公开(公告)号：US3446842A

公开(公告)日：1969-05-27

申请号：US3446842D

申请日：1966-08-04

申请人： SHELL OIL CO

发明人： NOZAKI KENZIE

IPC分类号： C07C233/00 ,  C07C103/02 ,  C07C103/36

CPC分类号： C07C233/00

公开(公告)号：US3694412A

公开(公告)日：1972-09-26

申请号：US3694412D

申请日：1971-03-04

申请人： SHELL OIL CO

发明人： NOZAKI KENZIE

IPC分类号： C08G67/02 ,  C08F1/64 ,  C08F13/04

CPC分类号： C08G67/02

摘要： HIGH MELTING, HIGH MOLECULAR WEIGHT INTERPOLYMERS OF CARBON MONOXIDE WITH AT LEAST ONE UNSATURATED COMPOUND SUCH AS THE ALIPHATIC MONOOLEFINS, I.E., ETHYLENE, ARE PREPARED BY REACTING CARBON MONOXIDE WITH SAID UNSATURATED COMPOUNDS IN THE PRESENCE OF AN ARYL PHOSPHINE COMPLEX OF A PALLADIUM HALIDE AND CERTAIN INERT SOLVENTS.

公开(公告)号：US3887595A

公开(公告)日：1975-06-03

申请号：US33811273

申请日：1973-03-05

申请人： SHELL OIL CO

发明人： NOZAKI KENZIE

IPC分类号： C07C67/38 ,  B01J31/00 ,  B01J31/24 ,  C07B61/00 ,  C07C51/00 ,  C07C51/14 ,  C07C51/54 ,  C07C67/00

CPC分类号： B01J31/2404 ,  B01J31/1616 ,  B01J31/24 ,  B01J2231/321 ,  B01J2531/824 ,  B01J2531/828 ,  C07C51/14

摘要： An improved catalyst composition for carbonylating olefinically unsaturated hydrocarbons with carbon monoxide and a hydroxylic compound comprises a zero-valent palladium or platinum complex incorporating stabilizing phosphine ligands, and excess ligand. Use of these catalyst compositions results in a high ratio of straight-chain to branch-chain product when employed in the carbonylation of alpha olefins to produce carboxylic acids, esters or acid anhydrides.

摘要翻译： 用于使烯属不饱和烃与一氧化碳和羟基化合物羰基化的改进的催化剂组合物包括含有稳定膦配体的零价钯或铂络合物和过量的配体。 当用于α-烯烃的羰基化以产生羧酸，酯或酸酐时，使用这些催化剂组合物导致直链与支链产物的高比例。

公开(公告)号：US3577466A

公开(公告)日：1971-05-04

申请号：US3577466D

申请日：1968-07-30

申请人： SHELL OIL CO

发明人： NOZAKI KENZIE

IPC分类号： C07C43/14

CPC分类号： C07C43/14

摘要： PRODUCTION OF ALLYLIC ETHERS BY REACTING IN HIGH CONVERSION AN ALLYLIC ALCOHOL OF THE FORMULA
WHERE R IS HYDROGEN, METHYL OR HYDROXYMETHYL AND R'' IS HYDROGEN OR METHYL, WITH ITSELF OR WITH A NONALLYLIC ALCOHOL IN THE PRESENCE AS CATALYST OF CUPRIC CHLORIDE OR BROMIDE OR ADDITIONALLY IN THE PRESENCE AS CATALYST PROMOTER OF AN ACIDIC MATERIAL OR AN ALLYLIC HALIDE, WHERE THE HALIDE IS CHLORIDE OR BROMIDE.

R-CH=CH-CHR''-OH

公开(公告)号：US3914391A

公开(公告)日：1975-10-21

申请号：US34468073

申请日：1973-03-26

申请人： SHELL OIL CO

发明人： NOZAKI KENZIE

IPC分类号： B01J27/26 ,  C01C3/08 ,  C08G67/02 ,  C01C3/00

CPC分类号： C01C3/08 ,  B01J27/26 ,  C08G67/02

摘要： A novel palladium-containing compound, HPd(CN)3, and its preparation are described. This compound is particularly useful as a catalyst for the copolymerization of carbon monoxide and ethylenically unsaturated monomers such as ethylene.

摘要翻译： 描述了一种新型的含钯化合物HPd（CN）3及其制备方法。 该化合物特别可用作一氧化碳和烯属不饱和单体如乙烯的共聚催化剂。

公开(公告)号：US3689460A

公开(公告)日：1972-09-05

申请号：US3689460D

申请日：1971-03-04

申请人： SHELL OIL CO

发明人： NOZAKI KENZIE

IPC分类号： C08G67/02 ,  C08F1/64 ,  C08F13/04

CPC分类号： C08G67/02

摘要： HIGH MELTING, CRYSTALLINE INTERPOLYMERS OF CARBON MONOXIDE WITH ONE OR MORE UNSATURATED COMPOUNDS SUCH AS ALIPHATIC MONOOLEFINS PARTICULARLY ETHYLENE, ARE PREPARED BY REACTING CARBON MONIXIDE WITH SAID UNSATURATED COMPOUNDS IN THE PRESENCE OF SELECTED INERT SOLVENTS AND A CATALYTIC AMOUNT OF TETRAKIS(TRIARYL PHOSPHINE) PALLADIUM, PARTICULARLY TETRAKIS(TRIPHENYL PHOSPHINE) PALLADIUM.