摘要:
Compositions for golf balls that include polyurethane and/or polyurea linkages and that are crosslinked in the soft segments of the polymer backbone to improve the crosslink density and effect a hardness gradient throughout the molded article.
摘要:
Golf balls having a hard outer skin produced from a material that includes crosslinks in both the hard and soft segments of the polymer backbone that improve the crosslink density. Compositions formed from polyurethane and/or polyurea prepolymers that are first cured with a curative blend including an isocyanate-reactive component to crosslink the hard segment and then exposed to a free radical initiator and radiation to crosslink the soft segments are used in an outer layer of a golf ball, a unitary golf ball, or other golf ball constructions.
摘要:
Golf balls having improved cut and shear resistance that include covers and/or other layers formed from polyurea compositions formed with at least one amine-terminated polytetramethylene ether glycol homopolymer, at least one amine-terminated copolymer of polytetramethylene ether glycol and polyalkylene glycol. The amine-terminated polytetramethylene ether glycol homopolymer or amine-terminated copolymer of polytetramethylene ether glycol and polyalkylene glycol may be used as the isocyanate-reactive in the prepolymer and/or the curing agent.
摘要:
A golf ball having a cover is cast from a castable reactive aliphatic functional composition consisting essentially of: a methylene dicyclohexyl diisocyanate based prepolymer; at least one polyamine/polyamide functional component used as a backbone of the prepolymer; a free isocyanate group; and a curative. The polyamine/polyamide is formed from the condensation reaction of a polyamine and a polyacid, with the equivalent ratio of polyamine to polyacid ranges from 2:1 to 10:1, preferably the ratio is 3:1, and more preferably 2:1. It is preferable that the polyamine be a Jeffamine series D-2000. The polyacid can be chosen from acids such as maleic, adipic, azelaic or sebacic. It is preferable that the prepolymer be a polyurethane or urea. The formulating techniques eliminate the need for post curing when using aliphatic chemistries in golf ball covers.
摘要:
A golf ball comprising a core and at least one layer disposed about the core, wherein at least one of the core and the layer comprises a thermoplastic or thermoset composition comprising a reaction product of a polyurethane or polyurea prepolymer comprising at least one isocyanate and a curative comprising a blend of at least one aliphatic diamine and at least one polyaspartic ester formed from reactants comprising at least one aliphatic primary polyamine and at least one maleic or fumaric diester, and wherein the thermoplastic or thermoset composition comprises a gel time of about 90 seconds or greater. Also, a golf ball comprising a core and at least one layer disposed about the core wherein at least one of the core and the layer comprises a thermoplastic or thermoset composition T comprising a reaction product of a polyurethane or polyurea prepolymer P comprising at least one isocyanate and a curative C comprising a blend of at least one aliphatic diamine D and at least one polyaspartic ester formed from reactants comprising at least one aliphatic primary polyamine and at least one maleic or fumaric diester, wherein the thermoplastic or thermoset composition T has a gel time X such that X>1.25Y, and wherein Y is the gel time of a thermoplastic or thermoset composition T′ comprising a reaction product of the polyurethane or polyurea prepolymer P and a curative C′ comprising a blend of aliphatic diamine D and a polyaspartic ester consisting of N,N′-diethylmaleate-2-methyl-pentamethylene diamine.
摘要:
Golf balls having improved cut and shear resistance that include covers and/or other layers formed from polyurea compositions formed with at least one amine-terminated polytetramethylene ether glycol homopolymer, at least one amine-terminated copolymer of polytetramethylene ether glycol and polyalkylene glycol. The amine-terminated polytetramethylene ether glycol homopolymer or amine-terminated copolymer of polytetramethylene ether glycol and polyalkylene glycol may be used as the isocyanate-reactive in the prepolymer and/or the curing agent.
摘要:
Compositions for golf balls that include polyurethane and/or polyurea linkages and that are crosslinked in the soft segments of the polymer backbone. In particular, the compositions of the invention, which are based on a polyurethane and/or polyurea, have improved crosslink density and hardness from the crosslinking between the soft, unsaturated segments of the polymer backbone. The curative blend includes at least one isocyanate-reactive component and a free radical initiator.
摘要:
The invention is directed to a golf ball providing improved UV resistance, abrasion resistance and hydrophobicity comprising cerium oxide nanoparticles having a particle size within the wavelength of visible light. The golf ball of the invention may comprise the cerium oxide nanoparticles in any or all of outer core layers, intermediate layers, inner cover layers, outer cover layers and even as a coating composition in an amount of from about 0.5 wt % to about 10 wt % of the respective layer. The cerium oxide nanoparticles may be randomly dispersed within a layer or coating, or alternatively, the cerium oxide nanoparticles may be ordered in an array within the layer or coating.
摘要:
Compositions for golf balls that include polyurethane linkages and that are crosslinked in the soft segments of the polymer backbone. In particular, the compositions of the invention, which are based on a polyurethane have improved crosslink density from the crosslinking between the soft, unsaturated segments of the polymer backbone. The curative blend includes at least one isocyanate-reactive component and a free radical initiator.
摘要:
Compositions for golf balls that include polyurea linkages and that are crosslinked in the soft segments of the polymer backbone. In particular, the compositions of the invention, which are based on a polyurea have improved crosslink density from the crosslinking between the soft, unsaturated segments of the polymer backbone. The curative blend includes at least one isocyanate-reactive component and a free radical initiator.