原子，烷基，环烷基，烷基环烷基，芳烷基或苯基，或两者R4一起形成直接键，由-S-表示的基团或任选取代的亚甲基; A表示亚烷基; W表示由-O-表示的基团或由-NR 7表示的基团，其中R7表示氢原子，烷基等; B表示亚烷基; Y和Z中的一个表示羟基，烷氧基或芳烷氧基，另一个表示氢原子或烷基。

    Organic phosphorous compound, a process for producing the same and a use thereof
    8.
    发明授权
    Organic phosphorous compound, a process for producing the same and a use thereof 失效
    有机磷化合物，其制备方法及其用途

    公开(公告)号：US5847187A

    公开(公告)日：1998-12-08

    申请号：US942792

    申请日：1997-10-02

    申请人： Taketoshi Kikuchi ,  Naoki Inui ,  Kanaku Fukuda ,  Takashi Sanada

    发明人： Taketoshi Kikuchi ,  Naoki Inui ,  Kanaku Fukuda ,  Takashi Sanada

    IPC分类号： C07F9/24 ,  C07F9/6574 ,  C07F9/6578 ,  C07F9/6584 ,  C08K5/5399 ,  C07F9/06

    CPC分类号： C08K5/5399 ,  C07F9/2458 ,  C07F9/65744 ,  C07F9/6578 ,  C07F9/6584

    摘要： An organic phosphorous compound represented by the following formula (I): ##STR1## wherein R.sup.1, R.sup.2, R.sup.5 and R.sup.6 represent a hydrogen atom, an alkyl group, a cycloalkyl group, an alkylcycloalkyl group, an aralkyl group or a phenyl group; R.sup.3 represents a hydrogen atom or an alkyl group; R.sup.4 represents a hydrogen atom, an alkyl group, a cycloalkyl group, an alkylcycloalkyl group, an aralkyl group or a phenyl group, or the two R.sup.4 may be combined with each other to form a direct bond, a sulfur bond (--S--), or aN optionally substituted methylene group; R.sup.7 and R.sup.8 represent a hydrogen atom or an alkyl group, or R.sup.7 and R.sup.8 may be combined with each other to form an alkylene group; A represents an alkylene group; B represents a direct bond or an alkylene group; and one of Y and Z represents a hydroxyl group, an alkoxy group or an aralkyloxy group, and the other one represents a hydrogen atom or an alkyl group; and the organic phosphorous compound is useful as a stabilizer for an organic material.

    摘要翻译： 由下式（I）表示的有机磷化合物：其中R 1，R 2，R 5和R 6表示氢原子，烷基，环烷基，烷基环烷基，芳烷基或苯基 组; R3表示氢原子或烷基; R4表示氢原子，烷基，环烷基，烷基环烷基，芳烷基或苯基，或者两个R 4可以相互结合形成直接键，硫键（-S-） ，或aN任选取代的亚甲基; R 7和R 8表示氢原子或烷基，或者R 7和R 8可以相互结合形成亚烷基; A表示亚烷基; B表示直接键或亚烷基; Y和Z中的一个表示羟基，烷氧基或芳烷氧基，另一个表示氢原子或烷基; 有机磷化合物可用作有机材料的稳定剂。

    Air battery
    9.
    发明授权
    Air battery 有权
    空气电池

    公开(公告)号：US09379397B2

    公开(公告)日：2016-06-28

    申请号：US13877183

    申请日：2011-10-03

    申请人： Takitaro Yamaguchi ,  Takashi Sanada

    发明人： Takitaro Yamaguchi ,  Takashi Sanada

    IPC分类号： H01M8/04 ,  H01M12/06 ,  H01M2/40

    CPC分类号： H01M8/04276 ,  H01M2/40 ,  H01M12/06 ,  H01M12/065

    摘要： An air battery having a main body including a container package member, an electrolytic solution contained in the container package member, a cathode having a cathode catalyst that is in contact with the electrolytic solution, and an anode that is in contact with the electrolytic solution; a tank storing the electrolytic solution; a pump circulating the electrolytic solution between the main body and the tank; an oxygen intake incorporating oxygen into the electrolytic solution in the way of circulation of the electrolytic solution; and a pipe arrangement connecting the tank, the pump, the oxygen intake and the main body so that the electrolytic solution circulates in the order thus named, wherein the oxygen intake has an oxygen selective permeable membrane.

    摘要翻译： 一种空气电池，其具有包括容器封装构件的主体，容纳在容器封装构件中的电解液，具有与电解液接触的阴极催化剂的阴极和与电解液接触的阳极; 储存电解液的罐; 使电解液在主体和容器之间循环的泵; 以电解液循环的方式将氧气引入电解液中; 以及连接罐，泵，氧气进口和主体的管道装置，使得电解溶液按照这样命名的顺序循环，其中氧气进入具有氧选择性渗透膜。

    Process for producing propylene resin composition
    10.
    发明授权
    Process for producing propylene resin composition 有权
    制备丙烯树脂组合物的方法

    公开(公告)号：US08293843B2

    公开(公告)日：2012-10-23

    申请号：US11100629

    申请日：2005-04-07

    申请人： Satoru Moritomi ,  Takashi Sanada ,  Mitsuyoshi Shimano

    发明人： Satoru Moritomi ,  Takashi Sanada ,  Mitsuyoshi Shimano

    IPC分类号： C08L23/10 ,  C08F297/08

    CPC分类号： C08F297/083 ,  C08F297/08 ,  C08L23/10 ,  C08L23/14 ,  C08L23/16 ,  C08L53/00 ,  C08L2205/02 ,  C08L2205/03 ,  C08L2205/035 ,  C08L2666/02 ,  C08L2666/24

    摘要： Disclosed are processes for producing polypropylene resin compositions including two or three sorts of propylene-based polymeric materials, the processes including a first step of melt-kneading at least a propylene-α-olefin block copolymer containing a polymer portion composed mainly of propylene and a propylene-α-olefin copolymer portion having a relatively high intrinsic viscosity and a second step of melt-kneading the product of the first step with a propylene-ethylene block copolymer containing a polymer portion composed mainly of propylene and a propylene-ethylene copolymer portion having a relatively low intrinsic viscosity or a polymer portion composed mainly of propylene having a relatively low intrinsic viscosity. In the composition produced by these processes, no or substantially no fish eyes develop.

    摘要翻译： 公开了制备包含两种或三种丙烯类聚合物材料的聚丙烯树脂组合物的方法，该方法包括将至少含有主要由丙烯组成的聚合物部分的丙烯-α-烯烃嵌段共聚物熔融捏合的第一步骤和 具有相对高的特性粘度的丙烯-α-烯烃共聚物部分和将第一步骤的产物与含有主要由丙烯组成的聚合物部分的丙烯 - 乙烯嵌段共聚物和具有丙烯 - 乙烯共聚物部分的丙烯 - 乙烯共聚物部分进行熔融捏合的第二步骤， 相对低的特性粘度或主要由具有相对低的特性粘度的丙烯组成的聚合物部分。 在通过这些方法制备的组合物中，没有或基本上没有鱼眼发育。