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公开(公告)号：US20200087582A1
公开(公告)日：2020-03-19
申请号：US16470694
申请日：2017-12-19
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： Dafer Mubarak Alshahrani , Shahid Azam , Abdullah Saad Al-Dughaither , Abdulmajeed Mohammed Al-Hamdan
Abstract: A method of treating a hydrocarbon stream includes: withdrawing an effluent stream comprising hydrocarbons and polymer from a reactor; contacting the effluent stream with a coolant stream; passing the effluent stream through a heat exchanger; wherein after passing the effluent stream through the heat exchanger, the heat exchanger is substantially free of polymer deposits.
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公开(公告)号：US11331655B2
公开(公告)日：2022-05-17
申请号：US16474101
申请日：2017-12-21
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： Abdullah Saad Al-Dughaither , Shahid Azam , Abdulmajeed Mohammed Al-Hamdan , Dafer Mubarak Alshahrani , Sebastiano Licciulli , Anina Wohl , Wolfgang Muller , Heinz Bolt , Andreas Meiswinkel , Tobias Meier , Ralf Noack
IPC: B01J31/18 , B01J31/14 , C07C2/26 , B01J37/24 , B01J37/22 , C08F4/78 , C07C11/08 , C07C11/107 , B01J31/16
Abstract: A method for preparing a homogenous catalyst for the production of linear alpha olefins includes: preparing a first pre-catalyst solution comprising a modifier and an organoaluminum compound in a first solvent wherein the first pre-catalyst solution is reacted and stored in a first vessel for a period of time of 1 hour to 90 days; preparing a second pre-catalyst solution comprising a second solvent, a ligand, and a chromium containing compound, wherein the second pre-catalyst solution is stored in a second vessel for a period of time of 1 hour to 90 days; and after a period of time, adding the first pre-catalyst solution to a catalyst pre-formation unit; after the same period of time, adding the second pre-catalyst solution to the catalyst pre-formation unit; forming a homogenous catalyst by mixing the first pre-catalyst solution and the second pre-catalyst solution; adding the homogeneous catalyst to a reaction vessel, wherein the reaction vessel comprises an alpha olefin; and forming the linear alpha olefin by mixing the homogeneous catalyst and the homogenous catalyst.
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公开(公告)号：US11285469B2
公开(公告)日：2022-03-29
申请号：US16473674
申请日：2017-12-28
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： Abdullah Saad Al-Dughaither , Shahid Azam , Abdulmajeed Mohammed Al-Hamdan , Dafer Mubarak Alshahrani , Sebastiano Licciulli , Andreas Meiswinkel , Heinz Bolt , Wolfgang Muller , Anina Wohl
IPC: B01J37/04 , B01J31/02 , B01J31/14 , C07C11/107
Abstract: A method for preparing a homogenous catalyst for use in preparing a linear alpha olefin includes: preparing a first pre-catalyst solution by mixing a chromium source and a ligand in a first solvent, wherein the first pre-catalyst solution is stored in a first vessel; preparing a second pre-catalyst solution by mixing an organoaluminum compound and a modifier in a second solvent, wherein the second pre-catalyst solution is stored in a second vessel; and simultaneously feeding the first pre-catalyst solution and the second pre-catalyst solution directly into a reaction vessel, wherein the reaction vessel includes a third solvent.
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Patent Agency Ranking
公开(公告)号：US11254630B2
公开(公告)日：2022-02-22
申请号：US16470753
申请日：2017-12-19
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： Dafer Mubarak Alshahrani , Shahid Azam , Abdullah Saad Al-Dughaither , Abdulmajeed Mohammed Al-Hamdan
IPC: C07C7/04 , B01D3/14 , C07C11/04 , C07C11/08 , C07C11/107
Abstract: A method of separating linear alpha olefins, comprising: passing a feed stream comprising linear alpha olefins through a first column; distributing a C4− fraction to a top portion of the first column; withdrawing a C6+ fraction from a bottom portion of the first column and passing the C6+ fraction through a second column; distributing a C12+ fraction to a bottom portion of the second column; withdrawing a C10− fraction from a top portion of the second column and passing the C10− fraction through a third column, wherein the C10− fraction is substantially free of polymer; and distributing a C6 fraction to a top portion of the third column.
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公开(公告)号：US11225444B2
公开(公告)日：2022-01-18
申请号：US16471063
申请日：2017-12-19
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： Abdullah Saad Al-Dughaiter , Shahid Azam , Abdulmajeed Mohammed Al-Hamdan , Dafer Mubarak Alshahrani , Ralf Noack , Tobias Meier , Gabriel Waurick , Heinz Bolt , Andreas Meiswinkel , Wolfgang Müller , Anina Wohl , Hans-Jorge Zander
Abstract: A method of column control includes: passing a feed stream and a make-up stream through a column; withdrawing an overhead fraction from the column; purging at least a portion of the overhead fraction; cooling at least a portion of the overhead fraction in a heat exchanger and passing it through a reflux drum; withdrawing a purge stream and a distillate stream from the reflux drum, wherein the distillate stream has a constant flow rate; recycling at least a portion of the distillate stream back to the column; and passing at least a portion of the distillate stream to a downstream process.
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公开(公告)号：US20210130265A1
公开(公告)日：2021-05-06
申请号：US16471063
申请日：2017-12-19
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： Abdullah Saad Al-Dughaiter , Shahid Azam , Abdulmajeed Mohammed Al-Hamdan , Dafer Mubarak Alshahrani , Ralf Noack , Tobias Meier , Gabriel Waurick , Heinz Bolt , Andreas Meiswinkel , Wolfgang Müller , Anina Wohl , Hans-Jorge Zander
Abstract: A method of column control includes: passing a feed stream and a make-up stream through a column; withdrawing an overhead fraction from the column; purging at least a portion of the overhead fraction; cooling at least a portion of the overhead fraction in a heat exchanger and passing it through a reflux drum; withdrawing a purge stream and a distillate stream from the reflux drum, wherein the distillate stream has a constant flow rate; recycling at least a portion of the distillate stream back to the column; and passing at least a portion of the distillate stream to a downstream process.
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公开(公告)号：US20190351403A1
公开(公告)日：2019-11-21
申请号：US16473674
申请日：2017-12-28
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： Abdullah Saad Al-Dughaither , Shahid Azam , Abdulmajeed Mohammed Al-Hamdan , Dafer Mubarak Alshahrani , Sebastiano Licciulli , Andreas Meiswinkel , Heinz Bolt , Wolfgang Muller , Anina Wohl
IPC: B01J37/04 , B01J31/02 , B01J31/14 , C07C11/107
Abstract: A method for preparing a homogenous catalyst for use in preparing a linear alpha olefin includes: preparing a first pre-catalyst solution by mixing a chromium source and a ligand in a first solvent, wherein the first pre-catalyst solution is stored in a first vessel; preparing a second pre-catalyst solution by mixing an organoaluminum compound and a modifier in a second solvent, wherein the second pre-catalyst solution is stored in a second vessel; and simultaneously feeding the first pre-catalyst solution and the second pre-catalyst solution directly into a reaction vessel, wherein the reaction vessel includes a third solvent.
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公开(公告)号：US20190314798A1
公开(公告)日：2019-10-17
申请号：US16474101
申请日：2017-12-21
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： Abdullah Saad Al-Dughaither , Shahid Azam , Abdulmajeed Mohammed Al-Hamdan , Dafer Mubarak Alshahrani , Sebastiano Licciulli , Anina Wohl , Wolfgang Muller , Heinz Bolt , Andreas Meiswinkel , Tobias Meier , Ralf Noack
Abstract: A method for preparing a homogenous catalyst for the production of linear alpha olefins includes: preparing a first pre-catalyst solution comprising a modifier and an organoaluminum compound in a first solvent wherein the first pre-catalyst solution is reacted and stored in a first vessel for a period of time of 1 hour to 90 days; preparing a second pre-catalyst solution comprising a second solvent, a ligand, and a chromium containing compound, wherein the second pre-catalyst solution is stored in a second vessel for a period of time of 1 hour to 90 days; and after a period of time, adding the first pre-catalyst solution to a catalyst pre-formation unit; after the same period of time, adding the second pre-catalyst solution to the catalyst pre-formation unit; forming a homogenous catalyst by mixing the first pre-catalyst solution and the second pre-catalyst solution; adding the homogeneous catalyst to a reaction vessel, wherein the reaction vessel comprises an alpha olefin; and forming the linear alpha olefin by mixing the homogeneous catalyst and the homogenous catalyst.
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