公开(公告)号：US09206285B2

公开(公告)日：2015-12-08

申请号：US13562773

申请日：2012-07-31

申请人： Stephen Z. Cheng ,  Matthew J. Graham ,  Frank W. Harris ,  Shi Jin

发明人： Stephen Z. Cheng ,  Matthew J. Graham ,  Frank W. Harris ,  Shi Jin

IPC分类号： C30B29/54 ,  C30B29/58 ,  C30B29/64 ,  C08G61/12 ,  B82Y20/00 ,  G02B6/122

CPC分类号： C08G61/126 ,  B82Y20/00 ,  C08G61/124 ,  C08G61/125 ,  C08G2261/3221 ,  C08G2261/3222 ,  C08G2261/3223 ,  G02B6/1225

摘要： The present invention relates to conjugated polymers and a method for their synthesis. Furthermore, the present invention relates to electro-synthesis methods for producing polymers that include the use of at least one Lewis acid and at least one proton trap to form organic conjugated polymers having elevated refractive indices. In one embodiment, the present invention relates to an organic polymer having an elevated refractive index, the organic polymer formed by a process comprising the steps of: providing a solution of unsaturated organic monomer units and at least one acidic component; impeding saturation of the unsaturated organic-monomer units by at least one protic element in the solution; and polymerizing the unsaturated organic monomer units to form a conjugated organic polymer having a refractive index of at least about 2.3 for electromagnetic energy having a wavelength of about 700 nm.

摘要翻译： 本发明涉及共轭聚合物及其合成方法。 此外，本发明涉及用于制备聚合物的电合成方法，其包括使用至少一种路易斯酸和至少一个质子阱来形成具有升高折射率的有机共轭聚合物。 在一个实施方案中，本发明涉及具有升高的折射率的有机聚合物，所述有机聚合物通过包括以下步骤的方法形成，所述方法包括：提供不饱和有机单体单元和至少一种酸性组分的溶液; 通过溶液中的至少一种质子元件阻止不饱和有机单体单元的饱和​​; 并且使不饱和有机单体单元聚合以形成具有波长为约700nm的电磁能的折射率为至少约2.3的共轭有机聚合物。

公开(公告)号：US20120296060A1

公开(公告)日：2012-11-22

申请号：US13562773

申请日：2012-07-31

申请人： Stephen Z. Cheng ,  Matthew J. Graham ,  Frank W. Harris ,  Shi Jin

发明人： Stephen Z. Cheng ,  Matthew J. Graham ,  Frank W. Harris ,  Shi Jin

IPC分类号： C08G75/06

CPC分类号： C08G61/126 ,  B82Y20/00 ,  C08G61/124 ,  C08G61/125 ,  C08G2261/3221 ,  C08G2261/3222 ,  C08G2261/3223 ,  G02B6/1225

摘要： The present invention relates to conjugated polymers and a method for their synthesis. Furthermore, the present invention relates to electro-synthesis methods for producing polymers that include the use of at least one Lewis acid and at least one proton trap to form organic conjugated polymers having elevated refractive indices. In one embodiment, the present invention relates to an organic polymer having an elevated refractive index, the organic polymer formed by a process comprising the steps of: providing a solution of unsaturated organic monomer units and at least one acidic component; impeding saturation of the unsaturated organic-monomer units by at least one protic element in the solution; and polymerizing the unsaturated organic monomer units to form a conjugated organic polymer having a refractive index of at least about 2.3 for electromagnetic energy having a wavelength of about 700 nm.

摘要翻译： 本发明涉及共轭聚合物及其合成方法。 此外，本发明涉及用于制备聚合物的电合成方法，其包括使用至少一种路易斯酸和至少一个质子阱来形成具有升高折射率的有机共轭聚合物。 在一个实施方案中，本发明涉及具有升高的折射率的有机聚合物，所述有机聚合物通过包括以下步骤的方法形成，所述方法包括：提供不饱和有机单体单元和至少一种酸性组分的溶液; 通过溶液中的至少一种质子元件阻止不饱和有机单体单元的饱和​​; 并且使不饱和有机单体单元聚合以形成具有波长为约700nm的电磁能的折射率为至少约2.3的共轭有机聚合物。

公开(公告)号：US08257493B2

公开(公告)日：2012-09-04

申请号：US11573694

申请日：2005-08-19

申请人： Stephen Z. Cheng ,  Matthew J. Graham ,  Frank W. Harris ,  Shi Jin

发明人： Stephen Z. Cheng ,  Matthew J. Graham ,  Frank W. Harris ,  Shi Jin

IPC分类号： C30B29/06

CPC分类号： C08G61/126 ,  B82Y20/00 ,  C08G61/124 ,  C08G61/125 ,  C08G2261/3221 ,  C08G2261/3222 ,  C08G2261/3223 ,  G02B6/1225

摘要： The present invention relates to conjugated polymers and a method for their synthesis. Furthermore, the present invention relates to electro-synthesis methods for producing polymers that include the use of at least one Lewis acid and at least one proton trap to form organic conjugated polymers having elevated refractive indices. In one embodiment, the present invention relates to an organic polymer having an elevated refractive index, the organic polymer formed by a process comprising the steps of: providing a solution of unsaturated organic monomer units and at least one acidic component; impeding saturation of the unsaturated organic-monomer units by at least one protic element in the solution; and polymerizing the unsaturated organic monomer units to form a conjugated organic polymer having a refractive index of at least about 2.3 for electromagnetic energy having a wavelength of about 700 nm.

摘要翻译： 本发明涉及共轭聚合物及其合成方法。 此外，本发明涉及用于制备聚合物的电合成方法，其包括使用至少一种路易斯酸和至少一个质子阱来形成具有升高折射率的有机共轭聚合物。 在一个实施方案中，本发明涉及具有升高的折射率的有机聚合物，所述有机聚合物通过包括以下步骤的方法形成，所述方法包括：提供不饱和有机单体单元和至少一种酸性组分的溶液; 通过溶液中的至少一种质子元件阻止不饱和有机单体单元的饱和​​; 并且使不饱和有机单体单元聚合以形成具有波长为约700nm的电磁能的折射率为至少约2.3的共轭有机聚合物。

公开(公告)号：US20080130111A1

公开(公告)日：2008-06-05

申请号：US11573694

申请日：2005-08-19

申请人： Stephen Z. Cheng ,  Matthew J. Graham ,  Frank W. Harris ,  Shi Jin

发明人： Stephen Z. Cheng ,  Matthew J. Graham ,  Frank W. Harris ,  Shi Jin

IPC分类号： G02B5/18 ,  C08F2/04

CPC分类号： C08G61/126 ,  B82Y20/00 ,  C08G61/124 ,  C08G61/125 ,  C08G2261/3221 ,  C08G2261/3222 ,  C08G2261/3223 ,  G02B6/1225

摘要： The present invention relates to conjugated polymers and a method for their synthesis. Furthermore, the present invention relates to electro-synthesis methods for producing polymers that include the use of at least one Lewis acid and at least one proton trap to form organic conjugated polymers having elevated refractive indices. In one embodiment, the present invention relates to an organic polymer having an elevated refractive index, the organic polymer formed by a process comprising the steps of: providing a solution of unsaturated organic monomer units and at least one acidic component; impeding saturation of the unsaturated organic-monomer units by at least one protic element in the solution; and polymerizing the unsaturated organic monomer units to form a conjugated organic polymer having a refractive index of at least about 2.3 for electromagnetic energy having a wavelength of about 700 nm.

摘要翻译： 本发明涉及共轭聚合物及其合成方法。 此外，本发明涉及用于制备聚合物的电合成方法，其包括使用至少一种路易斯酸和至少一个质子阱来形成具有升高折射率的有机共轭聚合物。 在一个实施方案中，本发明涉及具有升高的折射率的有机聚合物，所述有机聚合物通过包括以下步骤的方法形成，所述方法包括：提供不饱和有机单体单元和至少一种酸性组分的溶液; 通过溶液中的至少一种质子元件阻止不饱和有机单体单元的饱和​​; 并且使不饱和有机单体单元聚合以形成具有波长为约700nm的电磁能的折射率为至少约2.3的共轭有机聚合物。