公开(公告)号：US10759819B2

公开(公告)日：2020-09-01

申请号：US16412768

申请日：2019-05-15

Applicant: PETROCHINA COMPANY LIMITED

Inventor： Jianhui Lou ,  Yongge Wei ,  Bin Ding ,  Jiangwei Zhang ,  Pingmei Wang ,  Jin Zhang ,  Xiangfei Geng ,  Zheyu Wei ,  Baoliang Peng ,  Lipeng He

IPC: C07F11/00

Abstract: The present disclosure provides a single-side modified β-Anderson-type heteropolymolybdate organic derivative having an anionic moiety with a general formula represented by: β-{[RC(CH2O)3]M(OH)3Mo6O18}3−; β represents a non-planar folded structure; R=substituted or unsubstituted phenyl, CnH2nX (n is an integer from 0 to 22; X═H, OH, NH(CH2)3SO3H, NHCH2COOH, NH2, or NO2); M=Cr3+. The single-side modified β-Anderson-type heteropolymolybdate organic derivative can be prepared under hydrothermal conditions.

公开(公告)号：US20190352320A1

公开(公告)日：2019-11-21

申请号：US16412768

申请日：2019-05-15

Applicant: Petrochina Company Limited

Inventor： Jianhui Luo ,  Yongge Wei ,  Bin Ding ,  Jiangwei Zhang ,  Pingmei Wang ,  Jin Zhang ,  Xiangfei Geng ,  Zheyu Wei ,  Baoliang Peng ,  Lipeng He

IPC: C07F11/00

Abstract: The present disclosure provides a single-side modified β-Anderson-type heteropolymolybdate organic derivative having an anionic moiety with a general formula represented by: β-{[RC(CH2O)3]M(OH)3Mo6O18}3−; β represents a non-planar folded structure; R=substituted or unsubstituted phenyl, CnH2nX (n is an integer from 0 to 22; X=H, OH, NH(CH2)3SO3H, NHCH2COOH, NH2, or NO2); M=Cr3+. The single-side modified β-Anderson-type heteropolymolybdate organic derivative can be prepared under hydrothermal conditions.