公开(公告)号：US4122291A

公开(公告)日：1978-10-24

申请号：US803889

申请日：1977-06-06

申请人： Sunao Kyo ,  Tsumoru Renge ,  Hidetsugu Tanaka

发明人： Sunao Kyo ,  Tsumoru Renge ,  Hidetsugu Tanaka

IPC分类号： C07D309/22 ,  C07C29/12 ,  C07D309/06 ,  C07D309/18 ,  C07F5/04

CPC分类号： C07D309/22

摘要： Production of an alken-2-ol-1, or of an alken-2-ol-1 and an alkanol-1 from the corresponding alken-3-ol-1 is described. The above compound or compounds can be produced with good selectivity by converting an alken-3-ol-1 to the boric acid ester, and, then, contacting the ester with a palladium catalyst in the presence of hydrogen or, alternatively, by carrying out the latter-mentioned step under conditions favorable to the formation of said boric acid ester and, thereafter, subjecting the reaction product to solvolysis.

摘要翻译： 描述了从相应的烯-3-醇-1生产烯-2-醇-1或烯-2-醇-1和链烷醇-1。 可以通过将烯-3-醇-1转化成硼酸酯，然后在氢气存在下使该酯与钯催化剂接触，或者通过进行 在有利于形成所述硼酸酯的条件下，在后述步骤中，然后使反应产物溶剂解。

公开(公告)号：US4511751A

公开(公告)日：1985-04-16

申请号：US540870

申请日：1983-10-11

申请人： Yoichi Ninagawa ,  Osamu Yamada ,  Tsumoru Renge ,  Sunao Kyo ,  Takayoshi Osaki ,  Koichi Kushida

发明人： Yoichi Ninagawa ,  Osamu Yamada ,  Tsumoru Renge ,  Sunao Kyo ,  Takayoshi Osaki ,  Koichi Kushida

IPC分类号： C07C1/20 ,  C07C2/86 ,  C07C29/40 ,  C07C45/00 ,  C07C45/81 ,  C07C45/82 ,  C07D309/18 ,  C07D319/06 ,  C07C11/18

CPC分类号： C07D319/06 ,  C07C1/20 ,  C07C2/867 ,  C07C29/40 ,  C07C45/00 ,  C07C45/81 ,  C07C45/82 ,  C07D309/18

摘要： A process for producing isoprene in good yield is provided. The process is characterized in that isobutene and/or tertiary butanol and a formaldehyde source are fed, together with water, into an acidic aqueous solution continuously or intermittently while maintaining the reaction pressure in an adequate range and at the same time distilling off the product isoprene and unreacted starting materials, together with water, from the reaction zone.

摘要翻译： 提供了以良好的产率生产异戊二烯的方法。 该方法的特征在于将异丁烯和/或叔丁醇和甲醛源与水一起连续或间歇地进料到酸性水溶液中，同时保持反应压力在适当的范围内，同时蒸除产物异戊二烯 和来自反应区的未反应的起始原料与水一起。

公开(公告)号：US4593145A

公开(公告)日：1986-06-03

申请号：US707842

申请日：1985-03-04

申请人： Yoichi Ninagawa ,  Osamu Yamada ,  Tsumoru Renge ,  Sunao Kyo ,  Takayoshi Osaki ,  Koichi Kushida

发明人： Yoichi Ninagawa ,  Osamu Yamada ,  Tsumoru Renge ,  Sunao Kyo ,  Takayoshi Osaki ,  Koichi Kushida

IPC分类号： C07C1/20

CPC分类号： C07C1/20

摘要： A process for producing isoprene in good yield is provided. The process is characterized in that an alkyl tertiary butyl ether and a formaldehyde source are fed, together with water, into a acidic aqueous solution continuously or intermittently while maintaining the reaction pressure in an adequate range and at the same time distilling off the product isoprene, unreacted starting materials, isobutene and tertiary butanol, together with water, from the reaction zone.

摘要翻译： 提供了以良好的产率生产异戊二烯的方法。 该方法的特征在于，将烷基叔丁基醚和甲醛源与水一起连续或间歇地进料到酸性水溶液中，同时将反应压力保持在适当的范围内，同时蒸除产物异戊二烯， 未反应的原料，异丁烯和叔丁醇，以及水，从反应区。

公开(公告)号：US4990697A

公开(公告)日：1991-02-05

申请号：US422049

申请日：1989-10-16

申请人： Tsumoru Renge ,  Osamu Yamada ,  Katumi Omura

发明人： Tsumoru Renge ,  Osamu Yamada ,  Katumi Omura

IPC分类号： C07C29/60

CPC分类号： C07C29/60

摘要： A process for producing homoallyl alcohols of the general formula (I) ##STR1## in which either A.sup.1 or A.sup.3 represents a hydrogen atom, the other represents a single bonding along with A.sup.2 ; R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are the same or different and independently represents a hydrogen atom, or an alkyl or alkenyl group with or without being substituted with a hydroxyl group or an akoxyl group; and Y represents a hydrogen atom, an alkyl group or an alkenyl group, by reacting 1,3-glycols of the general formula (II) ##STR2## in which X and Y are the same or different and independently represents a hydrogen atom, an alkyl group or an alkenyl group, R.sup.1, R.sup.2, R.sup.3, R.sup.4, and R.sup.5 independently represents as defined above, at a temperature in the range of 130.degree. to 250.degree. C. in liquid phase with the contact of .gamma.-alumina catalyst.