公开(公告)号：US08506067B2

公开(公告)日：2013-08-13

申请号：US12664084

申请日：2008-07-22

申请人： Shoji Koike ,  Ryota Kato ,  Hitoshi Yoshino

发明人： Shoji Koike ,  Ryota Kato ,  Hitoshi Yoshino

IPC分类号： C09D11/02

CPC分类号： B41M5/0023 ,  C09D11/322

摘要： An ink jet image-forming method for forming an image by applying an ink in a fixed amount of 0.5 pl or more to 6.0 pl or less to plain paper. The ink contains a self-dispersion pigment, water, a water-soluble compound having a coefficient of hydrophilicity-hydrophobicity of 0.37 or more as defined by the equation (A) stated in the description and a water-soluble compound having a coefficient of hydrophilicity-hydrophobicity of 0.25 or less, and has a surface tension of 34 mN/m or less. The application of the ink is divided into plural times when an image having a portion where the ink is applied in a duty of 80% or more and an amount of 5.0 μl/cm2 or less in total is formed in a basic matrix for forming the image, and the amount of the ink applied at each of the times divided is 0.7 μl/cm2 or less.

摘要翻译： 一种喷墨图像形成方法，用于通过将普通纸的固定量为0.5pl以上至6.0pl以下的墨水进行图像形成。 油墨含有自分散颜料，水，具有亲水性 - 疏水性系数的水溶性化合物，如描述中所述的式（A）所定义的0.37以上，具有亲水性系数的水溶性化合物 - 疏水性为0.25以下，表面张力为34mN / m以下。 当在具有80％以上的占空比和总共5.0mul / cm 2以下的量施加墨水的部分的图像形成在基本基质中时，油墨的涂布被分成多次，以形成 图像，并且在每次分割时施加的油墨量为0.7mul / cm 2以下。

公开(公告)号：US08328926B2

公开(公告)日：2012-12-11

申请号：US12665065

申请日：2008-07-22

申请人： Shoji Koike ,  Ryota Kato ,  Hitoshi Yoshino

发明人： Shoji Koike ,  Ryota Kato ,  Hitoshi Yoshino

IPC分类号： C09D11/02

CPC分类号： C09D11/322

摘要： The invention provides an ink jet recording ink containing a self-dispersion pigment having a lactone group and a carboxyl group, an organic carboxylic acid salt, water and a water-soluble substance having a coefficient of hydrophilicity-hydrophobicity of 0.37 or more as defined by the following equation (A), and having a surface tension of 34 mN/m or less. Coefficient of hydrophilicity-hydrophobicity=[(Water activity value of a 20% aqueous solution)−(Molar fraction of water in the 20% aqueous solution)]/ [1−(Molar fraction of water in the 20% aqueous solution)]  Equation (A)

摘要翻译： 本发明提供一种含有内酯基和羧基的自分散颜料，有机羧酸盐，水和亲水疏水性系数为0.37以上的水溶性物质的喷墨记录油墨，其定义如下： 下述式（A），表面张力为34mN / m以下。 亲水性 - 疏水性系数= [（20％水溶液的水分活度值） - （20％水溶液中的水的摩尔分数）] / [1-（20％水溶液中的水的摩尔分数）]式 （一个）

公开(公告)号：US20100165019A1

公开(公告)日：2010-07-01

申请号：US12600893

申请日：2008-07-22

申请人： Shoji Koike ,  Ryota Kato ,  Hitoshi Yoshino

发明人： Shoji Koike ,  Ryota Kato ,  Hitoshi Yoshino

IPC分类号： B41J29/38 ,  C09D11/02

CPC分类号： B41M5/0023 ,  C09D11/322

摘要： The invention provides an ink jet recording ink containing a self-dispersion pigment, to the surface of which an anionic functional group represented by the following general formula (I) has been bonded directly or through another atomic group, water, a water-soluble substance having a coefficient of hydrophilicity-hydrophobicity of 0.37 or more as defined by the following equation (A) and a water-soluble substance having a coefficient of hydrophilicity-hydrophobicity of 0.25 or less as defined by the equation (A), and having a surface tension of 34 mN/m or less. wherein M1 and M2 are, independently of each other, a hydrogen atom, alkali metal, ammonium or organic ammonium; Coefficient of hydrophilicity-hydrophobicity=[(Water activity value of a 20% aqueous solution)−(Molar fraction of water in the 20% aqueous solution)]/[1−(Molar fraction of water in the 20% aqueous solution)]

摘要翻译： 本发明提供一种含有自分散颜料的喷墨记录油墨，其表面由以下通式（I）表示的阴离子官能团直接或通过另一原子团，水，水溶性物质 具有如下式（A）所定义的亲水性 - 疏水性系数为0.37以上的亲水性 - 疏水性系数为0.25以下的水溶性物质，如式（A）所示，具有表面 张力34 mN / m以下。 其中M1和M2彼此独立地为氢原子，碱金属，铵或有机铵; 亲水性 - 疏水性系数= [（20％水溶液的水分活度值） - （20％水溶液中的水的摩尔分数）] / [1-（20％水溶液中的水的摩尔分数）]

公开(公告)号：US20100214351A1

公开(公告)日：2010-08-26

申请号：US12664084

申请日：2008-07-22

申请人： Shoji Koike ,  Ryota Kato ,  Hitoshi Yoshino

发明人： Shoji Koike ,  Ryota Kato ,  Hitoshi Yoshino

IPC分类号： B41J2/015

CPC分类号： B41M5/0023 ,  C09D11/322

摘要： An ink jet image-forming method for forming an image by applying an ink in a fixed amount of 0.5 pl or more to 6.0 pl or less to plain paper. The ink contains a self-dispersion pigment, water, a water-soluble compound having a coefficient of hydrophilicity-hydrophobicity of 0.37 or more as defined by the equation (A) stated in the description and a water-soluble compound having a coefficient of hydrophilicity-hydrophobicity of 0.25 or less, and has a surface tension of 34 mN/m or less. The application of the ink is divided into plural times when an image having a portion where the ink is applied in a duty of 80% or more and an amount of 5.0 μl/cm2 or less in total is formed in a basic matrix for forming the image, and the amount of the ink applied at each of the times divided is 0.7 μl/cm2 or less.

摘要翻译： 一种喷墨图像形成方法，用于通过将普通纸的固定量为0.5pl以上至6.0pl以下的墨水进行图像形成。 油墨含有自分散颜料，水，具有亲水性 - 疏水性系数的水溶性化合物，如描述中所述的式（A）所定义的0.37以上，具有亲水性系数的水溶性化合物 - 疏水性为0.25以下，表面张力为34mN / m以下。 当在具有80％以上的负荷的一部分的图像和总共5.0μl/ cm 2以下的总量的基底基体上形成具有油墨部分的图像时，油墨的涂布被分成多次，以形成 图像，并且分配的每一次施加的油墨量为0.7μl/ cm 2以下。

公开(公告)号：US08328341B2

公开(公告)日：2012-12-11

申请号：US12600893

申请日：2008-07-22

申请人： Shoji Koike ,  Ryota Kato ,  Hitoshi Yoshino

发明人： Shoji Koike ,  Ryota Kato ,  Hitoshi Yoshino

IPC分类号： G01D11/00

CPC分类号： B41M5/0023 ,  C09D11/322

摘要： The invention provides an ink jet recording ink containing a self-dispersion pigment, to the surface of which an anionic functional group represented by the following general formula (I) has been bonded directly or through another atomic group, water, a water-soluble substance having a coefficient of hydrophilicity-hydrophobicity of 0.37 or more as defined by the following equation (A) and a water-soluble substance having a coefficient of hydrophilicity-hydrophobicity of 0.25 or less as defined by the equation (A), and having a surface tension of 34 mN/m or less. wherein M1 and M2 are, independently of each other, a hydrogen atom, alkali metal, ammonium or organic ammonium; Coefficient of hydrophilicity-hydrophobicity=[(Water activity value of a 20% aqueous solution)−(Molar fraction of water in the 20% aqueous solution)]/[1−(Molar fraction of water in the 20% aqueous solution)]  Equation (A)

摘要翻译： 本发明提供一种含有自分散颜料的喷墨记录油墨，其表面由以下通式（I）表示的阴离子官能团直接或通过另一原子团，水，水溶性物质 具有如下式（A）所定义的亲水性 - 疏水性系数为0.37以上的亲水性 - 疏水性系数为0.25以下的水溶性物质，如式（A）所示，具有表面 张力34 mN / m以下。 其中M1和M2彼此独立地为氢原子，碱金属，铵或有机铵; 亲水性 - 疏水性系数= [（20％水溶液的水分活度值） - （20％水溶液中的水的摩尔分数）] / [1-（20％水溶液中的水的摩尔分数）]式 （一个）

公开(公告)号：US20100189902A1

公开(公告)日：2010-07-29

申请号：US12665065

申请日：2008-07-22

申请人： Shoji Koike ,  Ryota Kato ,  Hitoshi Yoshino

发明人： Shoji Koike ,  Ryota Kato ,  Hitoshi Yoshino

IPC分类号： C09D11/02 ,  B05D5/00 ,  B05C5/00 ,  B05C9/14 ,  B41J2/05

CPC分类号： C09D11/322

摘要： The invention provides an ink jet recording ink containing a self-dispersion pigment having a lactone group and a carboxyl group, an organic carboxylic acid salt, water and a water-soluble substance having a coefficient of hydrophilicity-hydrophobicity of 0.37 or more as defined by the following equation (A), and having a surface tension of 34 mN/m or less. Coefficient of hydrophilicity-hydrophobicity=[(Water activity value of a 20% aqueous solution)−(Molar fraction of water in the 20% aqueous solution)]/[1−(Molar fraction of water in the 20% aqueous solution)]  Equation (A)

摘要翻译： 本发明提供一种含有内酯基和羧基的自分散颜料，有机羧酸盐，水和亲水疏水性系数为0.37以上的水溶性物质的喷墨记录油墨，其定义如下： 下述式（A），表面张力为34mN / m以下。 亲水性 - 疏水性系数= [（20％水溶液的水分活度值） - （20％水溶液中的水的摩尔分数）] / [1-（20％水溶液中的水的摩尔分数）]式 （一个）

公开(公告)号：US20060119680A1

公开(公告)日：2006-06-08

申请号：US11275008

申请日：2005-12-01

申请人： Ryota Kato ,  Shoji Koike

发明人： Ryota Kato ,  Shoji Koike

IPC分类号： G01D11/00 ,  C09D11/02

CPC分类号： C09D11/38

摘要： An ink-jet recording ink comprising water, a colorant and a surfactant, wherein a content of the surfactant is 0.3 mass % or more based on the whole mass of the ink, and the ink further comprises a sucrose compound represented by the formula (i) wherein R1 to R8 are individually selected from the group consisting of hydrogen, alkyl groups and alkylene oxide groups, with the proviso that at least one of R1 to R8 is an alkylene oxide group, the total number of alkylene oxide units possessed by the alkylene oxide group in a molecule is 1 to 20, and the proportion of an ethylene oxide unit to the total number of the alkylene oxide units in the molecule is 20.0% or more.

摘要翻译： 一种包含水，着色剂和表面活性剂的喷墨记录油墨，其中所述表面活性剂的含量相对于所述油墨的总质量为0.3质量％以上，并且所述油墨还包含由式（i ）其中R 1至R 8各自独立地选自氢，烷基和氧化烯基团，条件是至少一个R 1，R 2， 1个R 8为环氧烷基，分子中烯化氧基团所具有的氧化烯单元的总数为1〜20，环氧乙烷单元的比例 相对于分子中的氧化烯单元的总数为20.0％以上。

公开(公告)号：US07544237B2

公开(公告)日：2009-06-09

申请号：US11388747

申请日：2006-03-24

申请人： Shoji Koike ,  Ryota Kato

发明人： Shoji Koike ,  Ryota Kato

IPC分类号： C09D11/02 ,  G01D11/00

CPC分类号： C09D11/38

摘要： An ink-jet recording ink which contains water, a coloring material and a surfactant, wherein the surfactant is in a content of from 0.6 to 5% by mass in the ink, and the ink further contains a block compound represented by the following formula (I): HO—(EO)a—(PO)b—(EO)c—H  (I) wherein EOs each represent an ethylene oxide moiety; PO represents a propylene oxide moiety; a, b and c satisfy a≧0, 2≦b≦12, c≧0 and 1≦a+c≦60; and the ethylene oxide moiety/-ies in one molecule is/are in a proportion of from 20 to 80% on the basis of mass. Also disclosed are an ink-jet recording process and an ink-jet recording apparatus which make use of this ink.

摘要翻译： 一种含有水，着色材料和表面活性剂的喷墨记录油墨，其中在油墨中表面活性剂的含量为0.6〜5质量％，并且油墨还含有下式所示的嵌段化合物（ HO（EO）a-（PO）b-（EO）cH（I）<？in-line-formula描述=“In-line formula”end =“lead” formula description =“In-line Formulas”end =“tail”？>其中EOs各自表示环氧乙烷部分; PO表示环氧丙烷部分; a，b和c满足> = 0,2 <= b <= 12，c> = 0和1 <= a + c <= 60; 并且一个分子中的环氧乙烷部分基于质量为20至80％的比例。 还公开了一种使用该油墨的喷墨记录方法和喷墨记录装置。

公开(公告)号：US20050229811A1

公开(公告)日：2005-10-20

申请号：US11095589

申请日：2005-04-01

申请人： Ryota Kato ,  Shoji Koike

发明人： Ryota Kato ,  Shoji Koike

IPC分类号： B41J2/01 ,  B41M5/00 ,  C09D11/00 ,  C09D11/322 ,  C09D11/326 ,  C09D11/328 ,  C09D11/38 ,  H01R13/11 ,  H01R13/115 ,  C09D11/02

CPC分类号： C09D11/38

摘要： An ink-jet recording ink containing water and a coloring material, wherein the ink-jet recording ink further contains an ethylenediamine compound represented by Formula (I). wherein R1, R2, R3 and R4 are each selected from the group consisting of a hydrogen atom, an alkyl group and an alkylene oxide group, provided that at least one of R1 and R2 and at least one of R3 and R4 are each an alkylene oxide group, and that alkylene oxide units in one molecule are 2 to 20 in total number.

摘要翻译： 一种含有水和着色材料的喷墨记录油墨，其中喷墨记录油墨还含有由式（I）表示的乙二胺化合物。 其中R 1，R 2，R 3和R 4都分别选自氢 原子，烷基和烯化氧基团，条件是R 1和R 2中的至少一个和R 3' 和R 4分别为环氧烷基，一个分子中的烯化氧单元总数为2〜20。

公开(公告)号：US07641723B2

公开(公告)日：2010-01-05

申请号：US11730827

申请日：2007-04-04

申请人： Shoji Koike ,  Ryota Kato

发明人： Shoji Koike ,  Ryota Kato

IPC分类号： C09D11/02 ,  B41J2/01

CPC分类号： C09D11/38

摘要： An ink jet recording ink is provided which does not have a problem concerning curling of a recording medium containing cellulose, and can deal with high-definition image recording while maintaining good response at a high level during ejection at a high drive frequency and good startup properties. The ink contains at least water, a colorant, a compound represented by the following general formula (I) accounting for 8 to 40% by mass of the total mass of the ink, and a water-soluble substance accounting for 5 to 30% by mass of the total mass of the ink, the ratio (A/B) of mass (A) of the compound represented by general formula (I) and mass (B) of the water-soluble substance is in a range of 1/3 to 7/1.General formula (I)

摘要翻译： 提供了一种喷墨记录油墨，其不含有含有纤维素的记录介质卷曲的问题，并且可以在高驱动频率的喷射期间以高水平保持良好的响应来处理高分辨率图像记录，并具有良好的启动特性 。 油墨至少含有水，着色剂，由以下通式（I）表示的化合物占总油墨的8〜40质量％，水溶性物质占5〜30％的水溶性物质 油墨总质量，通式（I）表示的化合物的质量（A）与水溶性物质的质量（B）之比（A / B）为1/3 至7/1。 通式（I）