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    Silver halide color photographic materials
    4.
    发明授权
    Silver halide color photographic materials 失效
    卤化银彩色照相材料

    公开(公告)号：US4774172A

    公开(公告)日：1988-09-27

    申请号：US935987

    申请日：1986-11-28

    申请人： Toshio Kawagishi ,  Takayoshi Kamio ,  Keizo Kimura ,  Tadahisa Sato ,  Nobuo Furutachi

    发明人： Toshio Kawagishi ,  Takayoshi Kamio ,  Keizo Kimura ,  Tadahisa Sato ,  Nobuo Furutachi

    IPC分类号： C07D487/04 ,  G03C7/38

    CPC分类号： C07D487/04 ,  G03C7/3825

    摘要： Silver halide color photographic materials are described, which comprise at least one silver halide emulsion layer coated on a support and which are characterized by the incorporation of a pyrazoloazole type coupler of the following general formula (I) into the silver halide emulsion layer(s) or the adjacent layer(s) thereto: ##STR1## wherein Za and Zb each may represent ##STR2## R.sup.1 and R.sup.2 each may represent a hydrogen atom or a substituent; X represents a hydrogen atom or a group capable of being removed upon a coupling reaction with an oxidized form of an aromatic primary amine type developing agent; when Za.dbd.Zb is a carbon-carbon double bond, this may be a part of the aromatic ring in the formula: with the proviso that at least one of R.sup.1 and R.sup.2 is a group represented by general formulae (II) or (III): ##STR3## wherein R.sup.3 represents a hydrogen atom or a substituted or unsubstituted alkyl group; R.sup.4 represents a hydrogen atom or a substituent; R.sup.5 represents a halogen atom, a substituted or unsubstituted alkoxy, aryloxy, amino, alkylthio or arylthio group; Ar represents an aryl group; Y represents an alkylene group or an arylene group; l' is an integer of 0 or 1; n is an integer of 0 or 1; and m is an integer of 1 to 3; and that when R.sup.1 represents an alkyl group or Y represents an alkylene group, the alkyl or alkylene group is a group of which the carbon atom directly bonded to the pyrazoloazole nucleus is a primary carbon.The pyrazoloazole type magenta couplers of general formula (I) may form azomethine dyes with improved color reproducibility and high light fastness. The present silver halide color photographic materials containing the coupler of general formula (I) have excellent colorability and excellent light fastness.

    摘要翻译： 描述了卤化银彩色照相材料，其包含涂覆在载体上的至少一种卤化银乳剂层，其特征在于将以下通式（I）的吡唑并唑型成色剂加入到卤化银乳剂层中， 或其相邻的层：其中Za和Zb各自可以表示R 1和R 2各自可以表示氢原子或取代基; X表示氢原子或能够与氧化形式的芳族伯胺型显影剂偶联反应时除去的基团; 当Za = Zb是碳 - 碳双键时，其可以是下式中的芳环的一部分：条件是R 1和R 2中的至少一个是由通式（II）或（III）表示的基团， （III）其中R3表示氢原子或取代或未取代的烷基; R4代表氢原子或取代基; R5表示卤素原子，取代或未取代的烷氧基，芳氧基，氨基，烷硫基或芳硫基; Ar表示芳基; Y表示亚烷基或亚芳基; l'是0或1的整数; n为0或1的整数; m为1〜3的整数。 当R 1表示烷基或Y表示亚烷基时，烷基或亚烷基是与吡唑并唑核直接键合的碳原子为伯碳的基团。 通式（I）的吡唑并噻唑型品红色成色剂可以形成具有改善的颜色再现性和高耐光性的偶氮甲碱染料。 含有通式（I）的成色剂的本发明的卤化银彩色照相材料具有优异的着色性和优异的耐光性。

    Method of forming color image comprising heterocyclic magenta dye-forming coupler
    5.
    发明授权
    Method of forming color image comprising heterocyclic magenta dye-forming coupler 失效
    形成包含杂环品红色染料成色剂的彩色图像的方法

    公开(公告)号：US4540654A

    公开(公告)日：1985-09-10

    申请号：US590818

    申请日：1984-03-19

    申请人： Tadahisa Sato ,  Toshio Kawagishi ,  Nobuo Furutachi

    发明人： Tadahisa Sato ,  Toshio Kawagishi ,  Nobuo Furutachi

    IPC分类号： C03C25/10 ,  B05D1/36 ,  C07D231/38 ,  C07D487/04 ,  C07D519/00 ,  C09B55/00 ,  G02B6/44 ,  G03C7/305 ,  G03C7/38 ,  G03C7/00 ,  G03C1/40 ,  G03C7/40

    CPC分类号： C07D231/38 ,  C07D487/04 ,  C09B55/00 ,  G03C7/30529 ,  G03C7/3835

    摘要： A method of forming a color image comprising developing a silver halide photographic light-sensitive material with a developing solution containing an aromatic primary amine is disclosed. The developing is carried out in the presence of a coupler represented by the general formula (I) described below and/or a polymer coupler which is a polymer or copolymer having a repeating unit derived from a vinyl monomer containing a part represented by the general formula (I) described below in its molecule: ##STR1## wherein R.sub.1 and R.sub.2, which may be the same or different, each represents a hydrogen atom or a substituent; and X represents a hydrogen atom or a group capable of being released upon coupling.The magenta color forming coupler represented by the general formula (I) or the polymer coupler containing the part represented by the general formula (I) has a good color forming property and provides a magenta color image having an excellent spectral absorption property free from subsidiary absorptions in the region around 430 nm and good fastness. A silver halide photographic light-sensitive material containing the magenta coupler is also disclosed.

    摘要翻译： 公开了一种形成彩色图像的方法，其包括用含有芳族伯胺的显影液显影卤化银照相感光材料。 在由下述通式（I）表示的成色剂和/或聚合物成色剂的存在下进行显影，所述聚合物成色剂是具有源自乙烯基单体的聚合物或共聚物，该乙烯基单体含有由通式 （I）：其中R 1和R 2可以相同或不同，各自表示氢原子或取代基; 并且X表示氢原子或在偶联时能够释放的基团。 由通式（I）表示的品红色成色剂或含有由通式（I）表示的部分的聚合物成色剂具有良好的成色性质，并提供具有优异的无辅助吸收光谱吸收特性的品红色图像 在430nm左右的区域和良好的牢度。 还公开了含有品红色成色剂的卤化银照相感光材料。

    Process for producing pyrazolo[1,5-b][1,2,4]triazole derivatives
    6.
    发明授权
    Process for producing pyrazolo[1,5-b][1,2,4]triazole derivatives 失效
    吡唑并[1,5-b] [1,2,4]三唑衍生物的制备方法

    公开(公告)号：US4705863A

    公开(公告)日：1987-11-10

    申请号：US713989

    申请日：1985-03-20

    申请人： Tadahisa Sato ,  Toshio Kawagishi ,  Nobuo Furutachi

    发明人： Tadahisa Sato ,  Toshio Kawagishi ,  Nobuo Furutachi

    IPC分类号： G03C7/38 ,  C07D487/04 ,  G03C7/333

    CPC分类号： C07D487/04

    摘要： Pyrazolo[1,5-b][1,2,4]triazole derivatives are produced by ring closure of an amidoxime compound having a pyrazolyl group. The product can be used as a photographic magenta coupler as such. It is also useful as an intermediate for the magenta coupler, as a dye developer for diffusion transfer process, as an intermediate for the dye releasing agent, and as an intermediate for the photographic sensitizing dye.

    摘要翻译： 吡唑并[1,5-b] [1,2,4]三唑衍生物是通过具有吡唑基的偕胺肟化合物的闭环制备的。 该产品可以用作摄影品红色耦合器。 作为品红色成色剂的中间体，作为扩散转印法的染料显影剂，作为染料脱模剂的中间体，以及作为感光增感染料的中间体也是有用的。

    Pyrazoloazoleazomethine dyes
    8.
    发明授权
    Pyrazoloazoleazomethine dyes 失效
    吡唑并唑吲嗪染料

    公开(公告)号：US5182339A

    公开(公告)日：1993-01-26

    申请号：US622466

    申请日：1990-12-05

    申请人： Shigeki Yokoyama ,  Tadahisa Sato ,  Keizo Kimura ,  Nobuo Furutachi ,  Osamu Takahashi

    发明人： Shigeki Yokoyama ,  Tadahisa Sato ,  Keizo Kimura ,  Nobuo Furutachi ,  Osamu Takahashi

    IPC分类号： C07D487/04 ,  C09B55/00 ,  G03C1/83 ,  G03C7/305

    CPC分类号： C07D487/04 ,  C09B55/009 ,  G03C1/83 ,  G03C7/30529

    摘要： A pyrazoloazoleazomethine dye represented by formula (I) ##STR1## wherein, R.sub.1 represents a substituent having a Hammett's substituent constant value of at least 0.6; Za, Zb, and Zc each represents ##STR2## (wherein R.sub.2 represents a hydrogen atom or a substituent), or .dbd.N--; when Zc=Zb is a carbon-carbon double bond, it may form a part of an aromatic ring; R.sub.3, R.sub.4, and R.sub.5 each represents a hydrogen atom or a substituent; and n represents 1 or 2; said dye may form a dimer or higher polymer by combining with each other or to a polymer through a divalent or higher valent group at R.sub.1, Za, Zb, or Zc.

    摘要翻译： 由式（I）表示的吡唑并唑甲酰胺染料其中，R1表示哈米特取代基常数值至少为0.6的取代基; Za，Zb和Zc各自表示（其中R2表示氢原子或取代基）或= N-; 当Zc = Zb是碳 - 碳双键时，它可以形成芳环的一部分; R3，R4和R5各自表示氢原子或取代基; n表示1或2; 所述染料可以通过在R1，Za，Zb或Zc处通过二价或更高价基团彼此结合或与聚合物形成二聚体或更高级聚合物。

    Process for forming color image
    9.
    发明授权
    Process for forming color image 失效
    形成彩色图像的过程

    公开(公告)号：US5242789A

    公开(公告)日：1993-09-07

    申请号：US542480

    申请日：1990-06-22

    申请人： Tadahisa Sato ,  Nobuo Furutachi

    发明人： Tadahisa Sato ,  Nobuo Furutachi

    IPC分类号： G03C7/305 ,  G03C7/38

    CPC分类号： G03C7/30529 ,  G03C7/3835

    摘要： A silver halide photographic material comprising a support having thereon a silver halide emulsion layer containing at least one coupler represented by the following formulae (I) and (II): ##STR1## wherein R.sub.1 represents an alkyl group, an aryl group or a heterocyclic group; R.sub.2 or R'.sub.2 represents an alkyl group, an aryl group; and X represents a coupling split-off group liked through a nitrogen or a sulfur atom.

    摘要翻译： 一种卤化银照相材料，其包含其上具有卤化银乳剂层的载体，所述卤化银乳剂层含有至少一种由下式（I）和（II）表示的偶联剂：其中R 1表示烷基 基，芳基或杂环基; R2或R'2表示烷基，芳基; X表示通过氮或硫原子获得的偶联分离基团。

    Pyrazoloazoleazomethine dyes
    10.
    发明授权
    Pyrazoloazoleazomethine dyes 失效
    吡唑并唑吲嗪染料

    公开(公告)号：US4921968A

    公开(公告)日：1990-05-01

    申请号：US130489

    申请日：1987-12-09

    申请人： Shigeki Yokoyama ,  Tadahisa Sato ,  Keizo Kimura ,  Nobuo Furutachi ,  Osamu Takahashi

    发明人： Shigeki Yokoyama ,  Tadahisa Sato ,  Keizo Kimura ,  Nobuo Furutachi ,  Osamu Takahashi

    IPC分类号： G03C7/38 ,  C07D487/04 ,  C09B55/00 ,  C09B57/00 ,  G03C1/83 ,  G03C7/305

    CPC分类号： C07D487/04 ,  C09B55/009 ,  G03C1/83 ,  G03C7/30529

    摘要： A pyrazoloazoleazomethine dye represented by formula (I) ##STR1## wherein, R.sub.1 represents a substituent having a Hammett's substituent constant value of at least 0.6; Za, Zb, and Zc each represents .dbd.CH--, ##STR2## (wherein R.sub.2 represents a hydrogen atom or a substituent), or .dbd.N--; when Zc=Zb is a carbon-carbon double bond, it may form a part of an aromatic ring; R.sub.3, R.sub.4, and R.sub.5 each represents a hydrogen atom or a substituent; and n represents 1 or 2; said dye may form a dimer or higher polymer by combining with each other or to a polymer through a divalent or higher valent group at R.sub.1, Za, Zb, or Zc.

    摘要翻译： 由式（I）表示的吡唑并唑甲酰胺染料其中，R1表示哈米特取代基常数值至少为0.6的取代基; Za，Zb和Zc各自表示= CH-，（其中R2表示氢原子或取代基）或= N-; 当Zc = Zb是碳 - 碳双键时，它可以形成芳环的一部分; R3，R4和R5各自表示氢原子或取代基; n表示1或2; 所述染料可以通过在R1，Za，Zb或Zc处通过二价或更高价基团彼此结合或与聚合物形成二聚体或更高级聚合物。