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    Removal of carbon dioxide from flue gases
    1.
    发明授权
    Removal of carbon dioxide from flue gases 有权
    从烟道气中去除二氧化碳

    公开(公告)号：US07887620B2

    公开(公告)日：2011-02-15

    申请号：US12304312

    申请日：2007-06-13

    申请人： Norbert Asprion ,  Iven Clausen ,  Ute Lichtfers

    发明人： Norbert Asprion ,  Iven Clausen ,  Ute Lichtfers

    IPC分类号： B01D53/14

    CPC分类号： B01D53/1493 ,  B01D53/1475 ,  Y02A50/2342 ,  Y02C10/06

    摘要： A description is given of a process for removing carbon dioxide from gas streams in which the partial pressure of the carbon dioxide is less than 200 mbar, in particular flue gases, the gas stream being contacted with a liquid absorption medium which comprises an aqueous solution (A) of a tertiary aliphatic alkanolamine and (B) an activator of the formula R1—NH—R2—NH2, where R1 is C1-C6-alkyl and R2 is C2-C6-alkylene, the sum of the concentrations of A and B being 2.5 to 7 mol/l, and the molar ratio of B to A being in the range of 1:3 to 1.5:1. The activator is, for example, 3-methylaminopropylamine, the tertiary aliphatic amine methyldiethanolamine, methyldiisopropanolamine or n-butyldiethanolamine. The process permits substantial removal of carbon dioxide and the regeneration of the absorption medium is possible with relatively low energy consumption.

    摘要翻译： 给出了从气流中除去二氧化碳的过程的描述，其中二氧化碳的分压小于200毫巴，特别是烟道气，气流与包含水溶液的液体吸收介质接触（ A）的叔脂肪族链烷醇胺和（B）式R1-NH-R2-NH2的活化剂，其中R1是C1-C6-烷基，R2是C2-C6-亚烷基，A和B的浓度之和 为2.5〜7mol / l，B与A的摩尔比为1：3〜1.5：1。 活化剂是例如3-甲基氨基丙胺，叔脂族胺甲基二乙醇胺，甲基二异丙醇胺或正丁基二乙醇胺。 该方法允许基本上去除二氧化碳，并且以相对低的能量消耗可以进行吸收介质的再生。

    Method for the Removal of Carbon Dioxide From Flue Gases
    2.
    发明申请
    Method for the Removal of Carbon Dioxide From Flue Gases 审中-公开
    从烟气中去除二氧化碳的方法

    公开(公告)号：US20080098892A1

    公开(公告)日：2008-05-01

    申请号：US10592419

    申请日：2005-03-09

    申请人： Norbert Asprion ,  Iven Clausen ,  Ute Lichtfers

    发明人： Norbert Asprion ,  Iven Clausen ,  Ute Lichtfers

    IPC分类号： B01D53/14

    CPC分类号： B01D53/1493 ,  B01D53/1475 ,  Y02A50/2342 ,  Y02C10/06

    摘要： The invention relates to a method for the removal of carbon dioxide from a gas flow, in which the partial pressure of the carbon dioxide in the gas flow is less than 200 mbar, whereby the gas flow is brought into contact with a liquid absorption agent, comprising an aqueous solution (A) of a tertiary aliphatic amine and (B) an activator of general formula R1-NH-R2-NH2, where R1=C1-C6 alkyl and R2=C2-C6 alkylene. The method is particularly suitable for treatment of flue gases and also relates to an absorption agent.

    摘要翻译： 本发明涉及一种从气流中除去二氧化碳的方法，其中气流中二氧化碳的分压小于200毫巴，由此使气流与液体吸收剂接触， 包括叔脂族胺的水溶液（A）和（B）通式为R 1，-NH-R 2，-NH 2的活化剂， 其中R 1是C 1 -C 6烷基，R 2是C 2 C 6 -C 6亚烷基。 该方法特别适用于烟道气的处理，也涉及吸收剂。

    Method For The Removal Of Carbon Dioxide From Gas Flows With Low Carbon Dioxide Partial Pressures
    6.
    发明申请
    Method For The Removal Of Carbon Dioxide From Gas Flows With Low Carbon Dioxide Partial Pressures 审中-公开
    采用低二氧化碳部分压力从气流中去除二氧化碳的方法

    公开(公告)号：US20080025893A1

    公开(公告)日：2008-01-31

    申请号：US10592420

    申请日：2005-03-09

    申请人： Norbert Asprion ,  Iven Clausen ,  Ute Lichtfers

    发明人： Norbert Asprion ,  Iven Clausen ,  Ute Lichtfers

    IPC分类号： B01D53/14

    CPC分类号： B01D53/1493 ,  Y02C10/06

    摘要： The invention relates to a method for the removal of carbon dioxide from a gas flow with a carbon dioxide partial pressure in the gas flow of less than 200 mbar, whereby the gas flow is brought into contact with a liquid absorption agent, selected from an aqueous solution (A) of an amino compound with at least two tertiary amino groups in the molecule and (B) an activator, selected from the primary and secondary amines, or (A) a tertiary aliphatic amine, the reaction enthalpy ΔRH for the protonation of which is greater than that for methyldiethanolamine and (B) an activator, selected from 3-methylaminopropylamine, piperazine, 2-methylpiperazine, N-methylpiperazine, homopiperazine, piperidine and morpholine. The method is particularly suitable for the treatment of flue gases and also relates to an absorption agent.

    摘要翻译： 本发明涉及一种从气流中二氧化碳分压小于200毫巴的气流中除去二氧化碳的方法，由此使气流与液体吸收剂接触，液体吸收剂选自水溶液 在分子中具有至少两个叔氨基的氨基化合物的溶液（A）和（B）选自伯胺和仲胺的活化剂，或（A）叔脂族胺，反应焓ΔR 其质子化度大于甲基二乙醇胺和（B）选自3-甲基氨基丙胺，哌嗪，2-甲基哌嗪，N-甲基哌嗪，高哌嗪，哌啶和吗啉的活化剂。 该方法特别适用于烟道气的处理，也涉及一种吸收剂。

    REMOVAL OF CARBON DIOXIDE FROM FLUE GASES
    8.
    发明申请
    REMOVAL OF CARBON DIOXIDE FROM FLUE GASES 有权
    从燃气中去除二氧化碳

    公开(公告)号：US20090199711A1

    公开(公告)日：2009-08-13

    申请号：US12304312

    申请日：2007-06-13

    申请人： Norbert Asprion ,  Iven Clausen ,  Ute Lichtfers

    发明人： Norbert Asprion ,  Iven Clausen ,  Ute Lichtfers

    IPC分类号： B01D53/14 ,  B01D19/00

    CPC分类号： B01D53/1493 ,  B01D53/1475 ,  Y02A50/2342 ,  Y02C10/06

    摘要： A description is given of a process for removing carbon dioxide from gas streams in which the partial pressure of the carbon dioxide is less than 200 mbar, in particular flue gases, the gas stream being contacted with a liquid absorption medium which comprises an aqueous solution (A) of a tertiary aliphatic alkanolamine and (B) an activator of the formula R1—NH—R2—NH2, where R1 is C1-C6-alkyl and R2 is C2-C6-alkylene, the sum of the concentrations of A and B being 2.5 to 7 mol/l, and the molar ratio of B to A being in the range of 1:3 to 1.5:1. The activator is, for example, 3-methylaminopropylamine, the tertiary aliphatic amine methyldiethanolamine, methyidiisopropanolamine or n-butyldiethanolamine. The process permits substantial removal of carbon dioxide and the regeneration of the absorption medium is possible with relatively low energy consumption.

    摘要翻译： 给出了从气流中除去二氧化碳的过程的描述，其中二氧化碳的分压小于200毫巴，特别是烟道气，气流与包含水溶液的液体吸收介质接触（ A）的叔脂肪族链烷醇胺和（B）下式的活化剂：式中：α-in-line-formula description =“In-line Formulas”end =“lead”→R1-NH-R2-NH2， line-formula description =“In-line Formulas”end =“tail”？>其中R1是C1-C6-烷基，R2是C2-C6-亚烷基，A和B的浓度之和为2.5〜7mol / 1，B与A的摩尔比在1：3至1.5：1的范围内。 活化剂是例如3-甲基氨基丙胺，叔脂族胺甲基二乙醇胺，甲基二异丙醇胺或正丁基二乙醇胺。 该方法允许基本上去除二氧化碳，并且以相对低的能量消耗可以进行吸收介质的再生。

    Process for the recovery of carbon dioxide
    9.
    发明授权
    Process for the recovery of carbon dioxide 有权
    回收二氧化碳的方法

    公开(公告)号：US08398749B2

    公开(公告)日：2013-03-19

    申请号：US12096917

    申请日：2006-12-12

    申请人： Ute Lichtfers ,  Norbert Asprion ,  Mark Claessen ,  Hiroshi Umino ,  Koji Tanaka

    发明人： Ute Lichtfers ,  Norbert Asprion ,  Mark Claessen ,  Hiroshi Umino ,  Koji Tanaka

    IPC分类号： B01D53/14

    CPC分类号： B01D53/1425 ,  B01D53/1475 ,  B01D53/1493 ,  B01D2257/504 ,  Y02A50/2342 ,  Y02C10/06

    摘要： A process for the recovery of carbon dioxide, which includes: (a) an absorption step of bringing a carbon dioxide-containing gaseous feed stream into gas-liquid contact with an absorbing fluid, whereby at least a portion of the carbon dioxide present in the gaseous stream is absorbed into the absorbing fluid to produce (i) a refined gaseous stream having a reduced carbon dioxide content and (ii) an carbon dioxide-rich absorbing fluid; and (b) a regeneration step of treating the carbon dioxide-rich absorbing fluid at a pressure of greater than 3 bar (absolute pressure) so as to liberate carbon dioxide and regenerate a carbon dioxide-lean absorbing fluid which is recycled for use in the absorption step, in which the absorbing fluid is an aqueous amine solution containing a tertiary aliphatic alkanol amine and an effective amount of a carbon dioxide absorption promoter, the tertiary aliphatic alkanol amine showing little decomposition under specified conditions of temperature and pressure under co-existence with carbon dioxide.

    摘要翻译： 一种回收二氧化碳的方法，其包括：（a）使含二氧化碳的气态进料流与吸收液体气液接触的吸收步骤，由此至少一部分二氧化碳存在于 气流被吸收到吸收流体中以产生（i）具有降低的二氧化碳含量的精炼气流和（ii）富含二氧化碳的吸收流体; 和（b）在大于3巴（绝对压力）的压力下处理富含二氧化碳的吸收液体以便释放二氧化碳并再生贫二氧化碳的吸收流体的再生步骤，其被再循环用于 吸收步骤，其中吸收液是含有叔脂肪烷醇胺和有效量的二氧化碳吸收促进剂的胺水溶液，叔脂肪烷醇胺在特定的温度和压力条件下几分解，与 二氧化碳。