Electrolyte and electrochemical device

    公开(公告)号:US11621437B2

    公开(公告)日:2023-04-04

    申请号:US16962422

    申请日:2020-02-14

    Abstract: An electrolyte, including a fluorine-containing phosphate ester and a carboxylate ester, wherein the fluorine-containing phosphate ester is represented by Formula 1: R1, R2 and R3 are each independently selected from hydrogen, a C1-C10 alkyl group, C1-C10 alkoxy group, C1-C10 haloalkyl group, C1-C10 haloalkoxy group, C1-C10 phosphate ester group, or C1-C10 mono- or multiple-carbonate ester group, wherein at least one of R1, R2 and R3 comprises a fluorine atom. The weight ratio of the fluorine-containing phosphate ester to the carboxylate ester is 0.001-0.5.

    Electrolyte and electrochemical device

    公开(公告)号:US12119446B2

    公开(公告)日:2024-10-15

    申请号:US17054053

    申请日:2020-03-31

    CPC classification number: H01M10/0567 H01M10/0525 H01M10/0569 H01M2300/0025

    Abstract: An electrolyte, comprising a compound of Formula I and an additive A,




    R1, R2, R3, R4, R5, R6, R7 and R8 are each independently selected from: hydrogen, halo, —COOX, substituted or unsubstituted C1-8alkyl, substituted or unsubstituted C2-10alkenyl, substituted or unsubstituted C2-10alkynyl, substituted or unsubstituted C1-8alkoxy, or —Ra—S(═O)2—Rb, wherein Ra is selected from substituted or unsubstituted C1-8alkylene, Rb is selected from halo or substituted or unsubstituted C1-8alkyl, and at least one of R1, R2, R3, R4, R5, R6, R7 and R8 is —COOX. When substituted, the substituent is selected from cyano or halo; and



    X is selected from Li+, Na+, K+ or Rb+. The additive A is at least one selected from fluoroethylene carbonate, LiPO2F2, or vinylene carbonate.

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