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1.发明授权Hydroxyl functional derivatives of epoxidized diene polymers and process for making them 失效环氧化二烯聚合物的羟基官能衍生物及其制备方法
公开(公告)号：US5262496A
公开(公告)日：1993-11-16
申请号：US049691
申请日：1993-04-16
IPC分类号： C08C19/40 , C08F8/00 , C08G18/62 , C09D175/04
CPC分类号： C09D175/04 , C08C19/40 , C08F8/00 , C08G18/6208
摘要： A process for making polymers of conjugated dienes which contain hydroxyl groups, including highly reactive primary hydroxyl groups, in the diene blocks which comprises(a) making a precursor polymer by polymerizing at least one conjugated diene which leaves 1,2 disubstituted, 1,1 disubstituted, 1,1,2 trisubstituted or tetrasubstituted olefinic unsaturation in the polymer,(b) optionally partially hydrogenating said precursor polymer,(c) epoxidizing said precursor polymer such that epoxy groups form at said substituted sites and the amount of epoxy functionality in the polymer is from at least 0.1 Meq/g polymer, and(d) reacting the epoxidized polymer with an alcohol having one unprotected hydroxyl group in a solvent in the presence of a Lewis acid selected from the group consisting of MX.sub.n where M is selected from the group consisting of boron, aluminum, iron and tin, and X is a halogen, and organic complexes of such acids.A diene polymer containing 0.01 to 15 Meq/g polymer of hydroxyl group, preferably including highly reactive primary hydroxyl groups, and comprised of ether-alcohol units of the formula ##STR1## where R is selected from the group consisting of alkyl radicals containing up to 10 carbon atoms, monohydric and dihydric alcohol groups and carbonate groups; and R.sub.1 and R.sub.2 are hydrogen or alkyl radicals wherein in (G) only one of R.sub.1 or R.sub.2 is hydrogen.
摘要翻译： 在二烯嵌段中制备含有羟基（包括高反应性伯羟基）的共轭二烯的聚合物的方法，其包括（a）通过聚合至少一种离去1,2-二取代的共轭二烯制备前体聚合物，1,1 聚合物中的二取代的，1,1,2三取代或四取代的烯属不饱和键，（b）任选地部分氢化所述前体聚合物，（c）环氧化所述前体聚合物，使得环氧基在所述取代部位形成， 聚合物为至少0.1Meq / g聚合物，和（d）使环氧化聚合物与具有一个未保护羟基的醇在溶剂中，在路易斯酸存在下反应，该路易斯酸选自MXn，其中M选自 由硼，铝，铁和锡组成的组，X是卤素，以及这些酸的有机络合物。 含有0.01至15Meq / g羟基聚合物的二烯聚合物，优选包括高度反应性的伯羟基，并且由选自以下的式（Ⅹ）或（IMA）（G）的醚 - 醇单元组成： 由含有至多10个碳原子的烷基组成的组，一元和二元醇基团和碳酸酯基团; 并且R 1和R 2是氢或烷基，其中在（G）中，R 1或R 2中只有一个是氢。
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2.发明授权Hydroxyl functional derivatives of epoxidized diene polymers and process for making them 失效环氧化二烯聚合物的羟基官能衍生物及其制备方法
公开(公告)号：US5284901A
公开(公告)日：1994-02-08
申请号：US49687
申请日：1993-04-16
IPC分类号： C08C19/40 , C08F8/00 , C08G18/62 , C09D175/04
CPC分类号： C09D175/04 , C08C19/40 , C08F8/00 , C08G18/6208
摘要： A process for making polymers of conjugated dienes which contain hydroxyl groups, including highly reactive primary hydroxyl groups, in the diene blocks which comprises(a) making a precursor polymer by polymerizing at least one conjugated diene which leaves 1,2 disubstituted, 1,1 disubstituted, 1,1,2 trisubstituted or tetrasubstituted olefinic unsaturation in the polymer,(b) optionally partially hydrogenating said precursor polymer,(c) epoxidizing said precursor polymer such that epoxy groups form at said substituted sites and the amount of epoxy functionality in the polymer is from at least 0.1 Meq/g polymer, and(d) reacting the epoxidized polymer with an alcohol having one unprotected hydroxyl group in a solvent in the presence of a Lewis acid selected from the group consisting of MX.sub.n where M is selected from the group consisting of boron, aluminum, iron and tin, and X is a halogen, and organic complexes of such acids.A diene polymer containing 0.01 to 15 Meq/g polymer of hydroxyl group, preferably including highly reactive primary hydroxyl groups, and comprised of ether-alcohol units of the formula ##STR1## where R is selected from the group consisting of alkyl radicals containing up to 10 carbon atoms, monohydric and dihydric alcohol groups and carbonate groups; and R.sub.1 and R.sub.2 are hydrogen or alkyl radicals wherein in (G) only one of R.sub.1 or R.sub.2 is hydrogen.
摘要翻译： 在二烯嵌段中制备含有羟基（包括高反应性伯羟基）的共轭二烯的聚合物的方法，其包括（a）通过聚合至少一种离去1,2-二取代的共轭二烯制备前体聚合物，1,1 聚合物中的二取代的，1,1,2三取代或四取代的烯属不饱和键，（b）任选地部分氢化所述前体聚合物，（c）环氧化所述前体聚合物，使得环氧基在所述取代部位形成， 聚合物为至少0.1Meq / g聚合物，和（d）使环氧化聚合物与具有一个未保护羟基的醇在溶剂中，在路易斯酸存在下反应，该路易斯酸选自MXn，其中M选自 由硼，铝，铁和锡组成的组，X是卤素，以及这些酸的有机络合物。 含有0.01〜15 Meq / g羟基聚合物的二烯聚合物，优选包括高反应性伯羟基，并且由式（*化学结构*）（F）或（*化学结构*）（ G）其中R选自含有至多10个碳原子的烷基，一元和二元醇基和碳酸酯基; 并且R 1和R 2是氢或烷基，其中在（G）中，R 1或R 2中只有一个是氢。
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3.发明授权Hydroxyl functional derivatives of epoxidized diene polymers and process for making them 失效环氧化二烯聚合物的羟基官能衍生物及其制备方法
公开(公告)号：US5264480A
公开(公告)日：1993-11-23
申请号：US49682
申请日：1993-04-16
IPC分类号： C08C19/40 , C08F8/00 , C08G18/62 , C09D175/04
CPC分类号： C09D175/04 , C08C19/40 , C08F8/00 , C08G18/6208
摘要： A process for making polymers of conjugated dienes which contain hydroxyl groups, including highly reactive primary hydroxyl groups, in the diene blocks which comprises(a) making a precursor polymer by polymerizing at least one conjugated diene which leaves 1,2 disubstituted, 1,1 disubstituted, 1,1,2 trisubstituted or tetrasubstituted olefinic unsaturation in the polymer,(b) optionally partially hydrogenating said precursor polymer,(c) epoxidizing said precursor polymer such that epoxy groups form at said substituted sites and the amount of epoxy functionality in the polymer is from at least 0.1 Meq/g polymer, and(d) reacting the epoxidized polymer with an alcohol having one unprotected hydroxyl group in a solvent in the presence of a Lewis acid selected from the group consisting of MX.sub.n where M is selected from the group consisting of boron, aluminum, iron and tin, and X is a halogen, and organic complexes of such acids.A diene polymer containing 0.01 to 15 Meq/g polymer of hydroxyl group, preferably including highly reactive primary hydroxyl groups, and comprised of ether-alcohol units of the formula ##STR1## where R is selected from the group consisting of alkyl radicals containing up to 10 carbon atoms, monohydric and dihydric alcohol groups and carbonate groups; and R.sub.1 and R.sub.2 are hydrogen or alkyl radicals wherein in (G) only one of R.sub.1 or R.sub.2 is hydrogen.
摘要翻译： 在二烯嵌段中制备含有羟基（包括高反应性伯羟基）的共轭二烯的聚合物的方法，其包括（a）通过聚合至少一种离去1,2-二取代的共轭二烯制备前体聚合物，1,1 聚合物中的二取代的，1,1,2三取代或四取代的烯属不饱和键，（b）任选地部分氢化所述前体聚合物，（c）环氧化所述前体聚合物，使得环氧基在所述取代部位形成， 聚合物为至少0.1Meq / g聚合物，和（d）使环氧化聚合物与具有一个未保护羟基的醇在溶剂中，在路易斯酸存在下反应，该路易斯酸选自MXn，其中M选自 由硼，铝，铁和锡组成的组，X是卤素，以及这些酸的有机络合物。 含有0.01至15Meq / g羟基聚合物的二烯聚合物，优选包括高度反应性的伯羟基，并且由式（I）所示的醚 - 醇单元组成，其中R选自含有至多 一个碳原子，一个羟基和二元醇基团和碳酸酯基团; 并且R 1和R 2是氢或烷基，其中在（G）中，R 1或R 2中只有一个是氢。
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公开(公告)号：US5242989A
公开(公告)日：1993-09-07
申请号：US863580
申请日：1992-04-03
IPC分类号： C08C19/40 , C08F8/00 , C08G18/62 , C09D175/04
CPC分类号： C09D175/04 , C08C19/40 , C08F8/00 , C08G18/6208
摘要： A process for making polymers of conjugated dienes which contain hydroxyl groups, including highly reactive primary hydroxyl groups, in the diene blocks which comprises(a) making a precursor polymer by polymerizing at least one conjugated diene which leaves 1,2 disubstituted, 1,1 disubstituted, 1,1,2 trisubstituted or tetrasubstituted olefinic unsaturation in the polymer,(b) optionally partially hydrogenating said precursor polymer,(c) epoxidizing said precursor polymer such that epoxy groups form at said substituted sites and the amount of epoxy functionality in the polymer is from at least 0.1 Meq/g polymer, and(d) reacting the epoxidized polymer with an alcohol having one unprotected hydroxyl group in a solvent in the presence of a Lewis acid selected from the group consisting of MX.sub.n where M is selected from the group consisting of boron, aluminum, iron and tin, and X is a halogen, and organic complexes of such acids.A diene polymer containing 0.01 to 15 Meq/g polymer of hydroxyl group, preferably including highly reactive primary hydroxyl groups, and comprised of ether-alcohol units of the formula ##STR1## where R is selected from the group consisting of alkyl radicals containing up to 10 carbon atoms, monohydric and dihydric alcohol groups and carbonate groups; and R.sub.1 and R.sub.2 are hydrogen or alkyl radicals wherein in (G) only one of R.sub.1 or R.sub.2 is hydrogen.
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公开(公告)号：US5356974A
公开(公告)日：1994-10-18
申请号：US217472
申请日：1994-03-24
IPC分类号： C08C19/40 , C08F8/00 , C08G18/62 , C09D175/04
CPC分类号： C09D175/04 , C08C19/40 , C08F8/00 , C08F8/04 , C08F8/12 , C08F8/32 , C08G18/6208 , C08F2810/20
摘要： A process for making polymers of conjugated dienes which contain hydroxyl groups in the diene blocks which comprises(a) making a precursor polymer by polymerizing at least one conjugated diene which leaves 1,2 disubstituted, 1,1 disubstituted, 1,1,2 trisubstituted or tetrasubstituted olefinic unsaturation in the polymer,(b) optionally partially hydrogenating said precursor polymer,(c) epoxidizing said precursor polymer such that epoxy groups form at said substituted sites and the amount of epoxy functionality in the polymer is from 0.1 to 5 Meq/g polymer, and(d) reacting the epoxidized polymer with an alcohol solution of hydrochloric acid.A diene polymer containing 0.1 to 10 Meq/g polymer of hydroxyl group and comprised of alcohol units of the formula ##STR1## where R.sub.1 and R.sub.2 are hydrogen or alkyl radicals and X and X' are either --OH or --Cl and at least one of them is --OH.
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6.发明授权Hydroxyl functional derivatives of epoxidized diene block copolymers and process for making them (II) 失效环氧二烯嵌段共聚物的羟基官能衍生物及其制备方法（II）
公开(公告)号：US5300586A
公开(公告)日：1994-04-05
申请号：US863648
申请日：1992-04-03
IPC分类号： C08C19/40 , C08F8/00 , C08G18/62 , C09D175/04
CPC分类号： C09D175/04 , C08C19/40 , C08F8/00 , C08F8/04 , C08F8/12 , C08F8/32 , C08G18/6208 , C08F2810/20
摘要： A process for making polymers of conjugated dienes which contain hydroxyl groups in the diene blocks which comprises(a) making a precursor polymer by polymerizing at least one conjugated diene which leaves 1,2 disubstituted, 1,1 disubstituted, 1,1,2 trisubstituted or tetrasubstituted olefinic unsaturation in the polymer,(b) optionally partially hydrogenating said precursor polymer,(c) epoxidizing said precursor polymer such that epoxy groups form at said substituted sites and the amount of epoxy functionality in the polymer is from 0.1 to 5 Meq/g polymer, and(d) reacting the epoxidized polymer with an alcohol solution of hydrochloric acid.A diene polymer containing 0.1 to 10 Meq/g polymer of hydroxyl group and comprised of alcohol units of the formula ##STR1## where R.sub.1 and R.sub.2 are hydrogen or alkyl radicals and X and X' are either --OH or --Cl and at least one of them is --OH.
摘要翻译： 一种在二烯嵌段中含有羟基的共轭二烯的聚合物的方法，其包括（a）通过聚合至少一种共轭二烯制备前体聚合物，所述共轭二烯离开1,2-二取代的1,1,1-二取代的1,1,2三取代 或聚合物中的四取代的烯属不饱和键，（b）任选地部分氢化所述前体聚合物，（c）使所述前体聚合物环氧化，使得环氧基在所述取代部位形成，聚合物中环氧官能度的量为0.1-5Meq / g聚合物，和（d）使环氧化聚合物与盐酸的醇溶液反应。 含有0.1〜10Meq / g羟基的二烯聚合物，由式（* CHEMICAL STRUCTURE *）的醇单元组成，其中R1和R2为氢或烷基，X和X'为-OH或-Cl， 其中至少一个是-OH。
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7.发明授权Hydroxyl functional derivatives of epoxidized diene block copolymers and process for making them (II) 失效环氧二烯嵌段共聚物的羟基官能衍生物及其制备方法（II）
公开(公告)号：US5356969A
公开(公告)日：1994-10-18
申请号：US217470
申请日：1994-03-24
IPC分类号： C08C19/40 , C08F8/00 , C08G18/62 , C09D175/04 , C08F8/30
CPC分类号： C09D175/04 , C08C19/40 , C08F8/00 , C08F8/04 , C08F8/12 , C08F8/32 , C08G18/6208 , C08F2810/20
摘要： A process for making polymers of conjugated dienes which contain hydroxyl groups in the diene blocks which comprises(a) making a precursor polymer by polymerizing at least one conjugated diene which leaves 1,2 disubstituted, 1,1 disubstituted, 1,1,2 trisubstituted or tetrasubstituted olefinic unsaturation in the polymer,(b) optionally partially hydrogenating said precursor polymer,(c) epoxidizing said precursor polymer such that epoxy groups form at said substituted sites and the amount of epoxy functionality in the polymer is from 0.1 to 5 Meq/g polymer, and(d) reacting the epoxidized polymer with an alcohol solution of hydrochloric acid.A diene polymer containing 0.1 to 10 Meq/g polymer of hydroxyl group and comprised of alcohol units of the formula ##STR1## where R.sub.1 and R.sub.2 are hydrogen or alkyl radicals and X and X' are either --OH or --Cl and at least one of them is --OH.
摘要翻译： 一种在二烯嵌段中含有羟基的共轭二烯的聚合物的方法，其包括（a）通过聚合至少一种共轭二烯制备前体聚合物，所述共轭二烯离开1,2-二取代的1,1,1-二取代的1,1,2三取代 或聚合物中的四取代的烯属不饱和键，（b）任选地部分氢化所述前体聚合物，（c）使所述前体聚合物环氧化，使得环氧基在所述取代部位形成，聚合物中环氧官能度的量为0.1-5Meq / g聚合物，和（d）使环氧化聚合物与盐酸的醇溶液反应。 包含0.1至10Meq / g羟基的聚合物并且由式（Ia）的醇单元组成的二烯聚合物，其中R 1和R 2是氢或烷基，X和X'是-OH或-Cl和至少一个 他们是-OH。
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公开(公告)号：US5356975A
公开(公告)日：1994-10-18
申请号：US217517
申请日：1994-03-24
IPC分类号： C08C19/40 , C08F8/00 , C08G18/62 , C09D175/04
CPC分类号： C09D175/04 , C08C19/40 , C08F8/00 , C08F8/04 , C08F8/12 , C08F8/32 , C08G18/6208 , C08F2810/20
摘要： A process for making polymers of conjugated dienes which contain hydroxyl groups in the diene blocks which comprises(a) making a precursor polymer by polymerizing at least one conjugated diene which leaves 1,2 disubstituted, 1,1 disubstituted, 1,1,2 trisubstituted or tetrasubstituted olefinic unsaturation in the polymer,(b) optionally partially hydrogenating said precursor polymer,(c) epoxidizing said precursor polymer such that epoxy groups form at said substituted sites and the amount of epoxy functionality in the polymer is from 0.1 to 5 Meq/g polymer, and(d) reacting the epoxidized polymer with an alcohol solution of hydrochloric acid.A diene polymer containing 0.1 to 10 Meq/g polymer of hydroxyl group and comprised of alcohol units of the formula ##STR1## where R.sub.1 and R.sub.2 are hydrogen or alkyl radicals and X and X' are either --OH or --Cl and at least one of them is --OH.
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9.发明授权Hydroxyl functional derivatives of epoxidized diene block copolymers and process for making them (II) 失效环氧二烯嵌段共聚物的羟基官能衍生物及其制备方法（II）
公开(公告)号：US5356970A
公开(公告)日：1994-10-18
申请号：US217397
申请日：1994-03-24
IPC分类号： C08C19/40 , C08F8/00 , C08G18/62 , C09D175/04 , C08F8/32
CPC分类号： C09D175/04 , C08C19/40 , C08F8/00 , C08F8/04 , C08F8/12 , C08F8/32 , C08G18/6208 , C08F2810/20
摘要： A process for making polymers of conjugated dienes which contain hydroxyl groups in the diene blocks which comprises(a) making a precursor polymer by polymerizing at least one conjugated diene which leaves 1,2 disubstituted, 1,1 disubstituted, 1,1,2 trisubstituted or tetrasubstituted olefinic unsaturation in the polymer,(b) optionally partially hydrogenating said precursor polymer,(c) epoxidizing said precursor polymer such that epoxy groups form at said substituted sites and the amount of epoxy functionality in the polymer is from 0.1 to 5 Meq/g polymer, and(d) reacting the epoxidized polymer with an alcohol solution of hydrochloric acid.A diene polymer containing 0.1 to 10 Meq/g polymer of hydroxyl group and comprised of alcohol units of the formula ##STR1## where R.sub.1 and R.sub.2 are hydrogen or alkyl radicals and X and X' are either --OH or --Cl and at least one of them is --OH.
摘要翻译： 一种在二烯嵌段中含有羟基的共轭二烯的聚合物的方法，其包括（a）通过聚合至少一种共轭二烯制备前体聚合物，所述共轭二烯离开1,2-二取代的1,1,1-二取代的1,1,2三取代 或聚合物中的四取代的烯属不饱和键，（b）任选地部分氢化所述前体聚合物，（c）使所述前体聚合物环氧化，使得环氧基在所述取代部位形成，聚合物中环氧官能度的量为0.1-5Meq / g聚合物，和（d）使环氧化聚合物与盐酸的醇溶液反应。 含有0.1〜10Meq / g羟基的二烯聚合物，其由式（III）或式（Ia）的醇单元组成，其中R 1和R 2为氢或烷基，X和X'为-OH或-Cl 并且其中至少一个是-OH。
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公开(公告)号：US5486568A
公开(公告)日：1996-01-23
申请号：US359805
申请日：1994-12-20
摘要： The capping of anionic polymers to make functionalized polymers is used to make heterotelechelic polymers by using a protected functional initiator to polymerize a polymer comprising a conjugated diene and then capping the polymer with low surface energy fluorocarbons. The protected functional groups are stable under a variety of conditions and then readily convert to more reactive terminal functional groups useful for making sealants, coatings, molded or extruded goods and fibers having low surface energy.
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