公开(公告)号：US3891539A

公开(公告)日：1975-06-24

申请号：US44536574

申请日：1974-02-25

Applicant: TEXACO INC

Inventor： NELSON GERALD VERDELL ,  WRAY GLENN COOPER

IPC: C10G47/12 ,  C10G65/10 ,  B01J11/82 ,  C10G13/02

CPC classification number: C10G65/10 ,  C10G47/12 ,  Y10S208/02

Abstract: A hydrocracking process wherein heavy hydrocarbon oils having from about 10 to 50 percent boiling above 1,000*F. and containing appreciable amounts of sulfur, nitrogen, and metal-containing compounds as well as asphaltenes are converted into a minor fraction of low sulfur residual fuel oil and a major fraction of low sulfur gasoline. The process comprises hydrocracking the heavy oil with molecular hydrogen, at a temperature of about 700*-850*F. in the presence of a sulfur and nitrogen resistant hydrocracking catalyst comprising a hydrogenating component supported upon an amorphous inorganic oxide cracking base to convert the heavy hydrocarbon oil into a gas-oil fraction and a low sulfur residual fraction; separating the gas-oil fraction from the residual fraction; hydrocracking the gas-oil fraction with molecular hydrogen, at a temperature of 700*-780*F., in the presence of a sulfur and nitrogen resistant hydrocracking catalyst comprising a hydrogenation component supported upon a cation exchanged crystalline silica-alumina zeolitic molecular sieve cracking base to yield low sulfur, low nitrogen gasoline.

Abstract translation: 一种加氢裂化方法，其中沸点高于1000°F且含有相当数量的含硫，氮和金属的化合物以及沥青质的重烃油被转化为少部分低硫残余燃料油 和大部分低硫汽油。 该方法包括在约700-850°F的温度下，在含有负载在无定形无机氧化物裂解碱上的氢化组分的硫和氮的加氢裂化催化剂存在下，用分子氢加氢裂化重质油，以将重质 烃油成为瓦斯油馏分和低硫残渣馏分; 从残余馏分中分离瓦斯油馏分; 在含有硫和氮的加氢裂化催化剂的存在下，在700-780°F的温度下，用分子氢加氢裂解粗柴油馏分，该加氢裂化催化剂包含负载在阳离子交换的结晶二氧化硅 - 氧化铝 - 沸石分子筛裂化 产生低硫，低氮汽油。