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1.发明授权Glass composition including sulfides having low visible and IR transmission 有权包括具有低可见光和IR透射率的硫化物的玻璃组合物公开(公告)号：US06927186B2
公开(公告)日：2005-08-09
申请号：US10309410
申请日：2002-12-04
申请人： Richard Hulme , Michael Cable , Ksenia A. Landa
发明人： Richard Hulme , Michael Cable , Ksenia A. Landa
摘要： A soda-lime-silica based privacy glass, having a visible transmission (Lta) of no greater than 25% and an infrared (IR) transmission no greater than 25%, includes the following colorants in addition to the base glass: total iron (expressed as Fe2O3): 0.1 to 1.0% cobalt oxide (e.g., Co3O4): 0 to 1,000 ppm sulfides (S2−): 0.0001 to 0.10%. In certain other embodiments the visible transmission may be higher, but low IR transmission is still realized.
摘要翻译： 具有不大于25％的可见透射率（Lta）和不大于25％的红外（IR）透射率的钠钙硅基隐私玻璃除了基础玻璃之外还包括以下着色剂：总铁（ 表示为Fe 2 O 3 O 3）：0.1至1.0％的氧化钴（例如，Co 3 O 4） ：0〜1,000ppm硫化物（S≤2〜）：0.0001〜0.10％。 在某些其他实施例中，可视传输可能更高，但仍然实现低IR传输。
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公开(公告)号：US07560403B2
公开(公告)日：2009-07-14
申请号：US11581779
申请日：2006-10-17
CPC分类号： C03C3/095
摘要： Glass is provided so as to have high visible transmission and/or fairly clear or neutral color. In certain example embodiments, the glass includes a low amount of iron coupled with erbium (Er, including an oxide thereof) designed to provide a neutral color and high transmittance. In certain example embodiments, the amount of SO3 in the glass composition is increased in order to provide increased visible transmission, without sacrificing neutral color. The glass may optionally include a small amount of cobalt (Co, including an oxide thereof) in certain example instances.
摘要翻译： 提供玻璃以具有高可见透射和/或相当清晰或中性的颜色。 在某些示例性实施例中，玻璃包括与设计成提供中性和高透射率的铒（Er，包括其氧化物）结合的少量铁。 在某些示例性实施方案中，增加了玻璃组合物中的SO 3的量，以提供增加的可见透射率，而不牺牲中性色。 在某些示例中，玻璃可以任选地包括少量的钴（Co，包括其氧化物）。
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公开(公告)号：US20090124480A1
公开(公告)日：2009-05-14
申请号：US12314810
申请日：2008-12-17
申请人： Ksenia A. Landa , Leonid Landa , Richard Hulme , Scott V. Thomsen
发明人： Ksenia A. Landa , Leonid Landa , Richard Hulme , Scott V. Thomsen
IPC分类号： C03C3/087
摘要： A high transmittance fairly clear/neutral colored glass composition is provided. An oxidizing agent(s) such as cerium oxide (e.g., CeO2) or the like is added to the glass batch in order to realize very oxidized conditions (i.e., to significantly lower the redox of the resulting glass). As a result of the oxidizing agent(s) used in the batch, the iron is oxidized to a very low FeO (ferrous state) content. For example, this may result in a glass having a glass redox value of no greater than 0.12 (more preferably
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公开(公告)号：US06949484B2
公开(公告)日：2005-09-27
申请号：US10457552
申请日：2003-06-10
申请人： Leonid Landa , Ksenia A. Landa , Scott V. Thomsen , Richard Hulme
发明人： Leonid Landa , Ksenia A. Landa , Scott V. Thomsen , Richard Hulme
摘要： Glass is provided so as to have high visible transmission and/or fairly clear or neutral color. In certain example embodiments of making glass according to examples of the invention, the glass batch may include a base glass (e.g., soda lime silica base glass) and, in addition, by weight percentage: total iron (expressed as Fe2O3): 0.01 to 0.30% erbium oxide (e.g., Er2O3): 0.01 to 0.30% cerium oxide (e.g., CeO2):0.005 to 0.30%. Optionally, neodymium oxide (e.g., Nd2O3) may also be provided in the glass in certain example embodiments. In other embodiments, the cerium oxide may be replaced with or supplemented by NaNO3 or some other nitrate(s) as an oxidizer.
摘要翻译： 提供玻璃以具有高可见透射和/或相当清晰或中性的颜色。 在根据本发明的实施例制造玻璃的某些示例性实施方案中，玻璃批料可以包括基础玻璃（例如，钠钙硅胶基础玻璃），并且还包括按重量百分比：
总铁（表示为Fe 2 3 ）： 0.01〜0.30 ％ 氧化铒（例如，呃呃O O 3 3）： 0.01〜0.30％ 氧化铈（例如CeO 2 2）： 0.005〜0.30％ 可选地，氧化钕（例如，Nd 2 3 3）。 在其它实施方案中，氧化铈可以被NaNO 3 N 3或一些其它硝酸盐替代或补充为氧化剂。 -
公开(公告)号：US20080090718A1
公开(公告)日：2008-04-17
申请号：US11581779
申请日：2006-10-17
IPC分类号： C03C3/095
CPC分类号： C03C3/095
摘要： Glass is provided so as to have high visible transmission and/or fairly clear or neutral color. In certain example embodiments, the glass includes a low amount of iron coupled with erbium (Er, including an oxide thereof) designed to provide a neutral color and high transmittance. In certain example embodiments, the amount of SO3 in the glass composition is increased in order to provide increased visible transmission, without sacrificing neutral color. The glass may optionally include a small amount of cobalt (Co, including an oxide thereof) in certain example instances.
摘要翻译： 提供玻璃以具有高可见透射和/或相当清晰或中性的颜色。 在某些示例性实施例中，玻璃包括与设计成提供中性和高透射率的铒（Er，包括其氧化物）结合的少量铁。 在某些示例性实施方案中，玻璃组合物中SO 3的量增加，以提供增加的可见透射率，而不牺牲中性色。 在某些示例中，玻璃可以任选地包括少量的钴（Co，包括其氧化物）。
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公开(公告)号：US20080085827A1
公开(公告)日：2008-04-10
申请号：US11543999
申请日：2006-10-06
IPC分类号： C03C3/102
摘要： Glass is provided so as to have high visible transmission and/or fairly clear or neutral color. In certain example embodiments, the clear glass includes a low amount of iron coupled with zinc oxide and/or erbium oxide in amounts designed to provide a neutral color. While the erbium oxide is used to provide for neutral color, the zinc oxide binds sulfur into whitish-colored zinc sulfide thereby reducing the amount of sulfur that binds/bonds with iron in the glass to form sulfides of iron which is/are brownish in color. Thus, the use of the zinc oxide helps make the glass more neutral in color. In certain example embodiments, the use of the erbium oxide brings the a* color value of the resulting glass closer to zero, whereas the use of the zinc oxide brings the b* value of the resulting glass closer to zero.
摘要翻译： 提供玻璃以具有高可见透射和/或相当清晰或中性的颜色。 在某些示例性实施例中，透明玻璃包括以设计成提供中性色的量的少量与氧化锌和/或氧化铒相结合的铁。 虽然氧化铒用于提供中性色素，但是氧化锌将硫结合成发白色的硫化锌，从而减少与玻璃中的铁结合/结合的硫的量，以形成棕色的铁的硫化物 。 因此，使用氧化锌有助于使玻璃的颜色更中性。 在某些示例性实施方案中，使用铒氧化物使所得玻璃的a *颜色值更接近于零，而使用氧化锌使所得玻璃的b *值更接近零。
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公开(公告)号：US07169722B2
公开(公告)日：2007-01-30
申请号：US10667975
申请日：2003-09-23
申请人： Ksenia A. Landa , Leonid Landa , Richard Hulme , Scott V. Thomsen
发明人： Ksenia A. Landa , Leonid Landa , Richard Hulme , Scott V. Thomsen
IPC分类号： C03C3/087
摘要： A high transmittance fairly clear/neutral colored glass composition is provided. An oxidizing agent(s) such as cerium oxide (e.g., CeO2) or the like is added to the glass batch in order to realize very oxidized conditions (i.e., to significantly lower the redox of the resulting glass). As a result of the oxidizing agent(s) used in the batch, the iron is oxidized to a very low FeO (ferrous state) content. For example, this may result in a glass having a glass redox value of no greater than 0.12 (more preferably
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公开(公告)号：US06953759B2
公开(公告)日：2005-10-11
申请号：US10227530
申请日：2002-08-26
申请人： Ksenia A. Landa , Leonid Landa , Richard Hulme
发明人： Ksenia A. Landa , Leonid Landa , Richard Hulme
CPC分类号： C03C3/087 , C03C1/00 , C03C4/02 , C03C4/082 , Y10S501/904 , Y10S501/905
摘要： A glass having a visible transmission of no greater than 28% and low IR transmission, and employing a colorant portion: total iron (expressed as Fe2O3): 0.7 to 1.8% cobalt oxide (e.g., Co3O4):0.001 to 1.0% titanium oxide (e.g., TiO2): 0.25 to 3.0% selenium (e.g., Se): 0 to 0.0020% chromium oxide (e.g., Cr2O3): 0 to 0.010%.
摘要翻译： 具有不大于28％的可见透射率和低IR透射率的玻璃，并且使用着色剂部分：
（表示为Fe 2 O 3 3）： 0.7至1.8％ < 进入>氧化钴（例如，CO 3 O 4）： 0.001至1.0％ 氧化钛（例如TiO 2）： 0.25至3.0％ 硒（例如Se）： 0至0.0020％ 氧化物（例如，Cr 2 O 3 3）： 0至0.010％。 -
9.发明授权Low iron transmission float glass for solar cell applications and method of making same 失效用于太阳能电池应用的低铁传输浮法玻璃及其制造方法公开(公告)号：US07893350B2
公开(公告)日：2011-02-22
申请号：US12453275
申请日：2009-05-05
IPC分类号： H01L31/042 , C03C3/087 , C03C3/095
CPC分类号： C03C3/087 , C03C4/0092 , C03C4/10 , C03C17/36 , C03C17/3678 , C03C2217/944 , H01L31/02366 , H01L31/03921 , Y02E10/50
摘要： Certain example embodiments of this invention relate to a high transmission low iron glass, which is highly oxidized and made using the float process, for use in photovoltaic devices such as solar cells or the like. In certain example embodiments, the glass composition used for the glass is made via the float process using an extremely high and positive batch redox in order to reduce % FeO to a low level and permit the glass to consistently realize a combination of high visible transmission (Lta or Tvis), high infrared (IR) transmission, and high total solar (TS) transmission. The glass substrate may be patterned or not patterned in different example embodiments of this invention.
摘要翻译： 本发明的某些示例性实施例涉及一种用于太阳能电池等太阳能装置的使用浮法的高度氧化和制造的高透光率低铁玻璃。 在某些示例性实施例中，用于玻璃的玻璃组合物通过使用非常高和正批式氧化还原的浮法来制造，以便将FeO％降低至低水平，并允许玻璃一致地实现高可见透射（ Lta或Tvis），高红外（IR）传输和高总太阳能（TS）传输。 可以在本发明的不同示例性实施例中对玻璃基板进行图案化或未图案化。
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公开(公告)号：US07772144B2
公开(公告)日：2010-08-10
申请号：US11196477
申请日：2005-08-04
摘要： A soda-lime-silica based glass composition for manufacturing on a float line that has a faster refining rate due to the introduction of alkali earth oxides such as BaO, ZnO and/or SrO in the amount of from about 1-4% in total. These oxides replace part or all of the MgO in the base glass composition thereby decreasing the overall MgO content in the glass composition to about 2% or less. The glass can realize a lower viscosity at high temperatures so that refining of the melt may occur faster.
摘要翻译： 一种用于制造浮法线的钠钙二氧化硅基玻璃组合物，其由于引入碱土金属氧化物如BaO，ZnO和/或SrO而具有更高的精炼速率，其总量为约1-4％ 。 这些氧化物代替基础玻璃组合物中的部分或全部MgO，从而将玻璃组合物中的MgO总量降低到约2％以下。 玻璃可以在高温下实现较低的粘度，从而可以更快地发生熔体的精炼。
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