公开(公告)号：US4777266A

公开(公告)日：1988-10-11

申请号：US888909

申请日：1986-07-22

申请人： Pavel Haspra ,  Alex Nicopoulos

发明人： Pavel Haspra ,  Alex Nicopoulos

IPC分类号： C09B5/62 ,  C09B5/24 ,  C07D209/56

CPC分类号： C09B5/2463

摘要： A process for the preparation of dyes of formula (1) as indicated in claim 1 or of mixtures of such dyes is described.The dyes of formula (1) are obtained by reacting 1,4-diaminoanthraquinone-2,3-dicarboximide, or the corresponding monoimino compound, with an amine and in the absence of a solvent. Dye mixtures are prepared by subsequently partially transamidating the resultant product.

摘要翻译： 描述了如权利要求1所述的制备式（1）染料的方法或这些染料的混合物。 式（1）的染料是通过使1,4-二氨基蒽醌-2,3-二甲酰亚胺或相应的单亚胺基化合物与胺和不存在溶剂反应而获得的。 随后将所得产物部分转酰胺化制备染料混合物。

公开(公告)号：US5284939A

公开(公告)日：1994-02-08

申请号：US882981

申请日：1992-05-14

申请人： Alex Nicopoulos ,  Hanspeter Birri ,  Gerhard Hanika

发明人： Alex Nicopoulos ,  Hanspeter Birri ,  Gerhard Hanika

IPC分类号： C09B67/34 ,  C09B69/06 ,  C09B41/00

CPC分类号： C09B69/065 ,  C09B67/0076

摘要： There is described a process for the preparation of highly concentrated aqueous solutions of specific cationic azo dyes. The solutions are prepared by diazotising a diazo component in a solution which contains sulfuric acid, coupling the diazotised component to a coupling component, treating the resultant azo dye with a bicarbonate, and converting the dye bicarbonate with an organic acid into the dye salt of said acid.

摘要翻译： 描述了制备高浓度特定阳离子偶氮染料水溶液的方法。 溶液是通过将重氮组分在包含硫酸的溶液中重氮化，将重氮化的组分偶合到偶联组分上，用碳酸氢盐处理所得的偶氮染料，并将有机酸的染料碳酸氢盐转化成所述的 酸。

公开(公告)号：US4536185A

公开(公告)日：1985-08-20

申请号：US564860

申请日：1983-12-23

申请人： Arnulf R. Lapple ,  Alex Nicopoulos

发明人： Arnulf R. Lapple ,  Alex Nicopoulos

IPC分类号： C09B67/22 ,  C09B67/34 ,  D06P1/41

CPC分类号： C09B67/0076 ,  C09B67/0041 ,  D06P1/41 ,  Y10S534/01 ,  Y10S8/922 ,  Y10S8/924 ,  Y10S8/927

摘要： A novel liquid preparation containing a mixture of dyes according to claim 1, an aliphatic carboxylic acid, and optionally water and organic solvents. This novel preparation is storage-stable and temperature-stable and can be used in particular for dyeing polyacrylonitrile materials in black shades, the dyeings obtained having a neutral shade, negligible change of shade in artificial light and very good fastness to light.

摘要翻译： 根据权利要求1的含有染料混合物的新型液体制剂，脂族羧酸和任选的水和有机溶剂。 该新型制剂具有储存稳定性和温度稳定性，特别可用于以黑色染色的聚丙烯腈材料进行染色，得到的染色具有中性色调，人造光线下的色调变化可忽略不计，光稳定性好。

公开(公告)号：US4018763A

公开(公告)日：1977-04-19

申请号：US567795

申请日：1975-04-14

申请人： Peter Moser ,  Alex Nicopoulos

发明人： Peter Moser ,  Alex Nicopoulos

IPC分类号： C09B19/00 ,  C07D265/12

CPC分类号： C09B19/00

摘要： A process for the preparation of basic oxazine dyes of the formula ##STR1## wherein R represents a low molecular alkoxy or alkyl group which is substituted or unsubstituted, R.sub.1 represents a low molecular alkyl group which is substituted or unsubstituted, R.sub.2 represents a low molecular alkyl group which is substituted or unsubstituted or an aryl radical, and each of R.sub.3 and R.sub.4 independently represents hydrogen or a low molecular alkyl radical which is substituted or unsubstituted, and R.sub.1 may be attached to R.sub.2 and R.sub.3 to R.sub.4 through a heteroatom, and wherein the ring a can carry further non-ionogenic substituents or a fused benzene ring, and X.sup.- represents an anion, which process comprises treating a compound of the formula ##STR2## wherein R.sub.1, R.sub.2 and a have the meanings previously assigned to them, with nitrous acid in a polar, water-miscible solvent and adding to the resultant nitrosation mixture, without isolating the nitroso compound, a diamine of the formula ##STR3## wherein R, R.sub.3 and R.sub.4 have the indicated meanings and each of R.sub.5 and R.sub.6 represents hydrogen or a low molecular alkyl group.

摘要翻译： 制备式（1）的基本恶嗪染料的方法，其中R表示低分子量烷氧基或取代或未取代的烷基，R 1表示取代或未取代的低分子量烷基，R 2表示 取代或未取代的低分子烷基或芳基，R3和R4各自独立地表示氢或被取代或未取代的低分子烷基，R1可以通过杂原子连接到R 2和R 3至R 4上， 并且其中所述环a可以携带另外的非离子型取代基或稠合的苯环，并且X 1代表阴离子，该方法包括处理式（2）的化合物，其中R1，R2和a具有 以前分配给它们的含义，与亚硝酸在极性，水混溶性溶剂中反应，并加入所得的亚硝化混合物中，而不分离出亚硝基化合物，式（3）的二胺其中R ，R3和R4具有指定的含义，R5和R6各自表示氢或低分子量烷基。

公开(公告)号：US5917035A

公开(公告)日：1999-06-29

申请号：US39733

申请日：1998-03-16

申请人： Hanspeter Birri ,  Gerhard Hanika ,  Alex Nicopoulos

发明人： Hanspeter Birri ,  Gerhard Hanika ,  Alex Nicopoulos

IPC分类号： C07D265/38 ,  C09B19/00

CPC分类号： C09B19/00

摘要： The compounds of formula ##STR1## wherein the substituents are as defined in the claims, are suitable for dyeing or printing, inter alia, polyacrylonitrile and acid-modified polyester fibers, and can furthermore be converted by anion exchange into a physical form suitable for liquid formulations.

摘要翻译： 下式的化合物其中取代基如权利要求中所定义，适用于特别是聚丙烯腈和酸改性聚酯纤维的染色或印花，并且还可以通过阴离子交换转化为适合于液体制剂的物理形式。