METAL-SUBSTITUTED METAL OXIDE MATERIALS FOR LITHIUM ION BATTERIES

    公开(公告)号:US20200075949A1

    公开(公告)日:2020-03-05

    申请号:US16603982

    申请日:2018-04-13

    摘要: Provided is a Li+ battery comprising an anode comprising an anode active material comprising a plurality of transition metal (TM1)-substituted binary transition metal (TM2) oxide nanocrystals, a cathode in electrical communication with the anode, a separator between the anode and the cathode, and an electrolyte in contact with the anode and the cathode. The anode active material, in a lithiated state, is characterized by a three-dimensional network of the TM1 and nanoparticles of Li2O nanoparticles of the TM2, both types of nanoparticles distributed throughout the network. In a delithiated state, the anode active material is characterized by the network of the TM1 and nanoparticles of an oxide of the TM1 and nanoparticles of an oxide of the TM2, both types of nanoparticles distributed throughout the network. The TM1-substituted binary TM2 oxide may be characterized by a ratio of TM2/TM1 of at least about 5.

    Metal-substituted metal oxide materials for lithium ion batteries

    公开(公告)号:US11367874B2

    公开(公告)日:2022-06-21

    申请号:US16603982

    申请日:2018-04-13

    摘要: Provided is a Li+battery comprising an anode comprising an anode active material comprising a plurality of transition metal (TM1)-substituted binary transition metal (TM2) oxide nanocrystals, a cathode in electrical communication with the anode, a separator between the anode and the cathode, and an electrolyte in contact with the anode and the cathode. The anode active material, in a lithiated state, is characterized by a three-dimensional network of the TM1 and nanoparticles of Li2O and nanoparticles of the TM2, both types of nanoparticles distributed throughout the network. In a delithiated state, the anode active material is characterized by the network of the TM1 and nanoparticles of an oxide of the TM1 and nanoparticles of an oxide of the TM2, both types of nanoparticles distributed throughout the network. The TM1-substituted binary TM2 oxide may be characterized by a ratio of TM2/TM1 of at least about 5.