Trifluoromethyl acylated urea carbamates
    1.
    发明授权
    Trifluoromethyl acylated urea carbamates 失效
    三氟甲磺酸聚乙二醇

    公开(公告)号:US3670010A

    公开(公告)日:1972-06-13

    申请号:US3670010D

    申请日:1969-05-06

    发明人: TEACH EUGENE G

    CPC分类号: C07C275/34 C07C275/50

    摘要: Acylated urea carbamate compounds having the formula

    IN WHICH R1 and R3 are independently selected from an alkyl radical of from 1 to about 8 carbon atoms, inclusive, cyclohexyl, lower alkenyl of from about 3 to about 4 carbon atoms, inclusive, phenyl and substituted phenyl in which the substituents are lower alkyl, lower alkoxy, nitro and halogen; R and R2 are independently selected from hydrogen, alkyl of from 1 to about 8 carbon atoms, inclusive, cyclohexyl, lower alkenyl of from about 3 to about 4 carbon atoms, inclusive, and trifluoroacetyl; provided that at least one of R or R2 is trifluoroacetyl; and R4 is selected from hydrogen, methyl or when only one of R or R2 is trifluoroacetyl then R4 can be trifluoroacetyl. These compounds are prepared by the reaction of an appropriate carbamoyloxyphenyl urea and trifluoroacetic anhydride. The compounds are useful as herbicides.

    摘要翻译: 具有式IN的酰化尿素氨基甲酸酯化合物,其中R1和R3独立地选自1至约8个碳原子的烷基,包括环己基,约3至约4个碳原子的低级烯基,包括苯基和取代的苯基 其中取代基是低级烷基,低级烷氧基,硝基和卤素; R和R 2独立地选自氢,1至约8个碳原子的烷基,包括端基,环己基,约3至约4个碳原子的低级链烯基和三氟乙酰基; 条件是R或R 2中的至少一个为三氟乙酰基; 并且R 4选自氢,甲基,或者当R或R 2中只有一个是三氟乙酰基时,R 4可以是三氟乙酰基。 这些化合物通过适当的氨基甲酰氧基苯基脲和三氟乙酸酐的反应来制备。 该化合物可用作除草剂。

    Ether and sulfide meta-substituted phenyl ureas
    3.
    发明授权
    Ether and sulfide meta-substituted phenyl ureas 失效
    醚和硫化物间位取代的苯基脲

    公开(公告)号:US3903156A

    公开(公告)日:1975-09-02

    申请号:US48920974

    申请日:1974-07-17

    发明人: TEACH EUGENE G

    IPC分类号: C07C275/34 C07C127/19

    CPC分类号: C07C275/34

    摘要: Ether and sulfide meta-substituted phenyl ureas having the formula

    IN WHICH X is oxygen or sulfur; Y is oxygen or sulfur; R is alkyl, alkenyl, vinyloxyalkyl, alkylthioalkyl, alkyloxyalkyl, and ketoalkyl; R1 is hydrogen or lower alkyl; R2 is lower alkyl, alkoxyphenyl, alkenyl, cycloalkyl, and phenyl; provided that when X is oxygen, Y is oxygen, R is alkyl containing 1 to 3 carbon atoms, and R1 is hydrogen or lower alkyl, then R2 is other than lower alkyl containing 1 to 4 carbon atoms. The compounds of this invention are useful as herbicides.

    摘要翻译: 醚和硫化物间位取代的苯基脲,其具有式I,其中X是氧或硫; Y是氧或硫; R是烷基,烯基,乙烯基氧基烷基,烷硫基烷基,烷氧基烷基和酮基烷基; R1是氢或低级烷基; R2是低级烷基,烷氧基苯基,烯基,环烷基和苯基; 条件是当X为氧时,Y为氧,R为含有1至3个碳原子的烷基,R1为氢或低级烷基,则R2为含有1至4个碳原子的低级烷基。 本发明的化合物可用作除草剂。

    Acylated anilide carbamates
    5.
    发明授权
    Acylated anilide carbamates 失效
    ACYLATED ANILIDE CARBAMATES

    公开(公告)号:US3592949A

    公开(公告)日:1971-07-13

    申请号:US3592949D

    申请日:1968-03-29

    摘要: COMPOUNDS CORRESPONDING TO THE FORMULA

    ((3-R3-CO-HN-)PHENYL)-OOC-N(-R2)-CO-R1

    INWHICH R1 AND R2 ARE INDEPENDENTLY LOWER ALKYL, HALOGENATED LOWER ALKYL, LOWER ALKENYL, CYCLOALKYL, PHENYL, SUBSTITUTED PHENYL IN WHICH SUBSTITUENTS ARE NITRO, HALOGEN, LOWER ALKYL OR LOWER ALKOXY AND R3 IS HYDROGEN, LOWER ALKYL, CYCLOALKYL, HALOGENATED LOWER ALKYL, LOWER ALKENYL, FURYL OR BENZYL. THE ABOVE-DEFINED COMPOUNDS ARE EFFECTIVE AS HERBICIDES, INECTICIDES AND ANIMAL PARASITICIDES, ESPECIALLY AS ANTHELMINTHICS. REPRESENTATIVE COMPOUNDS ARE: 3'' - (N-METHYL - N- ACETYLCARBAMOYLOXY) FORMANILIDE; 3'' - N - ISOPROPYL - N- TRIFLUOROACETYLCARBAMOYLOXY PROPIONANILIDE; 3'' - N- BUTYL - N- TRIFLUOROACETYLCARBAMOLOXYPROPIONANILIDE; 3'' - (N - ISOBUTYRYLN - ISOPROPYLARBAMOYLOXY) PROPIONANILIDE; 3'' - (N - IPROPYL-N-CHLOROACETYL-CARBAMOYLOXY) PROPIONANILIDE.

    Esterified bromoacetanilides
    6.
    发明授权
    Esterified bromoacetanilides 失效
    酯化溴乙酰苯胺

    公开(公告)号:US3898273A

    公开(公告)日:1975-08-05

    申请号:US31103472

    申请日:1972-11-30

    CPC分类号: A01N37/24 C07C271/06

    摘要: Esterified bromoacetanilides as new compositions of matter and their activity as microbiocides. Representative compounds include 3''-bromoacetoxy bromoacetanilide, 3''-acetoxy bromoacetanilide, 3''-propionoxy bromoacetanilide, 3''-(p-methylbenzoxy) bromoacetanilide, 3''-cyclohexane carbonyloxybromoacetanilide.

    摘要翻译: 酯化的溴乙酰苯胺作为新物质组成及其作为杀生物剂的活性。 代表性的化合物包括3'-溴乙酰氧基溴乙酰苯胺,3'-乙酰氧基溴乙酰苯胺,3'-丙酰氧基溴乙酰苯胺,3' - (对甲基苯甲氧基)溴乙酰苯胺,3'-环己烷羰氧基溴乙酰苯胺。

    Meta-anilide urea compositions and their utility as herbicides
    7.
    发明授权
    Meta-anilide urea compositions and their utility as herbicides 失效
    元苯胺尿素组合物及其作为除草剂的效用

    公开(公告)号:US3897493A

    公开(公告)日:1975-07-29

    申请号:US44463074

    申请日:1974-02-22

    发明人: TEACH EUGENE G

    CPC分类号: C07C275/40

    摘要: Meta-anilide urea compositions have the formula:

    IN WHICH X and Y are, independently, oxygen and sulfur; R1 is hydrogen or lower alkyl; R2 and R3 are, independently, hydrogen, alkyl, lower alkoxy, haloalkyl, lower alkenyl, cycloalkyl having from 3 to 6 carbon atoms, inclusive, carbalkoxyalkyl, furfuryl, naphthyl, phenyl or substituted-phenyl, inclusive, in which the substituents are halogen, nitro, or lower alkoxy; R4 is hydrogen or lower alkyl; R5 is hydrogen, alkyl, ethyl cycloalkyl, lower alkenyl, halogenated lower alkyl, cycloalkyl having 3 to 6 carbon atoms, inclusive, pinonoyl 2,4-dichlorophenoxymethylene, benzyl, phenyl, or substituted-phenyl in which the substituents are halogen, nitro, lower alkyl, lower alkoxy or trihalomethyl; Z is halogen, lower alkyl, nitro, amino or trifluoromethyl, and m is an integer having a value from 0 to 4, inclusive, provided that when R1, R2, R3 and R4 are each hydrogen, X and Y are each oxygen and m is O, then R5 is other than methyl or ethyl. The compounds are useful as herbicides and they exhibit both preemergence and post-emergence activity. Representative compounds are: 1-(3''isobutyramidophenyl)-3-methyl urea, 1-cyclohexyl-3-(3''propionamidophenyl)urea, 1-butyl-3-(3''-propionamidophenyl) urea, 1-butyl-3-(3''-isobutyramidophenyl)urea, 1-(3''-nitrophenyl)-3-(3''isobutyramidophenyl) urea, 1-N,N-dimethyl-3(pivalamidophenyl)urea, 1-(3''-propionamidophenyl)-3-n-butyl thiourea, and 1-(3''-pentafluoropropionamido phenyl)3,3-dimethyl urea.

    摘要翻译: 元苯胺尿素组合物具有下式:

    Substituted anilide carbamates
    8.
    发明授权
    Substituted anilide carbamates 失效
    取代的抗坏血酸

    公开(公告)号:US3872157A

    公开(公告)日:1975-03-18

    申请号:US67705067

    申请日:1967-10-23

    IPC分类号: C07D307/68 C07C125/06

    CPC分类号: C07D307/68

    摘要: New compounds corresponding to the formula:

    IN WHICH R1 is hydrogen, lower alkyl, or lower alkenyl; R2 is alkyl, lower alkenyl, cycloalkyl, phenyl or substituted phenyl in which the substituents are lower alkyl, lower alkoxy, nitro or halogen; and R3 is hydrogen, lower alkyl, cycloalkyl having 3 to 4 carbon atoms, inclusive, halogenated lower alkyl, lower alkenyl, furyl or benzyl; provided that when R1 is hydrogen or lower alkyl R3 is other than lower alkyl and further provided that when R1 is hydrogen and R2 is methyl, R3 is other than hydrogen, halogenated lower alkyl, cycloalkyl or lower alkenyl. The above-defined compounds are effective herbicides, particularly for the control of grasses and broadleaf plants with both pre-emergence and post-emergence activity. Representative compounds are: 3''-(N-n,propylcarbamoyloxy)cyclopropane carboxanilide, 3''-(N-n-butylcarbamoyloxy)crotonanilide, 3''-(Nethylcarbamoyloxy)furoyl anilide, 3''-(N,N-diallylcarbamoyloxy) propionanilide, 3''-(N-n-propylcarbamoyloxy)vinylacetanilide and 3''-(N-i-propylcarbamoyloxy)2-bromo isobutyranilide.

    摘要翻译: 新化合物对应于下式:

    Bis-meta-phenylene ureas
    9.
    发明授权
    Bis-meta-phenylene ureas 失效
    BIS-META-PHENYLENE UREAS

    公开(公告)号:US3707556A

    公开(公告)日:1972-12-26

    申请号:US3707556D

    申请日:1970-10-12

    发明人: TEACH EUGENE G

    IPC分类号: C07C275/40 C07C127/00

    CPC分类号: C07C275/40

    摘要: IN WHICH X REPRESENTS OXYGEN OR SULFUR, R1 REPRESENTS LOWER ALKYL OR LOWER ALKENYL, R2 IS HYDROGEN, R3 REPRESENTS ALKYL, ALKENYL, CHLOROACETYL, PHENYL AND CHLORO SUBSTITUTED PHENYL, R4 REPRESENTS HYDROGEN, LOWER ALKYL AND FURFUYL, AND Z REPRESENTS HYDROGEN OR LOWER ALKYL. THE COMPOUNDS OF THIS INVENTION ARE USEFUL AS HERBICIDES.

    1-(R1-N(-R2)-C(=X)-NH-),3-(R3-N(-R4)-CO-NH-),Z-BENZENE

    BIS-META-PHENYLENE UREAS HAVING THE FORMULA:

    Phenoxy acetals and their utility as herbicides
    10.
    发明授权
    Phenoxy acetals and their utility as herbicides 失效
    苯氧基缩醛及其作为除草剂的用途

    公开(公告)号:US3903155A

    公开(公告)日:1975-09-02

    申请号:US38550773

    申请日:1973-08-03

    发明人: TEACH EUGENE G

    CPC分类号: C07C275/34 C07C335/18

    摘要: Meta-phenoxy acetals having the formula

    in which X is oxygen or sulfur, R and R1 are independently lower alkyl, R and R1 taken together are ethylene or trimethylene, R2 is alkyl, monocyclohexylamino, monoalkylamino, monoalkenylamino, dialkylamino, alkoxy, alkylthio, haloalkyl, substituted-phenyl wherein said substituents are methyl, monochloro or dichloro. The compounds are useful as herbicides.

    摘要翻译: 具有式OR O-CH2CH ANGLE OR1 NHC-R2的2-氨基 - 苯氧基缩醛其中X是氧或硫,R和R1独立地是低级烷基,R和R1一起是亚乙基或三亚甲基,R 2是烷基,单环己基氨基, 单烷基氨基,单链烯基氨基,二烷基氨基,烷氧基,烷硫基,卤代烷基,取代的 - 苯基,其中所述取代基是甲基,一氯或二氯。 该化合物可用作除草剂。