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1.发明申请公开(公告)号：US20130233766A1
公开(公告)日：2013-09-12
申请号：US13865032
申请日：2013-04-17
申请人： Raheel SHAFI , Julio HASSELMEYER , Abdennour BOURANE , Ibrahim A. ABBA , Abdul Rahman Zafer AKHRAS
发明人： Raheel SHAFI , Julio HASSELMEYER , Abdennour BOURANE , Ibrahim A. ABBA , Abdul Rahman Zafer AKHRAS
IPC分类号： C10G69/06
CPC分类号： C10G69/06 , C10G9/36 , C10G45/00 , C10G2300/201 , C10G2300/308 , C10G2300/4081 , C10G2400/20 , C10G2400/30
摘要： An integrated hydrotreating and steam pyrolysis process for the direct processing of a crude oil is provided to produce olefinic and aromatic petrochemicals. Crude oil and hydrogen are charged to a hydroprocessing zone operating under conditions effective to produce a hydroprocessed effluent reduced having a reduced content of contaminants, an increased paraffinicity, reduced Bureau of Mines Correlation Index, and an increased American Petroleum Institute gravity. Hydroprocessed effluent is thermally cracked in the presence of steam to produce a mixed product stream, which is separated. Hydrogen from the mixed product stream is purified and recycled to the hydroprocessing zone, and olefins and aromatics are recovered from the separated mixed product stream.
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2.发明申请INTEGRATED HYDROTREATING AND STEAM PYROLYSIS PROCESS FOR DIRECT PROCESSING OF A CRUDE OIL 审中-公开用于直接加工原油的综合加氢和蒸汽热解方法公开(公告)号：US20130197285A1
公开(公告)日：2013-08-01
申请号：US13751946
申请日：2013-01-28
申请人： Raheel SHAFI , Julio HASSELMEYER , Abdennour BOURANE , Ibrahim A. ABBA , Abdul Rahman Zafer AKHRAS
发明人： Raheel SHAFI , Julio HASSELMEYER , Abdennour BOURANE , Ibrahim A. ABBA , Abdul Rahman Zafer AKHRAS
IPC分类号： C10G69/06
CPC分类号： C10G69/06 , B01D19/0057 , B01D53/22 , B01D53/526 , B01D2256/16 , B01D2257/7025 , C10G9/16 , C10G45/44 , C10G47/22 , C10G2300/1037 , C10G2300/308 , C10G2300/4075 , C10G2300/42 , C10G2400/20 , C10G2400/30 , Y02C20/20
摘要： An integrated hydrotreating and steam pyrolysis process for the direct processing of a crude oil is provided to produce olefinic and aromatic petrochemicals. Crude oil and hydrogen are charged to a hydroprocessing zone operating under conditions effective to produce a hydroprocessed effluent reduced having a reduced content of contaminants, an increased paraffinicity, reduced Bureau of Mines Correlation Index, and an increased American Petroleum Institute gravity. Hydroprocessed effluent is thermally cracked in the presence of steam to produce a mixed product stream, which is separated. Hydrogen from the mixed product stream is purified and recycled to the hydroprocessing zone, and olefins and aromatics are recovered from the separated mixed product stream.
摘要翻译： 提供了一种用于直接加工原油的综合加氢处理和蒸汽热解方法，用于生产烯烃和芳族石油化学品。 将原油和氢气加入加氢处理区，在有效地产生减少了污染物含量，增加的链烷烃含量，降低的矿山相关指数和增加的美国石油研究所重力的加氢处理流出物的条件下操作。 在蒸汽存在下，加氢处理的流出物被热裂解以产生分离的混合产物流。 将来自混合产物流的氢气纯化并再循环至加氢处理区，并从分离的混合产物流中回收烯烃和芳族化合物。
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3.发明申请INTEGRATED HYDROPROCESSING, STEAM PYROLYSIS AND CATALYTIC CRACKING PROCESS TO PRODUCE PETROCHEMICALS FROM CRUDE OIL 有权一体化水解，蒸汽热解和催化裂化工艺从原油生产石油化工公开(公告)号：US20130248419A1
公开(公告)日：2013-09-26
申请号：US13847945
申请日：2013-03-20
CPC分类号： C10G69/06 , C10G9/16 , C10G11/00 , C10G45/00 , C10G47/00 , C10G49/007 , C10G51/02 , C10G51/04 , C10G51/06 , C10G55/04 , C10G55/06 , C10G67/10 , C10G69/00 , C10G69/04 , C10G2300/201 , C10G2300/308 , C10G2400/20 , C10G2400/22 , C10G2400/30
摘要： An integrated hydrotreating, steam pyrolysis and catalytic cracking process for the production of olefins and aromatic petrochemicals from a crude oil feedstock is provided. Crude oil and hydrogen are charged to a hydroprocessing zone under conditions effective to produce a hydroprocessed effluent, which is thermally cracked in the presence of steam in a steam pyrolysis zone to produce a mixed product stream. Heavy components are catalytically cracked, which are derived from one or more of the hydroprocessed effluent, a heated stream within the steam pyrolysis zone, or the mixed product stream catalytically cracking. Catalytically cracked products are produced, which are combined with the mixed product stream and the combined stream is separated, and olefins and aromatics are recovered as product streams.
摘要翻译： 提供了一种用于从原油原料生产烯烃和芳族石油化工的综合加氢处理，蒸汽热解和催化裂化方法。 在有效地产生加氢处理的流出物的条件下，将原油和氢气加入加氢处理区，该加氢处理流出物在蒸汽热解区的蒸汽存在下被热裂解以产生混合产物流。 重组分被催化裂解，其衍生自一种或多种加氢处理的流出物，蒸汽热解区内的加热流，或混合产物流催化裂解。 产生催化裂化产物，将其与混合产物流混合，并将合并的流分离，并将烯烃和芳族化合物作为产物流回收。
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4.发明申请INTEGRATED SOLVENT DEASPHALTING, HYDROTREATING AND STEAM PYROLYSIS PROCESS FOR DIRECT PROCESSING OF A CRUDE OIL 有权用于直接加工原油的集成溶剂去除，加氢和蒸汽热解过程公开(公告)号：US20130233768A1
公开(公告)日：2013-09-12
申请号：US13865062
申请日：2013-04-17
CPC分类号： C10G55/04 , C10G9/36 , C10G21/003 , C10G45/00 , C10G67/0463 , C10G67/049 , C10G69/06 , C10G2300/201 , C10G2300/308 , C10G2300/4081 , C10G2400/20 , C10G2400/30
摘要： A process is provided that is directed to a steam pyrolysis zone integrated with a solvent deasphalting zone and a hydrotreating zone to permit direct processing of crude oil feedstocks to produce petrochemicals including olefins and aromatics. The integrated solvent deasphalting, hydrotreating and steam pyrolysis process for the direct processing of a crude oil to produce olefinic and aromatic petrochemicals comprises: charging the crude oil to a solvent deasphalting zone with an effective amount of solvent for producing a deasphalted and demetalized oil stream and a bottom asphalt phase; charging the deasphalted and demetalized oil stream and hydrogen to a hydroprocessing zone operating under conditions effective to produce a hydroprocessed effluent reduced having a reduced content of contaminants, an increased paraffinicity, reduced Bureau of Mines Correlation Index, and an increased American Petroleum Institute gravity; thermally cracking the hydroprocessed effluent in the presence of steam to produce a mixed product stream; separating the mixed product stream; purifying hydrogen recovered from the mixed product stream and recycling it to the hydroprocessing zone; recovering olefins and aromatics from the separated mixed product stream; and recovering pyrolysis fuel oil from the separated mixed product stream.
摘要翻译： 提供了一种方法，其涉及与溶剂脱沥青区和加氢处理区整合的蒸汽热解区，以允许原油原料直接加工以生产包括烯烃和芳族化合物的石化产品。 用于直接加工原油以生产烯烃和芳族石油化学品的综合溶剂脱沥青，加氢处理和蒸汽热解过程包括：用有效量的溶剂将原油装入溶剂脱沥青区，用于产生脱沥青和脱金属的油料流， 底部沥青相; 将脱沥青和脱金属的油流和氢气加氢到加氢处理区，在有效地产生具有降低的污染物含量，增加的链烷烃含量，减少的矿山相关指数和增加的美国石油公司重力的加氢处理流出物的条件下操作; 在蒸汽存在下对加氢处理的流出物进行热裂解以产生混合产物流; 分离混合产物流; 净化从混合产物流中回收的氢并将其再循环到加氢处理区; 从分离的混合产物流中回收烯烃和芳族化合物; 并从分离的混合产物流中回收热解燃料油。
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5.发明申请INTEGRATED HYDROTREATING AND STEAM PYROLYSIS PROCESS INCLUDING HYDROGEN REDISTRIBUTION FOR DIRECT PROCESSING OF A CRUDE OIL 有权一体化加氢和蒸汽热解过程，包括用于直接加工原油的氢再分配公开(公告)号：US20130228495A1
公开(公告)日：2013-09-05
申请号：US13865043
申请日：2013-04-17
IPC分类号： C10G69/06
CPC分类号： C10G69/06 , C10G9/36 , C10G19/00 , C10G45/00 , C10G55/04 , C10G2300/201 , C10G2300/202 , C10G2300/205 , C10G2300/308 , C10G2400/20 , C10G2400/22 , C10G2400/30
摘要： Steam pyrolysis and hydroprocessing are integrated including hydrogen redistribution to permit direct processing of crude oil feedstocks to produce petrochemicals including olefins and aromatics. A feed is initially split into a light portion and a heavy portion, and the heavy portion is hydroprocessed. A hydroprocessed effluent is charged, along with steam, to a convection section of a steam pyrolysis zone. The mixture is heated and passed to a vapor-liquid separation section. A residual portion is removed and light components are charged to a pyrolysis section of the steam pyrolysis zone. A mixed product stream is recovered from the steam pyrolysis zone and it is separated into product including olefins and aromatics.
摘要翻译： 蒸汽热解和加氢处理包括氢再分配，以允许直接加工原油原料以生产包括烯烃和芳烃的石化产品。 进料最初分为轻部分和重部分，重部分进行加氢处理。 将加氢处理的流出物与蒸汽一起装入蒸气热解区的对流段。 将混合物加热并通入气液分离段。 去除残留部分，将轻组分加入到蒸汽热解区的热解段。 从蒸汽热解区回收混合产物流，将其分离成产物，包括烯烃和芳烃。
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6.发明申请INTEGRATED HYDROTREATING, SOLVENT DEASPHALTING AND STEAM PYROLYSIS PROCESS FOR DIRECT PROCESSING OF A CRUDE OIL 审中-公开一体化加氢处理，溶剂脱硫和蒸汽热解法直接加工原油公开(公告)号：US20130197284A1
公开(公告)日：2013-08-01
申请号：US13751646
申请日：2013-01-28
IPC分类号： C10G69/06
CPC分类号： C10G69/06 , B01D17/0217 , B01D19/0057 , B01D53/526 , B01D2256/16 , B01D2257/7025 , C10G9/36 , C10G19/00 , C10G21/003 , C10G55/04 , C10G67/0463 , C10G2400/20 , C10G2400/30 , Y02C20/20
摘要： A process is provided that is directed to a steam pyrolysis zone integrated with a hydrotreating zone and a solvent deasphalting zone to permit direct processing of crude oil feedstocks to produce petrochemicals including olefins and aromatics. The integrated hydrotreating, solvent deasphalting and steam pyrolysis process comprises charging the crude oil to a hydroprocessing zone operating under conditions effective to produce a hydroprocessed effluent reduced having a reduced content of contaminants, an increased paraffinicity, reduced Bureau of Mines Correlation Index, and an increased American Petroleum Institute gravity; charging the hydroprocessed effluent to a solvent deasphalting zone with an effective amount of solvent to produce a deasphalted and demetalized oil stream and a bottom asphalt phase; thermally cracking the deasphalted and demetalized oil stream in the presence of steam to produce a mixed product stream; separating the mixed product stream; purifying hydrogen recovered from the mixed product stream and recycling it to the hydroprocessing zone; recovering olefins and aromatics from the separated mixed product stream; and recovering pyrolysis fuel oil from the separated mixed product stream.
摘要翻译： 提供了一种方法，其涉及与加氢处理区和溶剂脱沥青区一体化的蒸汽热解区，以允许直接处理原油原料以生产包括烯烃和芳族化合物的石油化学品。 综合的加氢处理，溶剂脱沥青和蒸汽热解过程包括将原油装入加氢处理区，该加氢处理区在有效产生具有降低的污染物含量，降低的污染物含量，降低的矿物相关指数局和减少的矿物相关指数减少的加氢处理流出物的条件下操作 美国石油学院重力; 将加氢处理的流出物用有效量的溶剂装入溶剂脱沥青区，以产生脱沥青和脱金属的油料流和底部沥青相; 在蒸汽存在下对脱沥青和脱金属精油流进行热裂解以产生混合产物流; 分离混合产物流; 净化从混合产物流中回收的氢并将其再循环到加氢处理区; 从分离的混合产物流中回收烯烃和芳族化合物; 并从分离的混合产物流中回收热解燃料油。
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7.发明申请INTEGRATED HYDROTREATING AND STEAM PYROLYSIS PROCESS INCLUDING RESIDUAL BYPASS FOR DIRECT PROCESSING OF A CRUDE OIL 有权一体化加氢和蒸汽热分解过程，包括用于直接加工原油的残留旁路公开(公告)号：US20130233767A1
公开(公告)日：2013-09-12
申请号：US13865060
申请日：2013-04-17
IPC分类号： C10G69/06
CPC分类号： C10G69/06 , C10G9/36 , C10G45/00 , C10G2300/201 , C10G2300/308 , C10G2300/4081 , C10G2400/20 , C10G2400/30
摘要： A process is provided that is directed to a steam pyrolysis zone integrated with a hydroprocessing zone including residual bypass to permit direct processing of crude oil feedstocks to produce petrochemicals including olefins and aromatics. The integrated hydrotreating and steam pyrolysis process for the direct processing of a crude oil to produce olefinic and aromatic petrochemicals comprises separating the crude oil into light components and heavy components; charging the light components and hydrogen to a hydroprocessing zone operating under conditions effective to produce a hydroprocessed effluent reduced having a reduced content of contaminants, an increased paraffinicity, reduced Bureau of Mines Correlation Index, and an increased American Petroleum Institute gravity; thermally cracking the hydroprocessed effluent in the presence of steam to produce a mixed product stream; separating the mixed product stream; purifying hydrogen recovered from the mixed product stream and recycling it to the hydroprocessing zone; recovering olefins and aromatics from the separated mixed product stream; and recovering a combined stream of pyrolysis fuel oil from the separated mixed product stream and heavy components from step (a) as a fuel oil blend.
摘要翻译： 提供了一种方法，其涉及与包含残留旁路的加氢处理区整合的蒸汽热解区，以允许原油原料直接加工以生产包括烯烃和芳族化合物的石油化学品。 用于直接加工原油以生产烯烃和芳族石油化学品的综合加氢处理和蒸汽热解方法包括将原油分离成轻组分和重组分; 将轻组分和氢充入加氢处理区，其工作条件有效地产生具有降低的污染物含量，增加的链烷烃含量，减少的矿物相关指数和美国石油公司重力增加的加氢处理废水。 在蒸汽存在下对加氢处理的流出物进行热裂解以产生混合产物流; 分离混合产物流; 净化从混合产物流中回收的氢并将其再循环到加氢处理区; 从分离的混合产物流中回收烯烃和芳族化合物; 并从分离的混合产物流和作为燃料油混合物的步骤（a）的重组分回收热解燃料油的混合物流。
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8.发明申请公开(公告)号：US20130197289A1
公开(公告)日：2013-08-01
申请号：US13751573
申请日：2013-01-28
IPC分类号： C10G55/04
CPC分类号： C10G55/04 , C10G9/16 , C10G21/003 , C10G47/22 , C10G47/34 , C10G67/04 , C10G67/049
摘要： A process is provided that is directed to a steam pyrolysis zone integrated with a solvent deasphalting zone to permit direct processing of crude oil feedstocks to produce petrochemicals including olefins and aromatics. The integrated solvent deasphalting and steam pyrolysis process for the direct processing of a crude oil to produce olefinic and aromatic petrochemicals comprises charging the crude oil to a solvent deasphalting zone with an effective amount of solvent to produce a deasphalted and demetalized oil stream and a bottom asphalt phase; thermally cracking the deasphalted and demetalized oil stream in the presence of steam to produce a mixed product stream; separating the mixed product stream; recovering olefins and aromatics from the separated mixed product stream; and recovering pyrolysis fuel oil from the separated mixed product stream.
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9.发明申请INTEGRATED HYDROTREATING AND STEAM PYROLYSIS PROCESS INCLUDING RESIDUAL BYPASS FOR DIRECT PROCESSING OF A CRUDE OIL 审中-公开一体化加氢和蒸汽热分解过程，包括用于直接加工原油的残留旁路公开(公告)号：US20130197283A1
公开(公告)日：2013-08-01
申请号：US13751395
申请日：2013-01-28
IPC分类号： C10G69/06
CPC分类号： C10G69/06 , B01D17/0217 , B01D19/0057 , C10G9/16 , C10G45/44 , C10G55/04 , C10G2300/4081 , C10G2400/20 , C10G2400/30
摘要： A process is provided that is directed to a steam pyrolysis zone integrated with a hydroprocessing zone including residual bypass to permit direct processing of crude oil feedstocks to produce petrochemicals including olefins and aromatics. The integrated hydrotreating and steam pyrolysis process for the direct processing of a crude oil to produce olefinic and aromatic petrochemicals comprises separating the crude oil into light components and heavy components; charging the light components and hydrogen to a hydroprocessing zone operating under conditions effective to produce a hydroprocessed effluent reduced having a reduced content of contaminants, an increased paraffinicity, reduced Bureau of Mines Correlation Index, and an increased American Petroleum Institute gravity; thermally cracking the hydroprocessed effluent in the presence of steam to produce a mixed product stream; separating the mixed product stream; purifying hydrogen recovered from the mixed product stream and recycling it to the hydroprocessing zone ; recovering olefins and aromatics from the separated mixed product stream; and recovering a combined stream of pyrolysis fuel oil from the separated mixed product stream and heavy components from step (a) as a fuel oil blend.
摘要翻译： 提供了一种方法，其涉及与包含残留旁路的加氢处理区整合的蒸汽热解区，以允许原油原料直接加工以生产包括烯烃和芳族化合物的石油化学品。 用于直接加工原油以生产烯烃和芳族石油化学品的综合加氢处理和蒸汽热解方法包括将原油分离成轻组分和重组分; 将轻组分和氢充入加氢处理区，其工作条件有效地产生具有降低的污染物含量，增加的链烷烃含量，减少的矿物相关指数和美国石油公司重力增加的加氢处理废水。 在蒸汽存在下对加氢处理的流出物进行热裂解以产生混合产物流; 分离混合产物流; 净化从混合产物流回收的氢并将其再循环到加氢处理区; 从分离的混合产物流中回收烯烃和芳族化合物; 并从分离的混合产物流和作为燃料油混合物的步骤（a）的重组分回收热解燃料油的混合物流。
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公开(公告)号：US20130220884A1
公开(公告)日：2013-08-29
申请号：US13865050
申请日：2013-04-17
IPC分类号： C10G69/06
CPC分类号： C10G69/06 , C10G9/36 , C10G21/003 , C10G45/00 , C10G55/04 , C10G67/0463 , C10G2300/201 , C10G2300/308 , C10G2300/4081 , C10G2400/20 , C10G2400/22 , C10G2400/30
摘要： A process is provided that is directed to a steam pyrolysis zone integrated with a hydrotreating zone and a solvent deasphalting zone to permit direct processing of crude oil feedstocks to produce petrochemicals including olefins and aromatics. The integrated hydrotreating, solvent deasphalting and steam pyrolysis process comprises charging the crude oil to a hydroprocessing zone operating under conditions effective to produce a hydroprocessed effluent reduced having a reduced content of contaminants, an increased paraffinicity, reduced Bureau of Mines Correlation Index, and an increased American Petroleum Institute gravity; charging the hydroprocessed effluent to a solvent deasphalting zone with an effective amount of solvent to produce a deasphalted and demetalized oil stream and a bottom asphalt phase; thermally cracking the deasphalted and demetalized oil stream in the presence of steam to produce a mixed product stream; separating the mixed product stream; purifying hydrogen recovered from the mixed product stream and recycling it to the hydroprocessing zone; recovering olefins and aromatics from the separated mixed product stream; and recovering pyrolysis fuel oil from the separated mixed product stream.
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