摘要:
An organometallic compound, represented by Formula 1: M(L1)n1(L2)n2 Formula 1 wherein M is a transition metal, L1 is a ligand represented by Formula 2-1, L2 is a ligand represented by Formula 2-2, n1 is 0, 1, or 2, n2 is 1, 2, or 3, and L1 and L2 are different from each other, wherein R1 to R4, rings CY1 to CY3, rings CY41 and CY42, Y1 to Y3, X4, Z4, a1 to a3, b4, *, and *′ are each as defined herein.
摘要:
An organometallic compound represented by Formula 1: M(L1)n1(L2)n2 Formula 1 wherein M, L1, L2, n1, and n2 are the same as described in the specification.
摘要:
A genetically modified microorganism comprising a polynucleotide encoding α-ketoglutarate synthase or a mutant thereof, and a polynucleotide encoding pyruvate carboxylase or a mutant thereof; wherein the genetically modified microorganism has decreased malate quinone oxidoreductase activity and/or decreased phosphoenolpyruvate carboxykinase activity compared to an unmodified microorganism of the same type, and wherein the genetically modified microorganism produces 4-hydroxybutyrate.
摘要:
An organometallic compound, represented by Formula 1: M1(Ln1)n1(Ln2)n2 Formula 1 wherein, in Formula 1, M1 is a transition metal, Ln1 is a ligand represented by Formula 1A, Ln2 is a ligand represented by Formula 1B, n1 is 1 or 2, and n2 is 1 or 2: wherein, in Formulae 1A, 1B, CY1, CY2, CY4, X1, X2, Y1, R1, R2, R10, R20, R40, R31, R32, R33, R34, R40, b10, b20, and b40 are as provided herein, and wherein * and * each indicate a binding site to M1.
摘要:
An organometallic compound represented by Formula 1: M(L1)n1(L2)n2 Formula 1 wherein M is a transition metal, L1 is a ligand represented by Formula 2, L2 is a monodentate ligand, a bidentate ligand, a tridentate ligand, or a tetradentate ligand, n1 is 1, 2, or 3, n2 is 0, 1, 2, 3, or 4, and Formula 2 is as described herein.
摘要:
An organometallic compound represented by Formula 1: M(L1)n1(L2)n2 Formula 1 wherein M is a transition metal, L1 is a ligand represented by Formula 2-1, L2 is a ligand represented by Formula 2-2, n1 and n2 are each independently 1 or 2, a sum of n1 and n2 is 2 or 3, and L1 and L2 are different from each other: wherein Y1, Y4, X1, X21, ring CY1, ring CY21, ring CY22, ring CY14, A1, a1, a2, b1, c1, R11 to R14, R21 to R23, and Z1 to Z5 are as defined in the specification, * and *′ in Formulae 2-1 and 2-2 each indicates a binding site to M, and * in Formula 3 indicates a binding site to ring CY1 in Formula 2-1.
摘要:
Provided is an acid-tolerant yeast cell, a method of producing an organic acid by using the yeast cell, and a method of producing the yeast cell resistant to acid.