公开(公告)号：US20220241764A1

公开(公告)日：2022-08-04

申请号：US17722794

申请日：2022-04-18

Applicant: SAUDI BASIC INDUSTRIES CORPORATION

Inventor： ANINA WOEHL ,  ANDREAS MEISWINKEL ,  HEINZ BOELT ,  BERND H. MUELLER ,  WOLFGANG MUELLER ,  NORMEN PEULECKE ,  UWE ROSENTHAL ,  MARCO HARFF ,  MOHAMMED H. AL-HAZMI ,  ABDULLAH ALQAHTANI

IPC: B01J31/18 ,  B01J31/14 ,  C07C2/36 ,  C07C2/32

Abstract: A catalyst composition including: (a) a chromium compound; (b) a ligand of the general structure (A) R1R2P—N(R3)—P(R4)—NR5R6 or (B) R1R2P—N(R3)—P(XR7)R8 or R1R2P—N(R3)—P(XR7)2, with X═O or S, wherein R1, R2, R3, R4, R5, R6, R7 and R8 are independently C1-C10-alkyl, C6-C20-aryl, C3-C10-cycloalkyl, aralkyl, alkylaryl, or trialkylsilyl, or any cyclic derivatives of (A) and (B), wherein at least one of the P or N atoms of the PNPN-unit or PNP-unit is a member of the ring system, the ring system being formed from one or more constituent compounds of structures (A) or (B) by substitution; and (c) an activator or co-catalyst; and a process for tri- and/or tetramerization.

公开(公告)号：US20190210011A1

公开(公告)日：2019-07-11

申请号：US16355298

申请日：2019-03-15

Applicant: SAUDI BASIC INDUSTRIES CORPORATION ,  LINDE AG

Inventor： ANINA WOEHL ,  ANDREAS MEISWINKEL ,  HEINZ BOELT ,  BERND H. MUELLER ,  WOLFGANG MUELLER ,  NORMEN PEULECKE ,  UWE ROSENTHAL ,  MARCO HARFF ,  MOHAMMED H. AL-HAZMI ,  ABDULLAH ALQAHTANI

IPC: B01J31/18 ,  C07C2/36 ,  B01J31/14 ,  C07C2/32

CPC classification number: B01J31/1885 ,  B01J31/143 ,  B01J2231/20 ,  B01J2531/62 ,  C07C2/32 ,  C07C2/36 ,  C07C2531/14 ,  C07C2531/22 ,  C07C2531/24 ,  Y02P20/52 ,  C07C11/02

Abstract: A catalyst composition including: (a) a chromium compound; (b) a ligand of the general structure R1R2P—N(R3)—P(XR7)2, wherein X is O or S, R1, R2, and R3 are each independently C1-C10-alkyl, C6-C20-cycloalkyl, arylalkyl, alkylaryl, or trialkylsilyl, or any cyclic derivatives of the ligand, wherein at least one of the P or N atoms of the PNP-unit is a member of the ring system, the ring system being formed from one or more constituent compounds of the ligand by substitution, and R7 is C1-C10-alkyl, C3-C10-cycloalkyl, arylalkyl, or trialkylsilyl; and (c) an activator or co-catalyst.

公开(公告)号：US20170128925A1

公开(公告)日：2017-05-11

申请号：US15379836

申请日：2016-12-15

Applicant: SAUDI BASIC INDUSTRIES CORPORATION ,  LINDE AG

Inventor： ANINA WOEHL ,  ANDREAS MEISWINKEL ,  HEINZ BOELT ,  BERND H. MUELLER ,  WOLFGANG MUELLER ,  NORMEN PEULECKE ,  UWE ROSENTHAL ,  MARCO HARFF ,  MOHAMMED H. AL-HAZMI ,  ABDULLAH ALQAHTANI

IPC: B01J31/18 ,  C07C2/32 ,  B01J31/14

CPC classification number: B01J31/1885 ,  B01J31/143 ,  B01J2231/20 ,  B01J2531/62 ,  C07C2/32 ,  C07C2/36 ,  C07C2531/14 ,  C07C2531/22 ,  C07C2531/24 ,  Y02P20/52 ,  C07C11/02

Abstract: A catalyst composition including: (a) a chromium compound; (b) a ligand of the general structure R1R2P—N(R3)—P(R4)—NR5R6 or  (A) R1R2P—N(R3)—P(XR7)R8 or R1R2P—N(R3)—P(XR7)2, with X=O or S,  (B) wherein R1, R2, R3, R4, R5, R6, R7 and R8 are independently C1-C10-alkyl, C6-C20-aryl, C3-C10-cycloalkyl, aralkyl, alkylaryl, or trialkylsilyl, or any cyclic derivatives of (A) and (B), wherein at least one of the P or N atoms of the PNPN-unit or PNP-unit is a member of the ring system, the ring system being formed from one or more constituent compounds of structures (A) or (B) by substitution; and (c) an activator or co-catalyst; and a process for tri- and/or tetramerization.

公开(公告)号：US20160167033A1

公开(公告)日：2016-06-16

申请号：US14908026

申请日：2014-07-28

Applicant: SAUDI BASIC INDUSTRIES CORPORATION ,  LINDE AGK

Inventor： ANINA WOEHL ,  ANDREAS MEISWINKLE ,  HEINZ BOELT ,  BERND H. MUELLER ,  WOLFGANG MUELLER ,  NORMEN PEULECKE ,  UWE ROSENTHAL ,  MARCO HARFF ,  MOHAMMED H. AL-HAZMI ,  ABDULLAH AL-QAHTANI

IPC: B01J31/18 ,  B01J31/14 ,  C07C2/32

CPC classification number: B01J31/1885 ,  B01J31/143 ,  B01J2231/20 ,  B01J2531/62 ,  C07C2/32 ,  C07C2/36 ,  C07C2531/14 ,  C07C2531/22 ,  C07C2531/24 ,  Y02P20/52 ,  C07C11/02

Abstract: A catalyst composition including: (a) a chromium compound; (b) a ligand of the general structure (A) R1R2P—N(R3)—P(R4)—NR5R6 or (B) R1R2P—N(R3)—P(XR7)R8 or R1R2P—N(R3)—P(XR7)2, with X=O or S, wherein R1, R2, R3, R4, R5, R6, R7 and R8 are independently C1-C10-alkyl, C6-C20-aryl, C3-C10-cycloalkyl, aralkyl, alkylaryl, or trialkylsilyl, or any cyclic derivatives of (A) and (B), wherein at least one of the P or N atoms of the PNPN-unit or PNP-unit is a member of the ring system, the ring system being formed from one or more constituent compounds of structures (A) or (B) by substitution; and (c) an activator or co-catalyst; and a process for tri- and/or tetramerization.

Abstract translation: 一种催化剂组合物，其包含：（a）铬化合物; （A）R 1 R 2 P -N（R 3）-P（R 4）-NR 5 R 6或（B）R 1 R 2 P-N（R 3）-P（XR 7）R 8或R 1 R 2 N-N（R 3）-P （XR7）2，其中X = O或S，其中R1，R2，R3，R4，R5，R6，R7和R8独立地为C1-C10-烷基，C6-C20-芳基，C3-C10-环烷基， 烷基芳基或三烷基甲硅烷基，或（A）和（B）的任何环状衍生物，其中PNPN单元或PNP单元的P或N原子中的至少一个是环系的成员，所述环系统形成 从结构（A）或（B）的一种或多种组成化合物通过取代; 和（c）活化剂或助催化剂; 以及三 - 和/或四聚过程。