公开(公告)号：US06300450B1

公开(公告)日：2001-10-09

申请号：US09197085

申请日：1998-11-19

申请人： Nobuhiro Tsujimoto ,  Koji Maeda ,  Masato Murakami ,  Michinori Suzuki ,  Yasumasa Iwamoto ,  Sakae Yuasa ,  Satoshi Bandai ,  Yoshihira Hosoyama ,  Nobuharu Hisano

发明人： Nobuhiro Tsujimoto ,  Koji Maeda ,  Masato Murakami ,  Michinori Suzuki ,  Yasumasa Iwamoto ,  Sakae Yuasa ,  Satoshi Bandai ,  Yoshihira Hosoyama ,  Nobuharu Hisano

IPC分类号： C08F3600

CPC分类号： C08F10/00 ,  C08F4/63908 ,  C08F36/04 ,  Y10S526/943 ,  C08F4/6392 ,  C08F4/63912 ,  C08F4/68

摘要： The present invention provides a process for the production of a conjugated diene polymer having a controlled microstructure at a high polymerization activity in the presence of a metallocene type complex of compound of transition metal of the group V of the Periodic Table. A novel catalyst is provided comprising (A) a metallocene type complex of a transition metal of the group V of the Periodic Table, (B) an ionic compound of a non-coordinating anion and a cation, (C) an organic metal compound of the groups I to III and (D) water, wherein the molar ratio of (C)/(D) is from 0.66 to 5. A novel process for the production of a conjugated diene polymer is also provided, which comprises the polymerization of a conjugated diene compound in the presence of a catalyst comprising (A) a metallocene type complex of a transition metal of the group V of the Periodic Table, (B) an ionic compound of a non-coordinating anion and a cation, (C) an organic metal compound of the groups I to III and (D) water, wherein the molar ratio of (C)/(D) is from 0.66 to 5.

摘要翻译： 本发明提供了在元素周期表第V族过渡金属化合物的金属茂型络合物存在下，制备具有高聚合活性的受控微结构的共轭二烯聚合物的方法。 提供一种新型催化剂，其包含（A）周期表第V族过渡金属的金属茂型配合物，（B）非配位阴离子的离子化合物和阳离子，（C）有机金属化合物 组分I至III和（D）水，其中（C）/（D）的摩尔比为0.66至5.还提供了一种制备共轭二烯聚合物的新方法，其包括 （A）元素周期表第V族过渡金属的金属茂型络合物，（B）非配位阴离子的离子化合物和阳离子的催化剂存在下，（C）共轭二烯化合物 I〜III族的有机金属化合物和（D）水，其中（C）/（D）的摩尔比为0.66〜5。

公开(公告)号：US4420594A

公开(公告)日：1983-12-13

申请号：US349872

申请日：1982-02-18

申请人： Haruo Ueno ,  Takefumi Yano ,  Michimasa Shimizu ,  Masanori Tamura ,  Sakae Yuasa

发明人： Haruo Ueno ,  Takefumi Yano ,  Michimasa Shimizu ,  Masanori Tamura ,  Sakae Yuasa

IPC分类号： C08F4/00 ,  C08F4/02 ,  C08F4/60 ,  C08F4/64 ,  C08F10/00 ,  C08F10/02

CPC分类号： C08F10/00

摘要： An ethylene polymer is produced with an excellent yield by bringing a feed containing ethylene into contact with a catalyst which comprises (A) a solid catalytic ingredient prepared (a) by reacting a Grignard compound with a reaction product of an aluminum halide with an organic silicon compound of the formula, R.sup.1.sub.n Si(OR.sup.2).sub.4-n, wherein R.sup.1 =C.sub.1-8 alkyl or phenyl, R.sup.2 =C.sub.1-8 alkyl and n=1, 2 or 3 and (b) by bringing the resultant solid reaction product into contact with titanium tetrahalide and (B) another catalytic ingredient consisting of at least one trialkyl aluminum.

摘要翻译： 通过使含有乙烯的进料与催化剂接触来生产乙烯聚合物，该催化剂包括（A）通过使格氏化合物与卤化铝与有机硅的反应产物反应制备的（a）固体催化成分 化学式为R 1 n Si（OR 2）4-n，其中R 1 = C 1-8烷基或苯基，R 2 = C 1-8烷基和n = 1,2或3，和（b）通过使得到的固体反应产物接触 与四卤化钛和（B）由至少一种三烷基铝组成的另一种催化成分。

公开(公告)号：US4324877A

公开(公告)日：1982-04-13

申请号：US208302

申请日：1980-11-19

申请人： Haruo Ueno ,  Takefumi Yano ,  Tokuji Inoue ,  Shigeru Ikai ,  Masanori Tamura ,  Sakae Yuasa

发明人： Haruo Ueno ,  Takefumi Yano ,  Tokuji Inoue ,  Shigeru Ikai ,  Masanori Tamura ,  Sakae Yuasa

IPC分类号： C08F4/00 ,  C08F4/60 ,  C08F4/64 ,  C08F10/00 ,  C08F4/02 ,  C08F10/06

CPC分类号： C08F10/00

摘要： An .alpha.-olefin polymer having an excellent H.I. is produced with a high yield by bringing, in the presence of an organic acid ester, a feed containing at least one .alpha.-olefin, having 3 or more carbon atoms, into contact with a catalyst composed of:a solid catalytic ingredient which has been prepared in such a manner that an aluminosiloxy compound of the formula, ##STR1## wherein X.sup.1 represents a chlorine atom, a bromine atom or an iodine atom, is reacted with a Grignard compound of the formula R.sup.1 MgX.sup.2 [II] wherein R.sup.1 represents an alkyl radical having 1 to 8 carbon atoms and X.sup.2 represents a halogen atom, the resultant solid reaction product is brought into contact with a titanium tetrahalide, the resultant titanium-containing solid product is treated with an organic acid ester, and the treated solid product is brought into contact with a titanium tetrahalide; anda trialkyl aluminum.

摘要翻译： 具有优异的H.I.的α-烯烃聚合物。 通过在有机酸酯的存在下，将含有至少一种具有3个或更多个碳原子的α-烯烃的进料与由以下物质组成的催化剂接触来制备：高固含量的固体催化成分 以如下方式制备：其中X1表示氯原子，溴原子或碘原子的下式的铝硅氧烷化合物，其中X1表示氯原子，溴原子或碘原子，与式R1MgX2 [II]的格利雅化合物反应，其中R1表示 具有1至8个碳原子的烷基，X 2表示卤素原子，使所得固体反应产物与四卤化钛接触，所得含钛固体产物用有机酸酯处理，并将处理过的固体产物 与四卤化钛接触; 和三烷基铝。

公开(公告)号：US4306046A

公开(公告)日：1981-12-15

申请号：US196095

申请日：1980-10-10

申请人： Haruo Ueno ,  Takefumi Yano ,  Michimasa Shimizu ,  Masanori Tamura ,  Sakae Yuasa

发明人： Haruo Ueno ,  Takefumi Yano ,  Michimasa Shimizu ,  Masanori Tamura ,  Sakae Yuasa

IPC分类号： C08F4/00 ,  C08F4/60 ,  C08F10/02 ,  C08F4/02

CPC分类号： C08F10/02

摘要： An ethylene polymer is produced with an excellent yield by bringing a feed containing ethylene into contact with a catalyst which comprises (A) a solid catalytic ingredient prepared (a) by reacting a Grignard compound with an aluminium halide-tetraalkoxysilane reaction product and (b) bringing the resultant reaction product into contact with titanium tetrahalide and; (B) another catalytic ingredient consisting of a trialkyl aluminium.

摘要翻译： 通过使含有乙烯的进料与催化剂接触来制备乙烯聚合物，该催化剂包含（A）通过使格利雅化合物与卤化铝 - 四烷氧基硅烷反应产物反应制备的（a）固体催化剂成分和（b） 使所得反应产物与四卤化钛接触; （B）由三烷基铝组成的另一催化成分。