公开(公告)号：US3800001A

公开(公告)日：1974-03-26

申请号：US29322272

申请日：1972-09-28

Applicant: TEXACO INC

Inventor： OWENS W ,  PRESCOTT G ,  LEWIS C

IPC: C07C1/30 ,  C07C2/62 ,  C07C9/16 ,  C07C3/56

CPC classification number: C07C9/16 ,  C07C1/30 ,  C07C2/62 ,  C07C2521/04 ,  C07C2527/11 ,  C07C2527/126 ,  C07C11/04

Abstract: Isobutane is alkylated with ethylene in the presence of HCl promoted aluminum chloride alkylation catalyst; ethyl chloride is a by-product formed and recovered from the hydrocarbon effluent in a normal butane - ethyl chloride fraction. The normal-butaneethyl chloride fraction is pyrolyzed at 400*-1,000* F with bauxite catalyst to form ethylene, hydrogen chloride along with normal butane; the normal butane is separated from the mixture, by condensation, and the remaining vapor stream of ethylene and hydrogen fluoride is recycled to the alkylation reaction.

Abstract translation: 在HCl促进的氯化铝烷基化催化剂存在下，将异丁烷与乙烯烷基化; 氯乙烷是在正丁烷 - 氯乙烷馏分中从烃流出物形成和回收的副产物。 正丁烷 - 氯乙烷馏分用铝土矿催化剂在400°-1000°F热解，与正丁烷一起形成乙烯，氯化氢; 通过缩合将正丁烷与混合物分离，并将乙烯和氟化氢的剩余蒸气流再循环至烷基化反应。