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公开(公告)号:US12179168B2
公开(公告)日:2024-12-31
申请号:US17361377
申请日:2021-06-29
Inventor: Naoya Sakata , Masashi Morita , Hidekazu Arase , Ryotaro Matsuda , Akihiro Hori
Abstract: A photoresponsive oxygen storage material includes a plurality of unit cells. Each of the plurality of unit cells has a shape of a cube having eight corners and six faces. Each of the plurality of unit cells includes a plurality of zirconium-oxo clusters each located at a corresponding corner of the eight corners, and a plurality of ligands each located on a corresponding face of the six faces and each having a porphyrin skeleton and including greater than or equal to 1 and less than or equal to 4 carboxy groups. A molybdenum ion is located at a center of the porphyrin skeleton, and at least some of the plurality of unit cells are empty.