Glyphosate formulations containing etheramine surfactants
    5.
    再颁专利
    Glyphosate formulations containing etheramine surfactants 有权
    含有醚胺表面活性剂的草甘膦制剂

    公开(公告)号:USRE37866E1

    公开(公告)日:2002-10-01

    申请号:US09569800

    申请日:2000-05-12

    IPC分类号: A01N5702

    摘要: Herbicidal compositions are provided comprising glyphosate or a salt thereof and an etheramine surfactant having the representative chemical structure (a) wherein R1 is a straight or branched chain C6 to about C22 alkyl, aryl or alkylaryl group, m is an average number from 1 to about 10, R2 in each of the m (O—R2) groups is independently C1-C4 alkylene, R3 groups are independently C1-C4 alkylene, and x and y are average numbers such that x+y is in the range from 2 to about 60; or (b) wherein R1 is a straight or branched chain C6 to about C22 alkyl, aryl or alkylaryl group, m is an average number from 1 to about 10, R2 in each of the m (O—R2) groups is independently C1-C4 alkylene, R3 groups are independently C1-C4 alkylene, R4 is C1-C4 alkyl, x and y are average numbers such that x+y is in the range from 0 to about 60, and A− is an agriculturally acceptable anion; or (c) wherein R1 is a straight or branched chain C6 to about C22 alkyl, aryl or alkylaryl group, m is an average number from 1 to about 10, R2 is each of the m (O—R2) groups is independently C1-C4 alkylene, R3 groups are independently C1-C4 alkylene, and x and y are average numbers such that x+y is in the range from 2 to about 60.

    摘要翻译: 提供除草组合物,其包含草甘膦或其盐和具有代表性化学结构(a)的醚胺表面活性剂,其中R 1是直链或支链C 6至C 22烷基,芳基或烷芳基,m是1至约 10,各个m(O-R 2)基团中的R 2独立地为C 1 -C 4亚烷基,R 3基团独立地为C 1 -C 4亚烷基,x和y为平均数,使得x + y在2至约 60; 或(b)其中R1是直链或支链C6至约C22烷基,芳基或烷基芳基,m是1至约10的平均数,m(O-R2)基团中的每个独立地为C1- C4亚烷基,R3基团独立地为C1-C4亚烷基,R4为C1-C4烷基,x和y为x + y为0至约60的平均数,A-为农业上可接受的阴离子; 或(c)其中R 1是直链或支链C 6至C 22烷基,芳基或烷基芳基,m是1至约10的平均数,R 2各自为m(O-R 2)基团, C4亚烷基,R3基团独立地为C1-C4亚烷基,x和y为平均数,使得x + y在2至约60的范围内。

    Glyphosate formulations containing etheramine surfactants
    6.
    发明授权
    Glyphosate formulations containing etheramine surfactants 失效
    含有醚胺表面活性剂的草甘膦制剂

    公开(公告)号:US5750468A

    公开(公告)日:1998-05-12

    申请号:US599363

    申请日:1996-03-15

    IPC分类号: A01N57/20 A01N25/30 A01N57/02

    CPC分类号: A01N57/20

    摘要: Herbicidal compositions are provided comprising glyphosate or a salt thereof and an etheramine surfactant having the representative chemical structure (a) ##STR1## wherein R.sub.1 is a straight or branched chain C.sub.6 to about C.sub.22 alkyl, aryl or alkylaryl group, m is an average number from 1 to about 10, R.sub.2 in each of the m (O--R.sub.2) groups is independently C.sub.1 -C.sub.4 alkylene, R.sub.3 groups are independently C.sub.1 -C.sub.4 alkylene, and x and y are average numbers such that x+y is in the range from 2 to about 60; or (b) ##STR2## wherein R.sub.1 is a straight or branched chain C.sub.6 to about C.sub.22 alkyl, aryl or alkylaryl group, m is an average number from 1 to about 10, R.sub.2 in each of the m (O--R.sub.2) groups is independently C.sub.1 -C.sub.4 alkylene, R.sub.3 groups are independently C.sub.1 -C.sub.4 alkylene, R.sub.4 is C.sub.1 -C.sub.4 alkyl, x and y are average numbers such that x+y is in the range from 0 to about 60, and A.sup.- is an agriculturally acceptable anion; or (c) ##STR3## wherein R.sub.1 is a straight or branched chain C.sub.6 to about C.sub.22 alkyl, aryl or alkylaryl group, m is an average number from 1 to about 10, R.sub.2 in each of the m (O--R.sub.2) groups is independently C.sub.1 -C.sub.4 alkylene, R.sub.3 groups are independently C.sub.1 -C.sub.4 alkylene, and x and y are average numbers such that x+y is in the range from 2 to about 60.

    摘要翻译: 提供了除草组合物,其包含草甘膦或其盐和具有代表性化学结构的(a)的醚胺表面活性剂,其中R 1是直链或支链C 6至C 22烷基,芳基或烷芳基,m是 1至约10个,m(O-R 2)基团中的R 2独立地为C 1 -C 4亚烷基,R 3基团独立地为C 1 -C 4亚烷基,x和y为平均数,使得x + y在 2到约60; 或(b)链C6至约C22烷基,芳基或烷基芳基,m为1至约10的平均数,m(O-R 2)基团中的每个独立地为C 1 -C 4亚烷基,R 3基团独立地为 C1-C4亚烷基,R4是C1-C4烷基,x和y是平均数,使得x + y在0至约60的范围内,A-是农业上可接受的阴离子; 或(c)其中R 1是直链或支链C 6至C 22烷基,芳基或烷基芳基,m是1至约10的平均数,m(O-R 2)基团中的每个为 独立地,C 1 -C 4亚烷基,R 3基团独立地是C 1 -C 4亚烷基,x和y是平均数,使得x + y在2至约60的范围内。

    Enhanced method of killing weeds with glyphosate herbicide
    7.
    发明授权
    Enhanced method of killing weeds with glyphosate herbicide 有权
    用草甘膦除草剂杀死杂草的增强方法

    公开(公告)号:US06908882B1

    公开(公告)日:2005-06-21

    申请号:US09652771

    申请日:2000-08-31

    摘要: A method is provided of enhancing the herbicidal activity of a glyphosate herbicide, comprising adding to the glyphosate herbicide a mixture of a first surfactant and a second surfactant at a weight ratio of total surfactant to glyphosate of about 1:30 to about 2:1, wherein the first surfactant has a chemical structure comprising a cationic or protonatable amino group and a C8-24 linear or branched, saturated or unsaturated hydrocarbyl group, and the second surfactant has the formula R—CO—NR′—(CR′2)n—COOM where R is a C7-23 linear or branched, saturated or unsaturated hydrocarbyl group, n is 1 to 4, M is hydrogen or a cationic counterion, and R′ groups are each independently hydrogen, C1-4 alkyl or a group —(CH2)m—COOM where m is 1 to 4 and M is as defined immediately above, with the proviso that no more than one R′ group is such a group —(CH2)m—COOM; the weight ratio of the first to the second surfactant being about 1:10 to about 10:1. Also provided is a herbicidal composition prepared according to the above method. The first and second surfactants exhibit a synergistic interaction in enhancing herbicidal activity of the glyphosate herbicide.

    摘要翻译: 提供了提高草甘膦除草剂除草活性的方法,其包括以总表面活性剂与草甘膦的重量比为1:30至约2:1,向草甘膦除草剂中加入第一表面活性剂和第二表面活性剂的混合物, 其中所述第一表面活性剂具有包含阳离子或可质子化氨基和C 8-24直链或支链饱和或不饱和烃基的化学结构,并且所述第二表面活性剂具有式 -formulae description =“In-line Formulas”end =“lead”?> R-CO-NR' - (CR'2 n)-COOM < line-formula description =“In-line Formulas”end =“tail”?>其中R是直链或支链饱和或不饱和烃基,n为1至4,M 是氢或阳离子抗衡离子,R'基团各自独立地为氢,C 1-4烷基或基团 - (CH 2 CH 2)m > -COOM,其中m为1至4,M如上所定义 iso,不超过一个R'基团是这样的基团 - (CH 2 CH 2)m -COOM; 第一和第二表面活性剂的重量比为约1:10至约10:1。 还提供了根据上述方法制备的除草组合物。 第一和第二表面活性剂在增强草甘膦除草剂的除草活性方面表现出协同相互作用。